• Ocean and Polar Research
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• v.41 no.4
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• pp.265-274
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• 2019

To trace the provenance of fine-grained sediments in response to the growth and retreat of glaciers (i.e., Ross Ice Sheet) that affects the depositional process, various kinds of analyses including magnetic susceptibility, granulometry, and clay mineral composition with AMS ¹⁴C age dating were carried out using a gravity core KI-13-GC2 obtained from the Central Basin of the Ross Sea continental margin. The sediments mostly consist of silty mud to sand with ice-rafted debris, the sediment colors alternate repeatedly between light brown and gray, and the sedimentary structures are almost bioturbated with some faint laminations. Among the fine-grained clay mineral compositions, illite is highest (59.1-76.2%), followed by chlorite (12.4-21.4%), kaolinite (4.1-11.6%), and smectite (1.2-22.6%). Illite and chlorite originated from the Transantarctic mountains (metamorphic rocks and granitic rocks) situated to the south of the Ross Sea. Kaolinite might be supplied from the sedimentary rocks of Antarctic continent underneath the ice sheet. The provenance of smectite was considered as McMurdo volcanic group around the Victoria Land in the western part of the Ross Sea. Chlorite content was higher and smectite content was lower during the glacial periods, although illite and kaolinite contents are almost consistent between the glacial and interglacial periods. The glacial increase of chlorite content may be due to more supply of the reworked continental shelf sediments deposited during the interglacial periods to the Central Basin. On the contrary, the glacial decrease of smectite content may be attributed to less transport from the McMurdo volcanic group to the Central Basin due to the advanced ice sheet. Although the source areas of the clay minerals in the Central Basin have not changed significantly between the interglacial and glacial periods, the transport pathways and delivery mechanism of the clay minerals were different between the glacial and interglacial periods in response to the growth and retreat of Ross Ice Sheet in the Ross Sea.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2008.11a
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• pp.533-537
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• 2008

• Proceedings of the Korean Geotechical Society Conference
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• 1998.10a
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• pp.57-64
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• 1998

• Macromolecular Research
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• v.14 no.2
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• pp.179-186
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• 2006

In the present work, low density polyethylene (LDPE)/aliphatic polyester (APES)/organoclay ternary nanocomposites were prepared. In particular, the effect of a compatibilizer, polyethylene-graft-maleic anhydride (PE-g-MAH), on the morphology and properties of the ternary nanocomposites was investigated. LDPE/APES/organoclay nanocomposites were prepared through melt intercalation method using two different kinds of organoclay. The dispersibility of silicate clays in the nanocomposites was investigated by X-ray diffraction and atomic force microscopy. The ternary nanocomposites showed higher tensile properties than the LDPE/APES blend did. The dispersibility and properties of nanocomposites containing Cloisite 30B were better than those of the nanocomposites containing Cloisite 20A. Unlike Cloisite 20A, hydroxyl groups in the intercalants in Cloisite 30B interlayer underwent a certain polar interaction with the carboxyl group of APES, favoring the intercalation of APES chains and the formation of LDPE/APES/Closite 30B nanocomposites. However, the introduction of the polar hydroxyl groups also enhanced the interaction with the silicate surface at the same time, thereby rendering somewhat difficult the replacement of the surface contacts by LDPE chains, and impeding the extensive intercalation and further exfoliation of Cloisite 30B in the LDPE/APES matrix. The compatibilizer enhanced the intercalation of the polymer chain inside the clay gallery and thus improved the mechanical properties of the ternary nanocomposites. Rheological measurements of the nanocomposites via frequency sweep experiment indicated a certain interaction between the clay platelet and the polymer molecules in the melted state.

• Journal of Soil and Groundwater Environment
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• v.25 no.4
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• pp.77-86
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• 2020

Persulfate-based advanced oxidation processes (AOPs) can oxidize various organic pollutants. In this study, persulfate/Fe(II) system was utilized in phenol removal, and the effect of various organic and inorganic chelators on Fe(II)-medicated persulfate activation was investigated. The feasibility of persulfate/Fe(II)/chelator in cleanup of phenol-contaminated sediment was confirmed through toxicity assessment. In persulfate/Fe(II) conditions, the rate and extent of phenol removal increased in proportion to persulfate concentration. In chelator injection condition, the rate of phenol removal was inversely proportional to chelator concentration when it was injected above optimum ratio. Thiosulfate showed greater chelation tendency with persulfate than citrate and interfered with persulfate access to Fe(II), making the latter a more suitable chelator for enhancing persulfate activation. In contaminated clay sediment condition, 100% phenol removal was obtained within an hour without chelator, with the removal rate increased up to four times as compared to the rate with chelator addition. A clay sediment toxicity assessment at persulfate:Fe(II):phenol 20:10:1 ratio indicated 71.3% toxicity reduction with 100% phenol removal efficiency. Therefore, persulfate/Fe(II) system demonstrated its potential utility in toxicity reduction and cleanup of organic contaminants in sediments.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.6
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• pp.687-695
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• 2020

