• Title/Summary/Keyword: quartz vein

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Mineralogy and Geochemistry of Carbonate Minerals from the Olon Ovoot Gold Mine, Mongolia (몽골 Olon Ovoot 금 광산에서 산출되는 탄산염광물의 산출상태 및 화학조성)

  • Yoo, Bong Chul;Tungalag, Naidansuren;Sereenen, Jargalen;Heo, Chul-Ho;Ko, Sang-Mo
    • Economic and Environmental Geology
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    • v.47 no.2
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    • pp.181-191
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    • 2014
  • Olon Ovoot gold mine, Mongolia, is located in the Omnogobi province which is south 500 km from Ulaanbaatar. The mine area consists of the Devonian Bot-Uul khudag formation, the Upper Devonian intrusions, and the Upper Devonian or the Early Jurassic quartz veins. The quartz veins contain from 1 to 32 g/t gold with an average of 5 g/t gold. The quartz veins vary from 0.2 m to 25 m and are concordant or discordant with foliation of the green-schist. The mineralogy of the quartz veins is simple and consists of mainly of white massive quartz with partly transparent quartz in cavity. Quartz, sericite, chlorite, pyrite and carbonates(ankerite, dolomite and siderite) were observed in the alteration zone. Carbonate minerals occur as disseminated, coarse or fine grains with quartz, sericite, chlorite and pyrite near vein margin or within wall-rock xenoliths in quartz vein. Ankerite is present as later dark grey ankerite(13.51 to 16.89 wt.% FeO) and early white grey ankerite(16.67 to 19.90 wt.% FeO). The FeO contents of early ankerite are higher than those of later ankerite. Dolomite contains from 3.89 to 10.44 wt.% FeO and from 0.10 to 0.47 wt.% MnO. Dolomite is present as dark grey dolomite(4.06 to 6.87 wt.% FeO), light white grey dolomite(6.74 to 7.58 wt.% FeO) and grey white dolomite(7.33 to 10.44 wt.% FeO). The FeO contents of white grey dolomite are higher than those of dark grey dolomite. Siderite contains from 34.25 to 48.66 wt.% FeO, from 6.79 to 14.38 wt.% MgO, from 0.06 to 0.26 wt.% MnO and from 2.08 to 8.08 wt.% CaO.

Hydrothermal Gold Mineralization of the Sambo Deposit in the Muan Area, Korea (무안 지역, 삼보 광상의 금광화작용)

  • Pak, Sang-Joon;Choi, Seon-Gyu
    • Economic and Environmental Geology
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    • v.41 no.3
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    • pp.275-286
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    • 2008
  • The Sambo gold deposit located nearby the Cretaceous Hampyeong basin is composed of gold quartz fine vein(the Jija vein) within Cretaceous rhyolite showing $N10{\sim}20W$ trends as well as $N5{\sim}10E$ trending quartz veins(the Pungja, Gwangsan and Pungjaji veins) in Precambrian gneiss. The gold vein typically displays the intermittent and irregular fine veins within rhyolite. Electrum is disseminated in wallrock along the fine cracks as well as coexists with hematite replacing pyrite. Ore-forming fluids from the mineralized vein($H_2O/-NaCl$ system, Th; $340{\sim}200^{\circ}C$, Salinity <2.7 eq. wt.% NaCl) and NE-trending veins($H_2O-NaCl/-CO_2$ system, Th; $400{\sim}190^{\circ}C$, salinity <7.9 eq. wt.% NaCl) are featured by dissimilar physicochemical conditions but their fluid evolution trends(boiling and mixing) are similar with each other. Gold veins of the Sambo deposit filled along NNW-trending tension crack are related to pull-apart basin evolution. Selective gold mineralization of the deposit reflect to dissimilarity between two ore-forming fluid sources. Consequently, gold veining of the Sambo deposit formed at shallow-crustal level and could be categorized into epithermal-type gold deposit related to tensional fractures filling triggered by Cretaceous geodynamics.

