• Transactions on Electrical and Electronic Materials
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• v.5 no.6
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• pp.223-226
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• 2004

The PZT thin films are one of well-known materials that has been widely studied for ferroelectric random access memory (FRAM). We etched the PZT thin films by $CF_{4}/(Cl_{2}+Ar)$ plasma and investigated improvement in etching damage by $O_{2}$ annealing. The maximum etch rate of the PZT thin films was 157 nrn/min and that the selectivity of the PZT thin films to Pt was 3.1 when $CF_{4}(30{\%})$ was added to a $Cl_{2}(80{\%})/Ar(20{\%})$ gas mixing ratio. To improve the ferroelectric properties of PZT thin films after etching, the samples were annealed for 10 min at various temperatures in $O_{2}$ atmosphere. After $O_{2}$ annealing, the remanent polarization of the asdeposited films was $34.6{\mu}/cm^{2}$ and the sample annealed at 650, 550, and $450^{\circ}C$ was 32.8, 22.3, and $18.6{\mu}/cm^{2}$, respectively. PZT thin films with $O_{2}$ annealing at $450^{\circ}C$ retained $77{\%}$ of their original polarization at 106 cycles. Also as the annealing temperature increased, the fatigue properties improved. And the leakage current was decreased gradually and almost recovered to the as-deposited value after the annealing at $450^{\circ}C$.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.28 no.4
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• pp.222-231
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• 2016

Multi-member lattice-type structures including jackets and tripods are being considered as good alternatives to monopile foundations for relatively deep water of 25-50 m of water depth owing to their technical and economic feasibility. In this study, the reliability analysis of bottom-fixed offshore wind turbines with monopile and/or multi-member lattice-type foundations is carried out and the sensitivities of random variables such as material properties, external wind loadings and scouring depth are compared with respect to different types of foundations. Numerical analysis of the NREL 5 MW wind turbine supported by monopile, tripod and jacket substructures shows that the uncertainties of soil properties affect the reliability index more significantly for the monopile-supported OWTs while the reliability index is not so sensitive to the material properties in the cases of tripod- and jacket-supported OWTs. In conclusion, the reliability analysis can be preliminarily carried out without considering soil-pile-interaction in the cases of tripod- and jacket-supported OWTs while it is very important to use the well-measured soil properties for reliable design of monopile-supported OWTs.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.05a
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• pp.190-197
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• 2004

In order to consider statistical properties of probability variables used in the structural analysis, the conventional approach using the safety factor based on past experience usually estimated the safety of a structure. Also, the real structures could only be analyzed with the error in estimation of loads, material characters and the dimensions of the members. But the errors should be considered systematically in the structural analysis. In this paper, we estimated the probability of failure of the pressure vessel. And also, this paper presents sensitivity values of the random variable. Finally, we show that reliability index and probability of failure can present the tolerance limit of dimension of randam variables.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.1130-1135
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• 2003

The need to increase the reliability of a structural system has been significantly brought in the procedure of real designs to consider, for instance, the material properties or geometric dimensions that reveal a random or incompletely known nature. Reliability based design optimization of a real system now becomes an emerging technique to achieve reliability, robustness and safety of these problems. Finite element analysis program and the reliability analysis program are necessary to evaluate the responses and the probabilities of failure of the system, respectively. Moreover, integration of these programs is required during the procedure of reliability based design optimization. It is well known that reliability based design optimization can often have so many local minima that it cannot converge to the specified probability of failure. To overcome this problem, barrier function method in reliability based design optimization is suggested. To illustrate the proposed formulation, reliability based design optimization of a bracket is performed. AMV and FORM are employed for reliability analysis and their optimization results are compared based on the accuracy and efficiency.

• Macromolecular Research
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• v.11 no.2
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• pp.80-86
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• 2003

The polymerization of a cyclopolymerizable disubstituted dipropargyl ether, his(3-trimethylsilyl-2-propynyl)ether (BTPE), was attempted by various transition metal catalysts. The yield for the polymerization of BTPE was generally low, which is possibly due to the steric hindrance of bulky substituents. In general, the catalytic activities of Mo-based catalysts were found to be greater than those of W-based catalysts. The highest yield was obtained when the MoCl$_{5}$,-EtAlCl$_2$(1:2) catalyst system was used. The copolymerization of BTPE and diethyl dipropargylmalonate yielded a random copolymer with conjugated polymer backbone. However the polymers were partially desilylated, depending on the reaction conditions. The thermal and morphological properties of the resulting polymers were also discussed.d.