Micropile is used to improve the stability of existing structures as well as solve various geotechnical problems, such as suppressing slope activity and shearing keys of retaining walls. The existing micropile method has a significantly less capacity to resist a horizontal force than a vertical force0355 Therefore, it is necessary to develop and study an umbrella-type micropile method with excellent seismic performance that can secure seismic performance economically while minimizing structures and ground disturbance areas in the limited space of existing structures. In this study, numerical analysis was performed on the umbrella-type micropile, in which the sloped pile and vertical pile were combined, and the horizontal behavior in soft clay ground during earthquakes was analyzed. Numerical analysis showed that umbrella-type micropile suppresses horizontal displacement in soft ground, and the effect of reducing the horizontal displacement was more pronounced when the embedded depth of the slope pile was 15 m or more. The embedded depth of the micropile and horizontal displacement suppression effect was proportional. Therefore, the umbrella-type micropile has an excellent effect of suppressing horizontal displacement during earthquakes on soft clay ground.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.361-368
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• 2000

In other to examine the compressibility characteristics of cohesive soils in the mouth of the Nakdong river, the oedometer tests were peformed on undisturbed and reconstituted samples obtained by continuous boring typically at 3 different sites. It is meaningful to compare the consolidation behavior of natural clays with a reference state because the natural clays are depending on the stress history, sedimentary environment and geological history. In this study, the insitu state of the Pusan clays was investigated using the concepts of ISL(Nagaraj, 2000) and ICL and SCL(Burland, 1990). And for the purpose of confirming the existence of the underconsolidated clays, a standpipe type piezometer test and a dissipation test by piezocone were performed at their sites. Consequently, the Pusan clays were evaluated as normally consolidated clays.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.23 no.3
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• pp.215-224
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• 1990

Finite element model capable of solving coupled deformation-fluid diffusion equations for the fully saturated porous medium was developed using Galerkin's residual method. This model was used to study the mechanical and hydraulic behaviors of unconsolidated sediment near South Harbor, Pusan. The vertical displacement of top surface clay sediment, when subjected to the external load, is significantly affected by the excessive pore pres- sure buildup and its decay due to the pore fluid diffusion. The sand deposit overlain by the much less permeable clay layer serves as a flow channel. Consequently, the fluid diffusion due to pore pressure difference is significantly facilitated, which also affects the diffusion-dependent sediment deformation.

• Journal of the Korean Geotechnical Society
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• v.24 no.11
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• pp.157-166
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• 2008

To investigate the relationship between compressive strength ($q_u$) of Lightweight Air-mixed soil (LAS) and its physical deformation coefficient ($E_{50}$), a series of unconfined compressive tests have been performed on specimens of LAS according to various dredged soil types by percentage of sand, silt and clay. From the results it was found that the cement content ($C_i$) and unit weight (${\gamma}_m$) are most influence factors on strength, and percentage of sand, silt, clay by grain size analysis (KS F2302) have more effect on compressive strength than other physical properties of soil. It was also found that the rate of strength (a) increases with curing time, but it reduces with the increase of percentage of clay ($C_%$).

• Journal of the Korean GEO-environmental Society
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• v.9 no.1
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• pp.41-46
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• 2008

In this study, the analysis of load transition of PHC pile was performed with the static load test, which was driven in deep soft clay layer of MyungJi site in the western area of Pusan. The results of test showed that the range of unit side resistance of pile in sand layer were $7.4t/m^2$ to $23.3t/m^2$ and $6.4t/m^2$ in the soft clay layer, while the unit base resistance was $955t/m^2$ in dense silty sand layer. To select the most reasonable static bearing capacity formular, the field measured values are compared with the calculated ones from the suggested various formular. In the case of side resistance in sand layer, the suggest formular in the Structural Foundation Design Manual by KGS was most reasonable, while in clay layer Railroad Design Manual.