Genetic Environments of Au-Ag-bearing Gasado Hydrothermal Vein Deposit (함 금-은 가사도 열수 맥상광상의 성인)

  • Ko, Youngjin;Kim, Chang Seong;Choi, Sang-Hoon
    • Economic and Environmental Geology
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    • v.55 no.1
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    • pp.53-61
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    • 2022
  • The Gasado Au-Ag deposit is located within the south-western margin of the Hanam-Jindo basin. The geology of the Gasado is composed of the late Cretaceous volcaniclastic sedimentary rocks and acidic or intermediate igneous rocks. Within the deposit area, there are a number of hydrothermal quartz and calcite veins, formed by narrow open space filling along subparallel fractures in the late Cretaceous volcaniclastic sedimentary rock. Vein mineralization at the Gasado is characterized by several textural varieties such as chalcedony, drusy, comb, bladed, crustiform and colloform. The textures have been used as exploring indicators of the epithermal deposit. Mineral paragenesis can be divided into two stages (stage I, ore-bearing quartz veins; stage II, barren carbonate veins) considering major tectonic fracturing event. Stage I, at which the precipitation of Au-Ag bearing minerals occurred, is further divided into three substages (early, middle and late) with paragenetic time based on minor fractures and discernible mineral assemblages: early, marked by deposition of pyrite and pyrrhotite with minor chalcopyrite, sphalerite and electrum; middle, characterized by introduction of electrum and base-metal sulfides with minor argentite; late, marked by argentite and native silver. Au-Ag-bearing mineralization at the Gasado deposit occurred under the condition between initial high temperatures (≥290℃) and later lower temperatures (≤130℃). Changes in stage I vein mineralogy reflect decreasing temperature and fugacity of sulfur (≈10-10.1 to ≤10-18.5atm) by evolution of the Gasado hydrothermal system with increasing paragenetic time. The Gasado deposit may represents an epithermal gold-silver deposit which was formed near paleo-surface.

Element Dispersion and Wall-rock Alteration from Daebong Gold-silver Deposit, Republic of Korea (대봉 금-은광상의 모암변질과 원소분산 특성 연구)

  • Yoo, Bong-Chul;Chi, Se-Jung;Lee, Gil-Jae;Lee, Jong-Kil;Lee, Hyun-Koo
    • Economic and Environmental Geology
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    • v.40 no.6
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    • pp.713-726
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    • 2007
  • The Daebong deposit consists of gold-silver-bearing mesothermal massive quartz veins which fill fractures along fault zones($N10{\sim}20^{\circ}W,\;40{\sim}60^{\circ}SW$) within banded gneiss or granitic gneiss of Precambrian Gyeonggi massif. Ore mineralization of the deposit is composed of massive white quartz vein(stage I) which was formed in the same stage by multiple episodes of fracturing and healing and transparent quartz vein(stage II) which is separated by a major faulting event. The hydrothermal alteration of stage I is sericitization, chloritization, carbonitization, pyritization, silicification and argillization. Sericitic zone occurs near and at quartz vein and includes mainly sericite, quartz, and minor illite, carbonates and epidote. Chloritic zone occurs far from quartz vein and is composed of mainly chlorite, quartz and minor sericite, carbonates and epidote. Fe/(Fe+Mg) ratios of sericite and chlorite range 0.36 to 0.59($0.51{\pm}0.10$) and 0.66 to 0.73($0.70{\pm}0.02$), and belong to muscovite-petzite series and brunsvigite, respectively. Calculated $Al_{IV}-Fe/(Fe+Mg)$ diagrams of sericite and chlorite suggest that this can be a reliable indicator of alteration temperature in Au-Ag deposits. Calculated activities of chlorite end member are $a3(Fe_5Al_2Si_3O_{10}(OH){_6}=0.00964{\sim}0.0291,\;a2(Mg_5Al_2Si_3O_{10}(OH){_6}= 9.99E-07{\sim}1.87E-05,\;a1(Mg_6Si_4O_{10}(OH){_6}=5.61E-07{\sim}1.79E-05$. It suggest that chlorite from the Daebong deposit is iron-rich chlorite formed due to decreasing temperature from $T>450^{\circ}C$. Calculated $log\;{\alpha}K^+/{\alpha}H^+,\;log\;{\alpha}Na^+/{\alpha}H^+,\;log\;{\alpha}Ca^{2+}/{\alpha}^2H^+$ and pH values during wall-rock alteration are $4.6(400^{\circ}C),\;4.1(350^{\circ}C),\;4.0(400^{\circ}C),\;4.2(350^{\circ}C),\;1.8(400^{\circ}C),\;4.5(350^{\circ}C),\;5.4{\sim}6.5(400^{\circ}C)\;and\;5.1{\sim}5.5(350^{\circ}C)$, respectively. Gain elements (enrichment elements) during wallrock alteration are $K_2O,\;P_2O_5,\;Na2O$, Ba, Sr, Cr, Sc, V, Pb, Zn, Be, Ag, As, Ta and Sb. Elements(Sr, V, Pb, Zn, As, Sb) represent a potentially tools for exploration in mesothermal and epithermal gold-silver deposits.

