• Journal of Powder Materials
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• v.15 no.4
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• pp.314-319
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• 2008

Nano-sized tungsten disulfide ($WS_2$) powders were synthesized by chemical vapor condensation (CVC) process using tungsten carbonyl ($W(CO)_6$) as precursor and vaporized pure sulfur. Prior to the synthesis of tungsten disulfide nanoparticles, the pure tungsten nanoparticles were produced by same route to define the optimum synthesis parameters, which were then successfully applied to synthesize tungsten disulfide. The influence of experimental parameters on the phase and chemical composition as well as mean size of the particles for the produced pure tungsten and tungsten disulfide nanoparticles, were investigated.

• Advances in nano research
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• v.2 no.2
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• pp.77-88
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• 2014

Solvothermal treatment of late transition metal acetylacetonates in a novel medium composed either of pure acetophenone or acetophenone mixtures with amino alcohols offers a general approach to uniform hydrophilic metal nanoparticles with high crystallinity and low degree of aggregation. Both pure metal and mixed-metal particles can be accesses by this approach. The produced materials have been characterized by SEM-EDS, TEM, FTIR in the solid state and by Nanoparticle Tracking Analysis in solutions. The chemical mechanisms of the reactions producing nanoparticles has been followed by NMR. Carrying out the process in pure acetophenone produces palladium metal, copper metal with minor impurity of $Cu_2O$, and NiO. The synthesis starting from the mixtures of Pd and Ni acetylacetonates with up to 20 mol% of Pd, renders in minor yield the palladium-based metal alloy along with nickel oxide as the major phase. Even the synthesis starting from a mixed solution of $Cu(acac)_2$ and $Ni(acac)_2$ produces oxides as major products. The situation is improved when aminoalcohols such as 2-aminoethanol or 2-dimethylamino propanol are added to the synthesis medium. The particles in this case contain metallic elements and pairs of individual metals (not metal alloys) when produced from mixed precursor solutions in this case.

• Journal of Powder Materials
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• v.14 no.6
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• pp.362-366
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• 2007

Magnesium and magnesium alloys are promising materials for light weight and high strength applications. In order to obtain homogeneous and high quality products in powder compaction and powder forging processes, it is very important to control density and density distributions in powder compacts. In this study, a model for densification of metallic powder is proposed for pure magnesium. The mode] considers the effect of powder characteristics using a pressure-dependent critical density yield criterion. Also with the new model, it was possible to obtain reasonable physical properties of pure magnesium powder using cold iso-state pressing. The proposed densification model was implemented into the finite element method code. The finite element analysis was applied to simulating die compaction of pure magnesium powders in order to investigate the density and effective strain distributions at room temperature.

• Journal of Powder Materials
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• v.18 no.5
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• pp.411-416
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• 2011

In this study, powder metallurgy and severe plastic deformation by high-pressure torsion (HPT) approaches were combined to achieve both full density and grain refinement at the same time. Water-atomized pure iron powders were consolidated to disc-shaped samples at room temperature using HPT of 10 GPa up to 3 turns. The resulting microstructural size decreases with increasing strain and reaches a steady-state with nanocrystalline (down to ~250 nm in average grain size) structure. The water-atomized iron powders were deformed plastically as well as fully densified, as high as 99% of relative density by high pressure, resulting in effective grain size refinements and enhanced microhardness values.

• International Journal of Concrete Structures and Materials
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• v.3 no.1
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• pp.39-45
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• 2009

The purpose of this study is to establish flexural behavior of high-strength concrete beams confined in the pure bending zone with stirrups. The experiment was carried out on full-scale high-strength reinforced concrete beams, of which the compressive strengths were 40 MPa and 70 MPa. The beams were confined with rectangular closed stirrups. Test results are reviewed in terms of flexural capacity and ductility. The effect of web reinforcement ratio, longitudinal reinforcement ratio and shear span to beam depth ratio on ductility are investigated. The analytic method is based on finite element method using fiber-section model, which is known to define the behavior of reinforced concrete structures well up to the ultimate state and is proven to be valid by the verification with the experimental results above. It is found that confinement of concrete compressive regions with closed stirrups does not affect the flexural strength but results in a significantly increased ductility. Moreover, the ductility tends to increase as the quantity of stirrups increases by reducing the spacing of stirrups.

