• Applied Biological Chemistry
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• v.9
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• pp.153-159
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• 1968

In this paper the auther investigated the chemical properties, process of humification and type of humic acid in soils which were reclaimed by farming for cultivation in Kangwondo. The results obtained in this studies were summarized as follows: 1. General chemical components of these soil were similar to the ordinary soil but C.E.C. and humus contents were found much more 2. Humic acid and fulvic acid which were extracted with NaOH from soil were greater than those of Na-pyrophosphate(Na-p.) and NaF. Hmus contents and PQ% were increased much more in the upper layer than in the lower layer. 3. Degree of humification of humic acid extracted with NaOH. was very similar to those extracted with Na-pyrophosphate. Humification degree of humic acid extracted with NaF was lower than humic acid which were extracted with NaOH and Na-pyrophosphate. But humification degree of humic acid extracted with NaOH was similar to that with Na-pyrophosphate. Humic acid in B soil and the upper layer was higher than A, C soil and the lower layer of soil, in humification degree. 4. Humic acids extracted with NaOH and Na-pyrophosphate from soil were fractionated by Mg into two parts ${\alpha}$ type and ${\beta}$ type humic acid. Humic acids of ${\alpha}$ and ${\beta}$ type extracted with NaOH were higher than these of Na-pyrophosphate in humification degree. In this soil the humification degree of humic acid was not changed during the period of cultivation. 5. ${\alpha}$, ${\beta}$ type humic acid extracted with NaOH were very similar to the humic acid extracted with Na-pyrophosphate in shapes of absorption curves.

• Korean Journal of Food Science and Technology
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• v.30 no.5
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• pp.1040-1044
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• 1998

Tetrasodium pyrophosphate peroxidate can be crystallized as a hydrogen-peroxide-bound salt from the solution of tetrasodium pyrophosphate and hydrogen peroxide. The antimicrobial activity and stability of the compound were tested for the use as a food preservative. It showed antimicrobial activities against several food spoilage microorganisms at the concentration of 0.1% (w/v), and was stable for 80 days in room temperature as a form of 70% hydrogen-peroxide-bound tetrasodium pyrophosphate peroxidate. It was also stable at the boiling temperature but decomposed significantly in the presence of metal ions. The compound can be an effective food preservative at the 0.2% (w/v) concentration, which contains 0.03% (v/v) hydrogen peroxide. The compound could be commercialized if the application area and usage direction as well as the removal method of hydrogen peroxide were developed.

• Korean Journal of Food Science and Technology
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• v.21 no.4
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• pp.549-555
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• 1989

The effect of high temperature aging on the meat tenderness improvement was studied, and also the effect of salt, pyrophosphate and succinic anhydride on binding characteristics of restructed beef were compared. At high temperature aging, shear force value decreased and myofibrillar fragmentation index increased as the aging progressed. From the electronic microscopic observation, the morphological change of myofibril appeared much faster when the meat was aged at high temperature. Added salt increased TBA values and rupture strength while reducing cooking loss. Increase in pyrophosphate decreased rooking loss and Increased rupture strength and TBA value. When salt and pyrophosphate were combined, the effects were somewhat additive. Added succinic anhydride increased cooking loss and hardness and decreased color rating, acceptability rating and adhesiveness, but cohessiveness was not significantly different from control group containing salt and pyrophosphate. The results suggest that high temperature aging have greater improving effect of meat tenderness of Korean native male cattle compared to low temperature aging and addition of succinic ahydride in combination with salt and pyrophosphate reduce binding ability of restructured beef.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2012.11a
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• pp.136-136
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• 2012

Cu 박막이 pyrophosphate baths로부터 전기도금공정에 의해 제조되었으며, 전류밀도 및 도금온도가 Cu 박막의 특성에 미치는 영향을 조사하였다. 전류 밀도 및 도금온도 모두 전류효율, 잔류응력, 표면형상, 미세조직에 상당한 영향을 미쳤음을 알 수 있었다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2008.11a
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• pp.99-100
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• 2008

전기도금 방법은 많은 장점(낮은 증착온도, 두께 조절용이, 낮은 제조비용, 빠른 증착속도, 복잡한 형상의 물체 증착 가능 등)을 가지고 있으며 현재 FPCB의 소재인 FCCL을 제조 하는데 핵심 공정으로 많이 사용되고 있다. Sulfate 및 Pyrophosphate 용액으로부터 Cu 박막/후막을 제조 하였으며 공정 변수가 최종 도금된 Cu 박막/후막에 미치는 영향을 고찰하였다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.124.1-124.1
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• 2016

In this work, uniform thickness and good adhesion of electrodeposited copper layer were achieved on AZ91 Mg alloy in alkaline noncyanide copper solution containing pyrophosphate ion by employing appropriate zincate pretreatment. Without zincate pretreatment, the electrodeposited copper layer on AZ91 Mg alloy was porous and showed poor adhesion which was explained by small number of nucleation sites of copper due to rapid dissolution of the magnesium substrate in the pyrophosphate solution. The zincate pretreatment was found as one of the most important steps that can form a conducting layer to cover AZ91 surface which decreased the dissolution rate of AZ91 Mg alloy about 40 times in the copper pyrophosphate solution. Electrodeposited copper layer on AZ91 Mg alloy after an appropriate zincate pretreatment showed good adhesion and uniform thickness with bright surface appearance, independent of the deposition time but the surface roughness of the electrodeposited copper layer increased with increasing Cu deposition time.

• 대한핵의학회:학술대회논문집
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• 1975.06a
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• pp.85.2-85.2
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• 1975

• Mass Spectrometry Letters
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• v.2 no.4
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• pp.92-95
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• 2011

Pyrophosphates are the key intermediates in the biosynthesis of isoprenoids, and their concentrations could reveal the benefits of statins in cardiovascular diseases. Quantitative analysis of five pyrophosphates, including isopentenyl pyrophosphate (IPP), dimethylallyl pyrophosphate (DMAPP), geranyl pyrophosphate (GPP), farnesyl pyrophosphate (FPP), and geranylgeranyl pyrophosphate (GGPP), was performed using liquid chromatography-tandem mass spectrometry (LC-MS/MS) in negative ionization mode. After dilution with methanol, samples were separated on a 3 ${\mu}m$ particle multi-modal $C_{18}$ column ($50{\times}2$ mm) and quantified within 10 min. The gradient elution consists of 10 mM ammonium bicarbonate and 0.5% triethylamine (TEA) in water and 0.1% TEA in 80% acetonitrile was used at the flow rate of 0.4 mL/min. Overall recoveries were 51.4-106.6%, while the limit of quantification was 0.05 ${\mu}g$/mL for GPP and FPP and 0.1 ${\mu}g$/mL for IPP, DMAPP, and GGPP. The precision (% CV) and accuracy (% bias) of the assay were 1.9-12.3% and 89.6-111.8%, respectively, in 0.05-10 ${\mu}g$/mL calibration ranges ($R^2$ > 0.993). The devised LC-MS/MS technique with the multi-modal $C_{18}$ column can be used to estimate the biological activity of pyrophosphates in plasma and may be applicable to cardiovascular events with cholesterol metabolism as well as the drug efficacy of statins.

• 대한핵의학회:학술대회논문집
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• 1975.06a
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• pp.85.1-85.1
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• 1975

• 대한핵의학회:학술대회논문집
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• 1979.05a
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• pp.16.1-16.1
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• 1979