Cu-Pb-Zn Mineralization of the Cheongsong Mine (청송광산의 동-연-아연 광화작용)

  • Lee, Hyun Koo;Kim, Sang Jung
    • Economic and Environmental Geology
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    • v.30 no.3
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    • pp.197-207
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    • 1997
  • Rocks in the Cheongsong mine area consist of Precambrian gneiss, Cretaceous sedimentry rocks and late Cretaceous quartz porphyry. The Cheongsong deposit is composed of many hydrothermal quartz veins of strikes $N30^{\circ}{\sim}60^{\circ}W$, dips $60{\sim}85^{\circ}E$ which fill WNW fault system. Pyrite and hematite occur within transparent quartz near margins of early stage II, and milky quartz of middle stage II coexists with sphalerite, chalcopyrite and galena coexisting with Cu-Pb-Bi minerals in center part of stage II quartz veins. Stage III calcite vein filled cracks or fractures of earlier quartz veins contains native copper and chalcopyrite. Supergene minerals are chalcocite, covellite, malanchite and chrysocolla. Alteration minerals are sericite, chlorite, argillite, epitode and pyrite. Ranges of salinities and homogenization temperatures for fluid inclusions in the individual periods of stage II are: 3.7 to 7.8 wt.% eq. NaCl and 200 to $380^{\circ}C$ in transparent quartz of early stage II; 0.7 to 6.4 wt.% eq. NaCl and 200 to $320^{\circ}C$ in milky quartz of middle stage II; 0.0 to 0.9 wt.% eq. NaCl and 250 to $320^{\circ}C$ in calcite of late stage II. Those of stage III calcite range about 0 wt.% eq. NaCl, and from 140 to $260^{\circ}C$, respectively. The relationship between salinities and temperatures shows decrease tendency with paragenetic time from stage II to III. The ${\delta}^{18}O_{H_2O}$ value is 0.5‰ in stage I, range from 0.5 to -0.4‰ in stage II, and from -3.2 to -3.7‰ in stage III. Calcite in the stage II and stage III has ${\delta}^{13}C$ values of -5.0‰ and -4.5 to -4.9‰, respectively. There is a decrease in sulfur fugacity values with paragenetic time of stage II, from $10^{-6.3}$ atm for early mineralization, to $10^{-6.5}$ atm for middle stage, to $10^{-8.0}$ atm for late mineralization of stage II. The results of stable isotope and fluid inclusion indicate that ore fluids reacted with meteoric water and wall rock in the Cheongsong hydrothermal system.

