• Title/Summary/Keyword: pure state

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Development of Cr cold spray-coated fuel cladding with enhanced accident tolerance

  • Sevecek, Martin;Gurgen, Anil;Seshadri, Arunkumar;Che, Yifeng;Wagih, Malik;Phillips, Bren;Champagne, Victor;Shirvan, Koroush
    • Nuclear Engineering and Technology
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    • v.50 no.2
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    • pp.229-236
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    • 2018
  • Accident-tolerant fuels (ATFs) are currently of high interest to researchers in the nuclear industry and in governmental and international organizations. One widely studied accident-tolerant fuel concept is multilayer cladding (also known as coated cladding). This concept is based on a traditional Zr-based alloy (Zircaloy-4, M5, E110, ZIRLO etc.) serving as a substrate. Different protective materials are applied to the substrate surface by various techniques, thus enhancing the accident tolerance of the fuel. This study focuses on the results of testing of Zircaloy-4 coated with pure chromium metal using the cold spray (CS) technique. In comparison with other deposition methods, e.g., Physical vapor deposition (PVD), laser coating, or Chemical vapor deposition techniques (CVD), the CS technique is more cost efficient due to lower energy consumption and high deposition rates, making it more suitable for industry-scale production. The Cr-coated samples were tested at different conditions ($500^{\circ}C$ steam, $1200^{\circ}C$ steam, and Pressurized water reactor (PWR) pressurization test) and were precharacterized and postcharacterized by various techniques, such as scanning electron microscopy, Energy-dispersive X-ray spectroscopy (EDX), or nanoindentation; results are discussed. Results of the steady-state fuel performance simulations using the Bison code predicted the concept's feasibility. It is concluded that CS Cr coating has high potential benefits but requires further optimization and out-of-pile and in-pile testing.

Investigation of gamma radiation shielding capability of two clay materials

  • Olukotun, S.F.;Gbenu, S.T.;Ibitoye, F.I.;Oladejo, O.F.;Shittu, H.O.;Fasasi, M.K.;Balogun, F.A.
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.957-962
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    • 2018
  • The gamma radiation shielding capability (GRSC) of two clay-materials (Ball clay and Kaolin)of Southwestern Nigeria ($7.49^{\circ}N$, $4.55^{\circ}E$) have been investigated by determine theoretically and experimentally the mass attenuation coefficient, ${\mu}/{\rho}(cm^2g^{-1})$ of the clay materials at photon energies of 609.31, 1120.29, 1173.20, 1238.11, 1332.50 and 1764.49 keV emitted from $^{214}Bi$ ore and $^{60}Co$ point source. The mass attenuation coefficients were theoretically evaluated using the elemental compositions of the clay-materials obtained by Particle-Induced X-ray Emission (PIXE) elemental analysis technique as input data for WinXCom software. While gamma ray transmission experiment using Hyper Pure Germanium (HPGe) spectrometer detector to experimentally determine the mass attenuation coefficients, ${\mu}/{\rho}(cm^2g^{-1})$ of the samples. The experimental results are in good agreement with the theoretical calculations of WinXCom software. Linear attenuation coefficient (${\mu}$), half value layer (HVL) and mean free path (MFP) were also evaluated using the obtained ${\mu}/{\rho}$ values for the investigated samples. The GRSC of the selected clay-materials have been compared with other studied shielding materials. The cognizance of various factors such as availability, thermo-chemical stability and water retaining ability by the clay-samples can be analyzed for efficacy of the material for their GRSC.

Solvent Resistance and Gas Permeation Property of PEI-PDMS Hollow Fiber Composite Membrane for Separation and Recovery of VOCs (VOCs의 분리 및 회수를 위한 PEI-PDMS 중공사 복합막의 내용매성 및 기체 투과 특성)

  • Kim, Se-Jong;Lee, Chung-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Rhim, Ji-Won;Choi, Whee-Moon
    • Membrane Journal
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    • v.22 no.1
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    • pp.54-61
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    • 2012
  • To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.