• Journal of IKEEE
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• v.23 no.2
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• pp.716-721
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• 2019

A novel switching differentiator-based backstepping controller for uncertain pure-feedback nonlinear systems is proposed. Using asymptotically convergent switching differentiator, time-derivatives of the virtual controls are directly estimated in every backstepping design steps. As a result, the control law has an extremely simple form and asymptotical stability of the tracking error is guaranteed regardless of parametric or unstructured uncertainties and unmatched disturbances in the considered system. It is required no universal approximators such as neural networks or fuzzy logic systems that are adaptively tuned online to cope with system uncertainties. Simulation results show the simplicity and performance of the proposed controller.

• Steel and Composite Structures
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• v.31 no.3
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• pp.291-301
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• 2019

Pure torsion loading conditions were not frequently occurred in practical engineering, but the torsional researches were important since it's the basis of mechanical property researches under complex loading. Then a 3D finite element model with precise material constitutive models was established, and the effectiveness was verified with test data. Parametric studies with varying factors as steel yield strength, concrete strength and sectional height-width ratio, were performed. Internal stress state and the interaction effect between encased steel tube and the core concrete were analyzed. Results indicated that due to the confinement effect between steel tube and core concrete, the torsional strength of CFT columns was greatly improved comparing to plain concrete columns. The steel ratio would greatly influence the torque share between the steel tube and the core concrete. Then the torsional strength calculation formulas for core concrete and the whole CFT column were proposed. The proposed formula could be simpler and easier to use with guaranteed accuracy. Related design codes were more conservative than the proposed formula, but the proposed formula presented more satisfactory agreement with experimental results.

• Bulletin of the Korean Chemical Society
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• v.32 no.4
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• pp.1277-1281
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• 2011

Making use of chitosan (CS) and ethylenediaminetetraacetic acid (EDTA) as a reaction system, CS-EDTA nanoparticles were synthesized through a facile counterion complex coacervation method. $Ag^+$ could enter porous CS nanoparticles synthesized with this method, allowing Ag nanoparticles within chitosan nanoparticles were synthesized by reducing silver nitrate with chitosan. Because of the noncovalent interaction between CS and EDTA, the EDTA could be easily removed via dialysis against water, and pure core/shell-type Ag/CS nanoparticles could be obtained. The nanoparticles showed higher antibacterial activity toward E. coli than the active precursor Ag nanoparticles and CS.

• Carbon letters
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• v.25
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• pp.55-59
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• 2018

Carbon chain inserted carbon nanotubes (CNTs) have been experimentally proven having undergone pronounced property change in terms of electrical conductivity compared with pure CNTs. This paper simulates the geometry of carbon chain inserted CNTs and analyzes the mechanism for conductivity change after insertion of carbon chain. The geometric simulation of Pt doped CNT was also implemented for comparison with the inserted one. The results indicate that both modification by Pt atom on the surface of CNT and addition of carbon chain in the channel of the tube are effective methods for transforming the electrical properties of the CNT, leading to the redistribution of electron and thereby causing the conductivity change in obtained configurations. All the calculations were obtained based on density functional theory method.

• Fibers and Polymers
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• v.3 no.2
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• pp.60-67
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• 2002

In the present study, the fluorescence behavior ova phenylethynyl-terminated imide (LaRC PETI-5) resin, a bismaleimide (BMI) resin, and various LaRC PETI-5/BMI blends with different blend compositions has been characterized as a function of heat-treatment temperature, using a steady-state fluorescence technique with a front-face illumination method far solid-state films. It is observed that there are distinguishable changes in the spectral shape, size, and position of fluorescence with varying heat-treatment temperature in the pure and blend samples. The result is qualitatively explained in terms of charge transfer complex formation as well as microenvironmental change with local mobility and viscosity occurring in the LaRC PETI-5, BMI, and their blends during the cure process. The result also implies that a steady-state fluorescence technique may be a useful tool to understand the processing conditions of polyimides and their blends in the film form on the basis of their thermo-photophysical responses.