• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.46 no.8
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• pp.652-661
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• 2018

It is necessary to resolve the absolute velocity as well as Mach number to reflect the high temperature effect in high speed flow. So this region is classified as high enthalpy flows distinguished from high speed flows. Many facilities, such as arc-jet, shock tunnel, etc. has been used to obtain the high enthalpy flows at the ground level. However, it is difficult to define the exact test condition in this type of facilities, because some chemical reactions and energy transfer take place during the experiments. In the present study, a quasi 1D code considering the thermochemical non-equilibrium effect is developed to effectively estimate the test condition of a shock tunnel. Results show that the code gives reasonable solution compared with the results from the known experiments and 2D axisymmetric simulations.

• Steel and Composite Structures
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• v.39 no.1
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• pp.51-64
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• 2021

This paper presents a high-order shear and normal deformation theory for the bending of FGM plates. The number of unknowns and governing equations of the present theory is reduced, and hence makes it simple to use. Unlike any other theory, the number of unknown functions involved in displacement field is only four, as against five or more in the case of other shear and normal deformation theories. Based on the novel shear and normal deformation theory, the position of neutral surface is determined and the governing equilibrium equations based on neutral surface are derived. There is no stretching-bending coupling effect in the neutral surface-based formulation, and consequently, the governing equations of functionally graded plates based on neutral surface have the simple forms as those of isotropic plates. Navier-type analytical solution is obtained for functionally graded plate subjected to transverse load for simply supported boundary conditions. The accuracy of the present theory is verified by comparing the obtained results with other quasi-3D higher-order theories reported in the literature. Other numerical examples are also presented to show the influences of the volume fraction distribution, geometrical parameters and power law index on the bending responses of the FGM plates are studied.

• Journal of Microbiology and Biotechnology
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• v.11 no.4
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• pp.649-655
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• 2001

The kinetics of the thermolysin-catalyzed synthesis of N-(benzyloxycarbonyl)-L-phenylalanyl-L-leucine ethyl ester (Z-Phe-LeuOEt) from N-(benzyloxycarbonyl)-L-phyenylalanine (Z-Phe) and L-leucine ethyl ester (LeuOEt) in an ethyl acetate saturated aqueous system in a batch operation were studied. The kinetics for the synthesis of Z-Phe-LeuOEt were expressed using a rate equation for the rapid equilibrium random bireactant mechanism. The four kinetic constants involved in the rate equation were determined numerically by the quasi-Newton method so as to fit the calculated results with the experimental data. Within the pH and temperature range examined, the $K_{cat}$ value for the synthesis of Z-Phe-LeuOEt reached a maximum at pH 7.0 and $45^{\circ}C$, whereas the affinity between Z-Phe and thermolysin reached a maximum at pH 6.0 adn $40^{\circ}C$. The inhibitory effect of Z-Phe on the condensation reaction decreased as the pH and temperature decreased. In contrast, they affinity between LeuOEt and thermolysin remained unchanged within the pH and temperature range examined. Therefore, it was concluded that the protonation state of the carboxyl groups. of Z-Phe was more imprtant than that of the amono groups of LeuOEt for the synthesis of Z-Phe-LeuOEt in the present solvent system. The equilibrium yield at pH 6.0 and $30^{\circ}C$ was 8% higher than that at pH 7.0 and $40^{\circ}C$, although the rate was much slower. This result suggested that the affinity between the enzyme and the substrate rather than the overall rate was a more important factor affecting the equilibrium yield, when the peptide synthesis was carried out in a product-precipitation system.