Oxidation Effect on the Critical Velocity of Pure Al Feedstock Deposition in the Kinetic Spraying Process (저온분사 공정에서 알루미늄 분말의 산화가 임계 적층 속도에 미치는 영향)

  • Kang, Ki-Cheol;Yoon, Sang-Hoon;Ji, Youl-Gwun;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.25 no.4
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    • pp.35-41
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    • 2007
  • In kinetic spraying process, the critical velocity is an important criterion which determines the deposition of a feedstock particle onto the substrate. In other studies, it was experimentally and numerically proven that the critical velocity is determined by the physical and mechanical properties and the state of materials such as initial temperature, size and the extent of oxidation. Compared to un-oxidized feedstock, oxidized feedstock required a greater kinetic energy of in-flight particle to break away oxide film during impact. The oxide film formed on the surface of particle and substrate is of a relatively higher brittleness and hardness than those of general metals. Because of its physical characteristics, the oxide significantly affected the deposition behavior and critical velocity. In this study, in order to investigate the effects of oxidation on the deposition behavior and critical velocity of feedstock, oxygen contents of Al feedstock were artificially controlled, individual particle impact tests were carried out and the velocities of in-flight Al feedstock was measured for a wide range of process gas conditions. As a result, as the oxygen contents of Al feedstock increased, the critical velocity increased.

Vaporization and condensation of metallic species in hazardous waste incineration (폐기물 소각시 생성되는 유해 중금속물질의 증발.응축현상에 대한 연구)

  • Song, Yu-Seok;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.6
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    • pp.1983-1993
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    • 1996
  • For selected (pure and compound) metallic species effects of saturation ratio, temperature, particle size and number density on condensation mechanisms are first reviewed. The tendencies for vaporization and condensation differ between metallic species because of the significant differences in their saturation pressures. Then particle pressure of a metal vapor species at incineration temperature is calculated by simplifying waste as a compound of methane, chlorine and small amounts of metals and assuming a thermodynamic equilibrium state. Next the condition is assessed for which supersaturation of combustion gases by the species above the critical level for homogeneous condensation may occur, when the gases contain a large number of pre-existing particles such as entrained ashes. Regardless of the presence of chlorine in the waste, the homogeneous condensation of PbO vapors may occur, depending on number density of the pre-existing particles. However, when chlorine exists in the waste, the homogeneous condensation of PbCl$_2$vapors does not occur, which is similar to the case of Cd and Hg vapors. Thus these highly volatile species, PbCl$_2$, Cd, and Hg, may emit to atmosphere as vapor phase. In general, for reducing the emission of hazardous metallic species into the atmosphere, the number density of pre-existing particles has to be increased. For fixed particle number density, the temperature drop rate must be kept in low if the temperature at which a condensable vapor species emits from a incineration system is fixed, while the temperature drop rate must be kept in high if the residence time for which a condensable species stays in the system is fixed.

Macroscopic Analysis on Supercritical Transition of Liquid Hydrocarbon Fuel (액체탄화수소의 초임계 천이과정에 대한 거시적 특성 분석)

  • Shin, Bongchul;Kim, Dohun;Son, Min;Lee, Keunwoong;Song, Wooseok;Koo, Jaye;Kwon, Oh Chae
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.4
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    • pp.26-33
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    • 2016
  • In order to analyze supercritical transition of liquid hydrocarbon fuel which used propulsion engine, visualization of phase changing using Methylcyclohexane (MCH) was performed. Also, measurements of temperature and pressure were conducted to obtain saturation lines of MCH and Decane. delayed increase of the pressure existed near the critical point due to dramatical increase of specific heats and the critical opalescence was only observed from the end point of delaying to the critical point. Beyond the critical point, the boundary between phases disappeared and the strong density gradient was observed. As the comparison between experimental and numerical saturation lines, the numerical estimation for mixture had relatively little difference while the results of pure components had almost coincidence.

Groundwater Analysis for Jun Stream Basin in Donghae City using MODFLOW (MODFLOW를 이용한 동해시 전천유역의 지하수분석)

  • Kim, Sam Eun;Kim, Hung Soo
    • Journal of Wetlands Research
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    • v.23 no.4
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    • pp.342-351
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    • 2021
  • The objective of this study is to evaluate the change of groundwater and its effect to hydraulic head or parameter sensitivity in order to predict the effect of a new groundwater well using MODFLOW. With the downstream area of the Jun stream basin in the Donghae city, two condition were simulated; (i) First simulation condition is to simulate natural steady-state and the groundwater heads for observation wells are calibrated. After the calibration, existing wells are simulated to find out the pure effect of the next simulation condition, (ii) Secondly, the design wells are planed and simulated for the solution of water shortage problem at Donghae city. As a result of the simulation, the maximum drawdown which is approximately 0.35m occurs in layer 1. This represents that there is no intrusion of salty water and the design plan is acceptable. Finally, the sensitivity analysis of each parameter in MODFLOW is accomplished. We found out that the sensitive parameters are initial head, anisotropic factor, hydraulic conductivity, and general head boundary

