• Title/Summary/Keyword: r-alumina

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Application of ANN modeling for oily wastewater treatment by hybrid PAC-MF process

  • Abbasi, Mohsen;Rasouli, Yaser;Jowkar, Peyman
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.285-292
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    • 2018
  • In the following study, Artificial Neural Network (ANN) is used for prediction of permeate flux decline during oily wastewater treatment by hybrid powdered activated carbon-microfiltration (PAC-MF) process using mullite and mullite-alumina ceramic membranes. Permeate flux is predicted as a function of time and PAC concentration. To optimize the networks performance, different transfer functions and different initial weights and biases have been tested. Totally, more than 850,000 different networks are tested for both membranes. The results showed that 10:6 and 9:20 neural networks work best for mullite and mullite-alumina ceramic membranes in PAC-MF process, respectively. These networks provide low mean squared error and high linearity between target and predicted data (high $R^2$ value). Finally, the results present that ANN provide best results ($R^2$ value equal to 0.99999) for prediction of permeation flux decline during oily wastewater treatment in PAC-MF process by ceramic membranes.

Flammability and Released Toxic Halogen Gases during Combustion of Flame-Retardant Flexible Polyurethane Foam (난연 연질 폴리우레탄 반도체의 난연성과 연소시 발생되는 유독성 할로겐 기체 검출에 관한 연구)

  • 전종한
    • Journal of the Korean Society of Safety
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    • v.6 no.1
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    • pp.26-30
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    • 1991
  • Flammability, and released toxic halogen gases during combustion about two kinds of flame-retardant flexible foam(F.R. flexible PV foam) were investigated. One of the above was F.R. flexible PU foam with the containment of halogen and the other was manufactured with pure flexible PU foam in aqueous solution of alumina trihydrate(ATH) and dried 4 hours at 10$0^{\circ}C$. Flammability by L.O.I and UL94 HF-1 of the two materials were similarly shown. And combustion gases were analyzed with GC-Mass. HCI, CI$_2$ and HF were detected at both halogen being contained F.R. flexible PU foam and ATH dolng one The reason, to find halogen gases from burning ATH-containing F, R. flexible PU foam which wasn't used for any halogenated F.R., could be considered as by using trichlorofluoromethane with blowing agent to make PU foam. The relative quanity of relesed halogen gases of F.R. flexible PU foam with the containment of halogen had been indicated tree times HCI and CI$_2$, two times HF than ATH containing, respectively.

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The Effect of Lithia Addition on the Sodium Ion Conductivity of Vapor Phase Converted Na-β"-alumina/YSZ Solid Electrolytes

  • Sasidharanpillai, Arun;Kim, Hearan;Cho, Yebin;Kim, Dongyoung;Lee, Seungmi;Jung, Keeyoung;Lee, Younki
    • Journal of the Korean Electrochemical Society
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    • v.25 no.4
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    • pp.191-200
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    • 2022
  • Na-β"-Al2O3 has been widely employed as a solid electrolyte for high-temperature sodium (Na) beta-alumina batteries (NBBs) thanks to its superb thermal stability and high ionic conductivity. Recently, a vapor phase conversion (VPC) method has been newly introduced to fabricate thin Na-β"-Al2O3 electrolytes by converting α-Al2O3 into β"-Al2O3 in α-Al2O3/yttria-stabilized zirconia (YSZ) composites under Na+ and O2- dual percolation environments. One of the main challenges that need to be figured out is lowered conductivity due to the large volume fraction of the non-Na+-conducting YSZ. In this study, the effect of lithia addition in the β"-Al2O3 phase on the grain size and ionic conductivity of Na-β"-Al2O3/YSZ solid electrolytes have been investigated in order to enhance the conductivity of the electrolyte. The amount of pre-added lithia (Li2O) precursor as a phase stabilizer was varied at 0, 1, 2, 3, and 4 mol% against that of Al2O3. It turns out that ionic conductivity increases even with 1 mol% lithia addition and reaches 67 mS cm-1 at 350 ℃ of its maximum with 3 mol%, which is two times higher than that of the undoped composite.

