• Bulletin of the Korean Chemical Society
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• v.33 no.2
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• pp.589-596
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• 2012

In this paper, the reactive dynamics properties of the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ were studied by means of the quasi-classical trajectory method based on the London-Eyring-Polanyi-Sato potential energy surfaces. The vibrational distributions, reaction cross sections, rotational alignments of the products BaBr all were obtained. The peak values of the vibrational distributions are located at $\nu$ = 0 for the reactions Ba + $C_6H_5Br$ and Ba + m-$C_6H_4CH_3Br$ when the collision energies are 1.09 and 1.10 eV, respectively. The reaction cross sections increase with the increasing collision energy, which changes from 0.6 to 1.5 eV. The product rotational alignments deviate from -0.5 and firstly increase and then decrease while the collision energy is increasing, just like that of Heavy+Light-Light system.

• Journal of KSNVE
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• v.6 no.5
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• pp.661-669
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• 1996

Proposed is an aero-acoustic performance prediction method of axial fan. The fan aerodynamic performance is predicted by combining pitch-averaged quasi 3-D flow analysis with pressure loss models for blade boundary layer and wake, secondary flow, endwall boundary layer and tip leakage flows. Fan noise is assumed to be radiated as dipole distribution type, and its generation is assumed to be mainly due to the vortex street shed from blade trailing edge. The fluctuating pressure and lift on the blade surface are analyzed by incorporating the wake vortex stree shed from blade trailing edge. The fluctuating pressure and lift on the blade surface are analyzed by incorporating the wake vortex street model with thin airfoil theory. The aero-acoustic performance prediction results by the present method are in good agreement with the measured results of several axial fans. With the present prediction method, parametric studies are carried out to investigate the effects of blade chord length and spacing on the efficiency and the noise level of fan. In the case of lightly loaded fan, both efficiency improvement and noise reduction can be achieved by decreasing chord length or by increasing blade specing. However, when fan is designed at highly loaded condition, the noise reduction by increasing blade spacing penalizes the attaninable efficiency of fan.

• Wind and Structures
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• v.20 no.5
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• pp.683-699
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• 2015

Lighting poles and antenna masts are typically high, slender and light structures. Moreover, they are often characterized by distributed eccentricities that make very complex their shape. Experience teaches that this structural type frequently suffers severe damage and even collapses due to wind actions. To understand and interpret the aerodynamic and aeroelastic behavior of lighting poles and antenna masts, this paper presents the results of static and aeroelastic wind tunnel tests carried out on a complex prismatic element representing a segment of the shaft of such structures. Static tests are aimed at determining the aerodynamic coefficients and the Strouhal number of the test element cross-section; the former are used to evaluate the critical conditions for galloping occurrence based on quasi-steady theory; the latter provides the critical conditions for vortex-induced vibrations. Aeroelastic tests are aimed at reproducing the real behavior of the test element and at verifying the validity and reliability of quasi-steady theory. The galloping hysteresis phenomenon is identified through aeroelastic experiments conducted on increasing and decreasing the mean wind velocity.

• Elastomers and Composites
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• v.48 no.4
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• pp.276-281
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• 2013

Polyester type polyurethane foam modified with acrylic polyol was prepared by quasi prepolymer method. Thermal and dynamic mechanical properties of polyurethane foam were analysed by thermal gravimetric analysis(TGA) and dynamic mechanical analysis(DMA). Also, glass transition temperature was measured by differential scanning calorimeter(DSC). As acrylic polyol contents were increased, thermal stability measured by TGA was slightly decreased. Storage modulus was increased and tan delta was decreased with increasing of acrylic polyol contents.

• Korean System Dynamics Review
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• v.15 no.3
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• pp.105-141
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• 2014

Human Resource Planning and Management(HRPM) is to make organization efficiently and effectively. Based on Promotion and Aging Chain Model, a revised personnel management prediction simulation is established in terms of mid- and long-term organizational changes, annual budget and personnel strategy including a promotion, aging and laying off for the best personnel architecture in organization. Also, the model is possible to find a solution for increasing the organizational capacity. An empirical application to quasi-governmental organization proceeded to testing and validating the model.

• Structural Engineering and Mechanics
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• v.55 no.5
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• pp.913-929
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• 2015

The ratcheting and strain cyclic behaviour of joined conical-cylindrical shells under uniaxial strain controlled, uniaxial and multiaxial stress controlled cyclic loading are investigated in the paper. The elasto-plastic deformation of the structure is simulated using Chaboche non-linear kinematic hardening model in finite element package ANSYS 13.0. The stress-strain response near the joint of conical and cylindrical shell portions is discussed in detail. The effects of strain amplitude, mean stress, stress amplitude and temperature on ratcheting are investigated. Under strain symmetric cycling, the stress amplitude increases with the increase in imposed strain amplitude. Under imposed uniaxial/multiaxial stress cycling, ratcheting strain increases with the increasing mean/amplitude values of stress and temperature. The abrupt change in geometry at the joint results in local plastic deformation inducing large strain variations in the vicinity of the joint. The forcing frequency corresponding to peak axial ratcheting strain amplitude is significantly smaller than the frequency of first linear elastic axial vibration mode. The strains predicted from quasi static analysis are significantly smaller as compared to the peak strains from dynamic analysis.