The Changes of External Ear Resonance after Surgery for Repair of the Postauricular Meato-Mastoid Cutaneous Fistula (외이도-유양동-귀뒤바퀴피부 누공환자에서 수술 전, 후의 외이도 공명의 변화)

  • Kim, Sangjun;Kang, Myung Koo;Jeong, Sung Wook;Lee, Dong Kun
    • Journal of Clinical Otolaryngology Head and Neck Surgery
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    • v.29 no.2
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    • pp.235-239
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    • 2018
  • Due to the structure with one end closed, the external ear resonance effect in which the high frequency is amplified can be generated, and the sound can be perceived well. The external ear resonance normally has a first peak and a second peak. On average, the first peak has a gain of 18.6 dB at 2620 Hz and the second peak has a gain of 18.2 dB at 4210 Hz. The resonance of the external auditory canal changes with the state of the tympanic membrane, the presence of the ventilation tube, and the structure (length, diameter, shape) of the external auditory canal. A patient with a postauricular meatomastoid cutaneous fistula was admitted to the hospital with a foreign body which is the molding of the hearing aid. After removal of the foreign body, the resonance of the external auditory canal was lost and the subjective sound cognitive ability decreased. In the case of postauricular meatomastoid cutaneous fistula, we confirmed the improvement of sound cognitive ability, the change of pure tone hearing threshold, and the change of the external ear resonance after reconstruction of the ear canal without middle ear reconstruction.

Investigation of amorphous material with ice for cold thermal storage

  • Kim, Jhongkwon;Park, Hyunjun;Bae, Junhyuk;Jeong, Sangkwon;Chang, Daejun
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.1
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    • pp.40-44
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    • 2019
  • This study investigates mixtures of water and cryoprotectant agents (CPAs) to store high-grade cold energy. Although water is an ideal material for a cold thermal storage (CTS) due to its high specific heat, undesirable volume expansion may cause structural stresses during freezing. The volume expansion can be alleviated by adding the CPAs to water. However, the CPA aqueous solutions not only have different thermal properties but also transit to amorphous state different from pure water. Therefore, these characteristics should be considered when using them as material of the CTS. In experiments, glycerol and dimethyl sulfoxide (DMSO) are selected as the candidate CPA. The volume expansion of the solution is measured by an in-situ strain gauge in low temperature region. The specific heat capacity of the solution is also measured by differential scanning calorimetry (DSC). Both the amount of volume expansion and the specific heat capacity of the CPA aqueous solution decrease in the case of higher concentration of CPA. These characteristics should be contemplated to select optimal aqueous solution for CTS for liquid air energy storage system (LAES). The CPA solutions have advantages of having wide temperature range to utilize the latent heat of water and higher sensible heat of the CPA. The CPA solutions which can satisfy the allowable stress of the structure are determined. Consequently, among the CPA solutions investigated, DMSO 20% w/w solution is the most suitable for the CTS.

An Improved Round Reduction Attack on Triple DES Using Fault Injection in Loop Statement (반복문 오류 주입을 이용한 개선된 Triple DES 라운드 축소 공격)

  • Choi, Doo-Sik;Oh, Doo-Hwan;Park, Jeong-Soo;Ha, Jae-Cheol
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.22 no.4
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    • pp.709-717
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    • 2012
  • The round reduction on block cipher is a fault injection attack in which an attacker inserts temporary errors in cryptographic devices and extracts a secret key by reducing the number of operational round. In this paper, we proposed an improved round reduction method to retrieve master keys by injecting a fault during operation of loop statement in the Triple DES. Using laser fault injection experiment, we also verified that the proposed attack could be applied to a pure microprocessor ATmega 128 chip in which the Triple DES algorithm was implemented. Compared with previous attack method which is required 9 faulty-correct cipher text pairs and some exhaustive searches, the proposed one could extract three 56-bit secret keys with just 5 faulty cipher texts.