• Journal of Advanced Research in Ocean Engineering
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• v.4 no.1
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• pp.25-34
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• 2018

In this study, the behavior of the coupled mooring system and floating body is analyzed. The related works are introduced for the mooring analysis of the floating body. Equations motion are introduced for calculating mooring force connected with the floating body. For formulating the equations of motion, the concept of the constrained force is applied for compact expression of it. The input and output data of the module for calculating mooring force is defined. The static analysis and quasi-static analysis are performed. For the analysis, equilibrium equation for elastic catenary mooring line is used by employing finite element method, and the C# solver is developed in this research. The analysis results are validated by comparing with other research results.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 1998.10b
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• pp.10-10
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• 1998

The growth process of solid grains in a liquid matrix is usually explained in tem1S of Ostwald ripening. The variation of growth (dissolution) rate as a function of grain size during Ostwald ripening predicted that the dissolution rate becomes very large as grain size decreases but the growth rate of a large grain is rather limited. Therefore. a rather uniform size distribution of grain size is maintained once after the quasi-equilibrium state is reached. Quite frequently, however, the exaggerated grain growth (EGG) is observed to occur: only a limited number of grains grow exceptionally. From the observation that the EGG occurs only for the faceted grains with apparently straight solid-liquid interfaces, the EGG is suggested to be the consequence of growth process controlled by 2-dimensional nucleation. In this study, the result by computer calculation on the grain growth process controlled by various mechanisms will be given.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.341-341
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• 2006

Nanofishing enabled us to stretch a single polymer chain with picking it at its two modified termini using atomic force microscope (AFM). Stress-strain curves obtained to date had been the result on slow pulling events and therefore observed phenomena had been interpreted as quasi-static responses. In this study, we extended the capability of nanofishing to the phenomena far from equilibrium state by giving much faster pulling speeds. We could observe a momental increase entanglement and a successive stress relaxation.

• Journal of the Korea Institute of Military Science and Technology
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• v.3 no.1
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• pp.198-206
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• 2000

The transmission load of gear devices is important factor in the design of gear system. To design gear system precisely, an analysis and calculation methods for transmission load of gears are demanded. The purpose of this study is to develop a computer program for analyzing tooth load sharing of a spur gear system by means of the contact theory. In this paper, load transmission characteristics is identified with elastic contact problem which is assumed to quasi-static equilibrium. The modeling of spur gear tooth is accomplished by application of I-DEAS.

• Ocean and Polar Research
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• v.26 no.3
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• pp.515-521
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• 2004

The processes of formation and dissociation of gas hydrates were investigated by monitoring pressure and temperature variations in a pressure cell in order to understand the kinetic behavior of gas hydrate and the controlling factors fur the phase transition of gas hydrate below freezing. Gas hydrates were made kom guest gases ($CH_4,\;CO_2$, and their mixed-gas) and fine ice powder. We found that formation and dissociation speeds of gas hydrates were not controlled by temperature and pressure conditions alone. The results of this study suggested that pressure levels at the formation of mixed-gas hydrate determine the transient equilibrium pressure itself.

• Proceedings of the KSME Conference
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• 2001.11b
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• pp.670-675
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• 2001

This paper describes aerodynamic preliminary design performance prediction and flow analysis for turbine of the marine middle engine turbocharger. The performance characteristics of turbocharger turbine are investigated at various operating conditions using mass flow rate and computational flow analysis for rotor and nozzle at design point are performed. Preliminary design results are performed by applying mean line and radial equilibrium theory. Performance prediction and flow analysis results show good agreement with experiments. From 3 dimensional flow analysis result, efficiency is 0.6% greater than design point. Therefore, this design approach is useful for preliminary design, and helps to increase the design capability for optimized rotor blade.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2301-2305
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• 2011

The potential energy surface (PES) for the loss of HCN or HNC from the pyrazine molecular ion was determined based on quantum chemical calculations using the G3//B3LYP method. Four possible dissociation pathways to form four $C_3H_3N^{+{{\bullet}}$ isomers were examined. A Rice-Ramsperger-Kassel-Marcus quasi-equilibrium theory model calculation was performed to predict the dissociation rate constant and the product branching ratio on the basis of the obtained PES. The resultant rate constant for the HCN loss agreed with the previous experimental result. The kinetic analysis predicted that the formation of $CH=CHN{\equiv}CH^{+{\bullet}}+HCN$ was predominant, which occurred by three consecutive steps, a C-C bond cleavage to form a linear intermediate, a rearrangement to form an H-bridged intermediate, and elimination of HCN.