ALLOY STRUCTURE AND ANODIC FILM GROWTH ON RAPIDLY SOLIDIFIED AL-SI-BASED ALLOYS

  • Kim, H.S.;Thompson, G.E.;Wood, G.C.;Wright, I.G.;Maringer, R.E.
    • Journal of the Korean institute of surface engineering
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    • v.17 no.2
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    • pp.29-40
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    • 1984
  • The structure of rapidly solidified Al-Si-based alloys and its relationship to subsequent anodic film growth in near neutral and acid solutions have been investigated. Solidification of the alloys proceeds via pre-dendritic nuclei, associated with rugosity of the casting surface, from which cellular-type growth, comprised of aluminium-rich material surrounded by silicon-containing material, emanates. Observation of ultramicrotomed sections of the alloys and their anodic films reveals the local oxidation of the silicon-rich phase and its incorporation into the anodic alumina film, formed in near neutral solutions. Such incorporation occurs but resultant isolation of the silicon-rich phase is not possible for anodizing in phosphoric acid, and a three-dimensional network of the oxidized silicon-containing phase, with continuing development of porous anodic alumina, is observed.

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Preparation and Sintering Behavior of Monodispersed Alumina-Zirconia Fine Powders (단분산 $Al_2O_3-ZrO_2$ 복합분말의 합성과 소결특성)

  • 부재필;송용원;최상홀
    • Journal of the Korean Ceramic Society
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    • v.31 no.10
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    • pp.1209-1217
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    • 1994
  • Monodispersed alumina-zirconia fine powders were prepared by controlled hydrolysis of alkoxides. These powders and the sintered bodies were characterized. Aluminium alkoxide and zirconium alkoxide were dissolved into complex solvent with butanol and n-propanol, and by acetonitrile added hydrolytic solution, hydrolysis rate was controlled. The oil, as a dispersant, was added in hydrolytic solution, and then prepared powders were nano-sized and well-monodispersed. In the case of hydroxypropyl celluose (HPC) as a dispersant, it was added in complex solution with butanol and iso-propanol, sub-micrometer sized and well-monodispersed powders could be prepared. The value of relative density (R.D.) and tetragonal phase fraction of zirconia in the sintered body made by nano-meter sized powders were respectively higher than those in the case of sub-micrometer sized one.

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Wafer cleaning efficiency by Laser Shock Wave (레이저충격파를 이용한 웨이퍼 세정)

  • Kang Y. J.;Lee S. H.;Park J. G.;Lee J. M.;Kim T. H.
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2003.11a
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    • pp.256-259
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    • 2003
  • To develop cleaning process various particles should be deposited on wafer surfaces to measure particle removal efficiencies. The purpose of the article in to evaluate, removal efficient)r of silica and alumina particles from wafer surfaces when they are deposited by dry and wet method. Dry deposition in air and wet spray deposition using solutions are used. van der Waals are considered to calculate the adhesion force of particles on surfaces. Higher adhesion force is measured on alumina particles on silicon when particles are deposited in air.

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Effect of Water Back-flushing Condition in Hybrid Water Treatment Process of Carbon Fiber Microfiltration Membrane and Photocatalyst (탄소섬유 정밀여과막 및 광촉매 혼성 수처리 공정에서 물 역세척 조건의 영향)

  • Park, Jin Yong;Cho, Gwang Hee
    • Membrane Journal
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    • v.22 no.3
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    • pp.216-223
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    • 2012
  • The effect of water back-flushing period (FT) was investigated in hybrid process of carbon fiber microfiltration membrane and photocatalyst for advanced drinking water treatment in this study, and compared with the previous study using alumina ultrafiltration membrane. The FT was changed in the range of 2~10 min with fixed 10 sec of BT. Then, the FT effects on resistance of membrane fouling ($R_f$), permeate flux (J) and total permeate volume ($V_T$) were observed during total filtration time of 180 min. As decreasing FT, $R_f$ decreased and J increased, which was same with the previous result using alumina ultrafiltration membrane. The treatment efficiency of turbidity was high beyond 99.2%, and the effect of FT was not shown on treatment efficiency of turbidity, which was different with the previous result. The treatment efficiency of organic matters was the lowest value of 65.6% at NBF, and it increased as decreasing FT, which was different with the previous result, too. The reason was that the membrane fouling phenomena could show a different mechanism depending on ceramic membrane materials.