• Proceedings of the KIPE Conference
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• 2012.07a
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• pp.15-16
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• 2012

This paper is study on a novel high efficiency step up-down converter using loss-less snubber capacitor. The proposed converter is accomplished that the turn-on operation of switches is on zero current switching (ZCS) by DCM. The converter is also applicable to a new quasi-resonant circuit to achieve high efficiency converter. The control switches using in the converter are operated with soft switching, that is, ZVS and ZCS by quasi-resonant method. The control switches are operated without increasing their voltage and current stresses by the soft switching technology. The result is that the switching loss is very low and the efficiency of the converter is high.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.4
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• pp.625-628
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• 2008

Ba-Zn ferrite powders for electromagnetic insulator were synthesized by self-propagating high-temperature synthesis(SHS) with a reaction of $xBaO_2+(1-x)ZnO+0.5Fe_2O_3+Fe{\rightarrow}Ba_xZn_{1-x}Fe_2O_4$. In this study, phase indentification of SHS products was carried out by using x-ray diffractometry and quasi-nano sized Ba-Zn powders were prepared by a pulverizing process. SHS mechanism was studied by thermodynamical analysis about oxidation reaction among $BaO_2,\;ZnO,\;Fe_2O_3$, and Fe. As oxygen pressure increases from 0.25 MPa to 1.0 MPa, the SHS reactions occur well and make clearly the SHS products. X-ray analysis shows that final SHS products formed with the ratio of $BaO_2/ZnO$ of 0.25, 1.0 and 4.0, are mainly $Ba_xZn_{1-x}Fe_2O_4$. Based on thermodynamical evaluation, the heat of formation increases in the order of $ZnFe_2O_4,\;BaFe_2O_4$, and $Ba_xZn_{1-x}Fe_2O_4$. This supports that $Ba_xZn_{1-x}Fe_2O_4$ phase is predominately formed during SHS reaction. The SHS reactions to form $Ba_xZn_{1-x}Fe_2O_4$ depends on oxygen partial pressure, and the heat of formation during the SHS reaction. The SHS reactions tends to occur well with increasing the oxygen partial pressure and BaO2/ZnO ratio in the reactants This means that the SHS reaction for the formation of Ba-Zn ferrite includes the reduction of BaO2/ZnO and the oxidation of Fe. $Ba_xZn_{1-x}Fe_2O_4$ powders after pulverizing is agglomeratedwith a size of about $50{\mu}m$, in which quasi-nano sized particles with about 300nm are present.

• Journal of the Microelectronics and Packaging Society
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• v.21 no.3
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• pp.51-56
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• 2014

The reliability of solder joint is significantly affected by the property of surface finish. This paper reports on a study of high speed shear energy and failure mode for Sn-4.0wt%Ag-0.5wt%Cu (SAC405) solder joints with the time of Pd activation. The nodule size of electroless Ni-P deposit increased with increasing the time of Pd activation. The roughness (Ra) of electroless Ni-P deposit decreased with increasing the time of Pd activation. Then, with $HNO_3$ vapor, the quasi-brittle and brittle mode of SAC405 solder joint decreased with increasing the time of Pd activation. This results indicate that the increase in the Pd activation time for Electroless Ni/ Electroless Pd/ Immersion Au (ENEPIG) surface finish play a critical role for improving the robustness of SAC405 solder joint.

• Journal of the Korean Chemical Society
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• v.67 no.6
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• pp.407-414
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• 2023

The present study uses quasi-classical trajectory procedures to examine the vibrational relaxation and dissociation of the methyl and ring C-H bonds in excited methylpyrazine (MP) during collision with either N₂ or O₂. The energy-loss (-ΔE) of the excited MP is calculated as the total vibrational energy (E_T) of MP is increased in the range of 5,000 to 40,000cm^-1. The results indicate that the collision-induced vibrational relaxation of MP is not large, increasing gradually with increasing E_T between 5,000 and 30,000 cm^-1, but then decreasing with the further increase in E_T. In both N₂ and O₂ collisions, the vibrational relaxation of MP occurs mainly via the vibration-to-translation (V→T) and vibration-to-vibration (V→V) energy transfer pathways, while the vibration-to-rotation (V→R) energy transfer pathway is negligible. In both collision systems, the V→T transfer shows a similar pattern and amount of energy loss in the ET range of 5,000 to 40,000cm^-1, whereas the pattern and amount of energy transfer via the V→V pathway differs significantly between two collision systems. The collision-induced dissociation of the C-H_methyl or C-H_ring bond occurs when highly excited MP (65,000-72,000 cm^-1) interacts with the ground-state N₂ or O₂. Here, the dissociation probability is low (10^-4-10^-1), but increases exponentially with increasing vibrational excitation. This can be interpreted as the intermolecular interaction below E_T = 71,000 cm^-1. By contrast, the bond dissociation above E_T = 71,000 cm^-1 is due to the intramolecular energy flow between the excited C-H bonds. The probability of C-H_methyl dissociation is higher than that of C-H_ring dissociation.