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Occurrence and Chemical Composition of Ti-bearing Minerals from Samgwang Au-ag Deposit, Republic of Korea (삼광 금-은 광상에서 산출되는 함 티타늄 광물들의 산상 및 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.195-214
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    • 2020
  • The Samgwang Au-Ag deposit has been one of the largest deposits in Korea. The deposit consists of eight lens-shaped quartz veins which filled fractures along fault zones in Precambrian metasedimentary rock, which feature suggest that it is an orogenic-type deposit. The Ti-bearing minerals occur in wallrock (titanite, ilmenite and rutile) and laminated quartz vein (rutile). They occur minerals including biotite, muscovite, chlorite, white mica, monazite, zircon, apatite in wallrock and white mica, chlorite, arsenopyrite in laminated quartz vein. Chemical composition of titanite has maximum vaules of 3.94 wt.% (Al2O3), 0.49 wt.% (FeO), 0.52 wt.% (Nb2O5), 0.46 wt.% (Y2O3) and 0.43 wt.% (V2O5). Titanite with 0.06~0.14 (Fe/Al ratio) and 0.06~0.15 (XAl (=Al/Al+Fe3++Ti)) corresponds with metamorphic origin and low-Al variety. Chemical composition of ilmenite has maximum values of 0.07 wt.% (ZrO2), 0.12 wt.% (HfO2), 0.26 wt.% (Nb2O5), 0.04 wt.% (Sb2O5), 0.13 wt.% (Ta2O5), 2.62 wt.% (As2O5), 0.29 wt.% (V2O5), 0.12 wt.% (Al2O3) and 1.59 wt.% (ZnO). Chemical composition of rutile in wallrock and laminated quartz vein has maximum values of 0.35 wt.%, 0.65 wt.% (HfO2), 2.52 wt.%, 0.19 wt.% (WO3), 1.28 wt.%, 1.71 wt.% (Nb2O3), 0.03 wt.%, 0.07 wt.% (Sb2O3), 0.28 wt.%, 0.21 wt.% (As2O5), 0.68 wt.%, 0.70 wt.% (V2O3), 0.48 wt.%, 0.59 wt.% (Cr2O3), 0.70 wt.%, 1.90 wt.% (Al2O3) and 4.76 wt.%, 3.17 wt.% (FeO), respectively. Rutile in laminated quartz vein is higher contents (HfO2, Nb2O3, As2O5, Cr2O3, Al2O3 and FeO) and lower content (WO3) than rutile in wallrock. The substitutions of rutile in wallrock and laminated quatz vein are as followed : rutile in wallrock [(Fe3+, Al3+, Cr3+) + Hf4+ + (W5+, As5+, Nb5+) ⟵⟶ 2Ti4+ + V4+, 2Fe2+ + (Al3+, Cr3+) + Hf4+ + (W5+, As5+, Nb5+) ⟵⟶ 2Ti4+ + 2V4+], rutile in laminated quartz vein [(Fe3+, Al3+) + As5+ ⟵⟶ Ti4+ + V4+, (Fe3+, Al3+) + As5+ ⟵⟶ Ti4+ + Hf4+, 4(Fe3+, Al3+) ⟵⟶ Ti4+ + (W5+, Nb5+) + Cr3+], respectively. Based on these data, titanite, ilmenite and rutile in wallrock were formed by resolution and reconcentration of cations (W5+, Nb5+, As5+, Hf4+, V4+, Cr3+, Al3+, Fe3+, Fe2+) in minerals of wallrock during regional metamorphism. And then rutile in laminated quartz vein was formed by reconcentration of cations (Nb5+, As5+, Hf4+, Cr3+, Al3+, Fe3+, Fe2+) in alteration minerals (white mica, chlorite) and Ti-bearing minerals reaction between hydrothermal fluid originated during ductile shear and Ti-bearing minerals (titanite, ilmenite and rutile) in wallrock.

Oxygen Isotope Study of Mulgeum, Yangseong, Maeri and Kimhae Iron Ore Deposits in Gyeongnam Province, Korea

  • Woo, Young-Kyun;Savin, Samuel M.
    • Journal of the Korean earth science society
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    • v.23 no.1
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    • pp.97-104
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    • 2002
  • Mulgeum, Yangseong, Maeri and Kimhae iron ore deposits in Gyeongnam Province are hydrothermal skarn type magnetite ore deposits in propylitized andesitic rock near the contact with Cretaceous Masanite. Symmetrical zoned skarns are commonly developed around the magnetite veins. The skarn zones away from the vein are quartz-garnet skarn, epidote skarn and epidote-orthoclase skarn. Oxygen isotope analyses of coexisting minerals from andesitic rock, Masanite and major skarn zones, and of magnetite, hematite and quartz were conducted to provide the information on the formation temperature, the origin and the evolution of the hydrothermal solution forming the iron ore deposits. Becoming more distant from the ore vein, temperatures of skarn zones represent the decreasing tendency, but most ${\delta}^{18}O$ and ${\delta}^{18}O_{H2O}$ values of skarn minerals represent no variation trend, and also the values are relatively low. Judging from all the isotopic data from the ore deposits, the major source of hydrothermal solution altering the skarn zones and precipitating the ore bodies was magmatic water derived from the deep seated Masanite. This high temperature hydrothermal solution rising through the fissures of propylitized andesitic rock was mixed with some meteoric water, and occurred the extensive isotopic exchange with the propylitized andesitic rock, and formed the skarns. During these processes, the temperature and ${\delta}^{18}O_{H2O}$ value of hydrothermal solution were lowered gradually. At the main stage of iron ore precipitation, because all the alteration was already finished, the new rising hydrothermal solution formed only the magnetite ore without oxygen isotopic exchange with the wall rock.