0.6 mAh All-Solid-State Thin Fim Battery Fabricated on Alumina Substrate (알루미나 기판상에 구현된 0.6mAh급 전고상 박막전지)

  • Park, H.Y.;Nam, S.C.;Lim, Y.C.;Choi, K.G.;Lee, K.C.;Park, G.B.;Cho, S.B.
    • Journal of the Korean Electrochemical Society
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    • v.8 no.4
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    • pp.181-185
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    • 2005
  • Lithium cobalt oxide thin film cathode, having thickness of $2.9{\mu}m$ with area of $4cm^2$, was deposited on platinum patterned alumina substrate by radio frequency magnetron sputtering. Li/Co molar ratio, which is an important factor for battery performance, was measured as a function of argon working pressure and applied R.F. power. Constant current charge and discharge performances were characterized with high rate discharge and cycling behavior. Using AC impedance analysis, internal resistance of the thin film battery was measured and simulated by proposed equivalent circuit model.

Microwave Properties and Microstructures of (Ba,Sr)TiO3 Thin Films on Various Substrates with Annealing Temperature (다양한 기판위에 증착된 BST 박막의 열처리 온도에 따른 마이크로파 유전성질과 미세구조 변화)

  • Cho, Kwang-Hwan;Kang, Chong-Yun;Yoon, Seok-Jin;Kim, Hyun-Jai
    • Korean Journal of Materials Research
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    • v.17 no.7
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    • pp.386-389
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    • 2007
  • The dielectric properties of $(Ba_{0.5}Sr_{0.5})TiO_3$ ferroelectric thin films have been investigated according to the substrates in order to optimize the their properties. MgO, r-plane sapphire, and poly-crystalline sapphire (Alumina) substrates have been used to deposite $(Ba_{0.5}Sr_{0.5})TiO_3$ ferroelectric thin films by RF magnetron sputtering. The BST thin films deposited on the single crystal (100)MgO substrates have high tunability and low dielectric loss. These results are caused by a low misfit between the lattice parameters of the BST films and the substrate. The BST films deposited on r-plane sapphire have relatively high misfit, and the tunability of 17% and dielectric loss of 0.0007. To improve the dielectric properties of the BST films, the post-annealing methods has been introduced. The BST films deposited on (100)MgO, (1102)r-plane sapphire, and poly-crystalline sapphire substrates have best properties in post-annealing conditions of $1050^{\circ}C$, $1100^{\circ}C$, and $1150^{\circ}C$, respectively. The different optimal post-annealing conditions have been found according to the different misfits between the films and substrates, and thermal expansion coefficients. Moreover, the films deposited on alumina substrate which is relatively cheap have a good tunability properties of 23% by the post-annealing.

Synthesis of Pure Butene-1 through Hydro-isomerization of Butene-2 and Distillation (2-부텐의 수첨이성화반응 및 증류공정을 통한 고순도 1-부텐의 제조)

  • Cho, Jungho;Jeon, Jong-Ki;Song, Youngha;Lee, Seong Jun;Lee, Jae Ho
    • Korean Chemical Engineering Research
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    • v.45 no.4
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    • pp.351-355
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    • 2007
  • It is necessary to convert butene-2 into butene-1 with higher added-values through positional isomerization. In this study, hydro-isomerization of butene-2 with hydrogen over Pd/alumina catalysts was investigated in a fixed bed reactor. The yield of butene-1 over Ld-265 catalyst was higher than that over other catalysts. The yield of butene-1 was highest (5.3%) under the conditions of reaction temperature of $75^{\circ}C$, reaction pressure of 150 psig, 2-butene flow rate of 48 cc/h and hydrogen flow rate of 3 cc/min. We conducted simulation for the process composed of a hydro-isomerization reactor and a distillation tower. In the case of 78% of tray efficiency, we obtained over 99% pure butene-1 through a distillation tower with 171 steps (R=120).