• Advances in concrete construction
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• v.3 no.2
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• pp.127-143
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• 2015

Steel fibre reinforced concrete (SFRC) is an anisotropic material due to the random orientation of the fibres within the cement matrix. Fibres under different inclination angles provide different strength contribution of a given crack width. For that the pull-out response of inclined fibres is of great importance to understand SFRC behaviour, particularly in the case of fibres with hooked ends, which are the most widely used. The paper focuses on the numerical modelling of the pull-out response of this kind of fibres from high-strength cementitious matrix in order to study the effects of different inclination angles of the fibres to the load-displacement pull-out curves. The pull-out of the fibres is studied by means of accurate three-dimensional finite element models, which take into account the nonlinearities that are present in the physical model, such as the nonlinear bonding between the fibre and the matrix in the early stages of the loading, the unilateral contact between the fibre and the matrix, the friction at the contact areas, the plastification of the steel fibre and the plastification and cracking of the cementitious matrix. The bonding properties of the fibre-matrix interface considered in the numerical model are based on experimental results of pull-out tests on straight fibres.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.365-370
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• 2004

Generally, component and FR-4 board are connected by solder joint. Because material properties of components and FR-4 board are different, component and FR-4 board show different coefficients of thermal expansion (CTE) and thus strains in component and board are different when they are heated. That is, the differences in CTE of component and FR-4 board cause the dissimilarity in shear strain and solder joint' failure. The first order Taylor series expansion of the limit state function incorporating with Tresca failure criterion is used in order to estimate the failure probability of solder joints under heated condition. Using shear stresses and shear strains appeared on the solder joint, we estimate the failure probability of solder joints with the Tresca failure criterion. The effects of random variables such as CTE, distance of the solder joint from the neutral point(DNP), temperature variation and height of solder on the failure probability of the solder joint are systematically studied by using the failure probability model with first order reliability method(FORM).

• Structural Engineering and Mechanics
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• v.54 no.6
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• pp.1097-1109
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• 2015

A novel optimization approach for reinforced concrete (RC) biaxially loaded columns is proposed. Since there are several design constraints and influences, a new computation methodology using iterative analyses for several stages is proposed. In the proposed methodology random iterations are combined with music inspired metaheuristic algorithm called harmony search by modifying the classical rules of the employed algorithm for the problem. Differently from previous approaches, a detailed and practical optimum reinforcement design is done in addition to optimization of dimensions. The main objective of the optimization is the total material cost and the optimization is important for RC members since steel and concrete are very different materials in cost and properties. The methodology was applied for 12 cases of flexural moment combinations. Also, the optimum results are found by using 3 different axial forces for all cases. According to the results, the proposed method is effective to find a detailed optimum result with different number of bars and various sizes which can be only found by 2000 trial of an engineer. Thus, the cost economy is provided by using optimum bars with different sizes.

• Computers and Concrete
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• v.15 no.4
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• pp.485-501
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• 2015

Cooling by the flow of water through an embedded cooling pipe has become a common and effective artificial thermal control measure for massive concrete structures. However, an extreme thermal gradient induces significant thermal stress, resulting in thermal cracking. Using a mesoscopic finite-element (FE) mesh, three-phase composites of concrete namely aggregate, mortar matrix and interfacial transition zone (ITZ) are modeled. An equivalent probabilistic model is presented for failure study of concrete by assuming that the material properties conform to the Weibull distribution law. Meanwhile, the correlation coefficient introduced by the statistical method is incorporated into the Weibull distribution formula. Subsequently, a series of numerical analyses are used for investigating the influence of the correlation coefficient on tensile strength and the failure process of concrete based on the equivalent probabilistic model. Finally, as an engineering application, damage and failure behavior of concrete cracks induced by a water-cooling pipe are analyzed in-depth by the presented model. Results show that the random distribution of concrete mechanical parameters and the temperature gradient near water-cooling pipe have a significant influence on the pattern and failure progress of temperature-induced micro-cracking in concrete.

• Transactions on Electrical and Electronic Materials
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• v.13 no.3
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• pp.144-148
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• 2012

In this work, we investigated to the etching characteristics of $TiO_2$ thin film and the selectivity using the inductively coupled plasma system. The etch rate and the selectivity were obtained with various gas mixing ratios. The maximum etch rate of $TiO_2$ thin film was 61.6 nm/min. The selectivity of $TiO_2$ to TiN, and $TiO_2$ to $SiO_2$ were obtained as 2.13 and 1.39, respectively. The etching process conditions are 400 W for RF power, -150 V for DC-bias voltage, 2 Pa for the process pressure, and $40^{\circ}C$ for substrate temperature. The chemical states of the etched surfaces were investigated with X-ray photoelectron spectroscopy (XPS). Its analysis showed that the etching mechanism was based on the physical and chemical pathways in the ion-assisted physical reaction.