Gold and Silver Mineralization in the Yonghwa Mine (용화광산(龍化鑛山)의 금은광화작용(金銀鑛化作用))

  • Youn, Seok-Tai;Park, Hee-In
    • Economic and Environmental Geology
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    • v.24 no.2
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    • pp.107-129
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    • 1991
  • The Yonghwa gold-silver deposits are emplaced along $N15^{\circ}{\sim}25^{\circ}W$ trending fissures in middle Cretaceous porphyritic granite or Precambrian Sobaegsan gneiss complex. The results of paragenetic studies suggest that vein filling can be subdivided into four identifiable stages; state I: the main sulfide stage, characterized by base-metal sulfide minerals, iron oxides and minor electrum, stage II: electrum stage, stage III: electrum and silver-bearing sulfosalts stage, stage IV: post ore stage of carbonates and quartz. The ore mineralogy suggests that depositional temperature of the formation of the gold and silver minerals are estimated as 200 to $250^{\circ}C$ and 140 to $180^{\circ}C$, respectively. Sulfur fugacity of the formation of the gold and silver minerals are estimated as $10^{-14.0}$ to $10^{-12.2}$ atm and $10^{-18.5}$ to $10^{-17.2}$ atm, respectively. A consideration of the pressure regime during ore deposition bases on the fluid inclusion evidence of boiling suggests lithostatic pressure of less than 180 bars. This range of pressure indicate that vein system lay at depth of 700m below the surface at the time during mineralization. Salinities of ore-bearing fluids range from 0.4 to 6.9 wt.% equivalent NaCl. The sulfur and carbon isotopic data reveal that these elements were probably derived from a deep-seated source. The ${\delta}^{18}O$ of the hydrothermal fluid was determined from ${\delta}^{18}O$ values of quartz and calcite. Oxygen and hydrogen isotopic studies reveal that meteoric water dominate over ore-bearing fluid.

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Occurrence of Gold Deposits of the Tumbang Lapan Area of the Middle Kalimantan, Indonesia (인도네시아 중부 칼리만탄 뚬방라판 지역 금광상의 산상)

  • Kim In-Joon
    • Economic and Environmental Geology
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    • v.38 no.3 s.172
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    • pp.347-353
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    • 2005
  • The geology of the Tumbang Lapan area consists of Permian to Carboniferous metamorphic rocks, Cretaceous granitic rocks, and Permian to Tertiary sedimentary and volcanic rocks. Three faults are developed in surveyed area, and are functioned as channels of the hydrothermal solution which farmed quartz veins within tuff3. In the mineralized area, argillic and propylitic alterations are dominant. Argillic altered rocks show the alteration mineral assemblages of kaolinte+sericite+quartz+chlorite+pyrite. Mineral association in propylitic alteration is chlorite+epidote+feldspar+quartz+pyrite+ magnetite. Vein type, fracture filling, stockwork are observed in survey area. As a result of analysis of samples from quartz veins and altered rocks, some mineralized rocks showed $0.01\~4.6g/t$ of gold.

Geology and Ore Deposits of Kubong Gold Mine (구봉광산(九峯鑛山)의 지질(地質)과 광상(鑛床))

  • Cheon, Chan Kyu;Oh, Mihn Soo
    • Economic and Environmental Geology
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    • v.3 no.3
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    • pp.169-176
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    • 1970
  • Kubong Gold Mine is located in Kuryongri, Sayang-myun, Chungyang-gun, Choongchung-Namdo.(latitude $36^{\circ}24^{\prime}N$. longitude $126^{\circ}45^{\prime}30^{{\prime}{\prime}}E$) The mine was begun to work soon after the inhabitants of this village had accidently discovered the outcrops in April 1908. It is one of the largest gold mines in Korea which produces 4,500 tons of crude ore a month. The geology in the area consists of granitic gneiss, banded gneiss, augen-gneiss, mica schist, limesilicate of Pre-Cambrian series and sedimentary rocks(sandstones & conglomerates) of Daedong series. Basic dikes intrude the former formations. The country rock of the ore deposit is a group of the metamorphic rocks mentioned above. Gold-silver bearing quartz vein contains small amounts of pyrite, chalcopyrite, arsenopyrite, galena and sphalerite in which gold and silver occur as native state. The vein strikes $N30^{\circ}{\sim}60^{\circ}E$ and dips $20^{\circ}{\sim}50^{\circ}S$ and the average width of the vein is estimated 1 to 1.5m. Average grade of ore is Au:6~8gr/t and Ag:5~6gr/t. The ore shoot continues from the outcrop to the depth of -1760ML with dip of $20{\sim}25^{\circ}$ and strike extension reaches to 400m at the depth of -1440 ML and to more or less 200m at below. Highgrade of ore vein was found at the lowest level of the ore shoot at the time of recent field survey at the end of August 1970. Its average grade was estimated as Au:20gr/t and its width 1~2.5M in average. A series of futher prospecting for other new ore shoot or parallel veins are urgent and crosscut prospecting along the horizontal level is strongly recommended.

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