• Title/Summary/Keyword: pulp slurry

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Pulp Bleaching Effect and Ionization Rate of Chlorine Dioxide by Additives and Various pH Conditions(I)-Ionization of ClO$_2$ and Formation of Chlorate in Pulp Bleaching- (pH와 첨가제에 의한 이산화염소의 분해율 및 펄프표백 효과(1)-표백 중에서 이산화염소의 분해와 Chlorate의 생성-)

  • ;Li Jun Wang
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.3
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    • pp.1-6
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    • 1998
  • Elementally Chlorine Free (ECF) bleaching will be superior than Totally Chlorine free (TCF) bleaching, not only because they have no significant difference in effluent toxicity, but also those pulps bleached by ECF have higher brightness, strength, yield, etc., over those by TCF. With this belief, this paper focused on the chemistry of chlorine dioxide decomposition and ionization, both in water solution and in pulp slurry. Special attention was paid to chlorate ion because there have been controversies as how it is formed and what its behavior to the end pH of pulp bleaching is. As a result, during ionization of chlorine dioxide with water, both chlorate and chlorite were found to increase with increasing pH, but during ionization with pulp, chlorite was found to increase with end pH while chlorate decreased with increasing end pH. In the case of ionization with water, the disproportion equation $2CIO_2 + OH^{-} \lightarrow H_2O + CIO_3^{-} + CIO_2^{-}$ was thought to become the main reaction with the increasing pH, while in the case of ionization with pulp, the reaction $HCIO + CIO_2^{-}\lightarow H^{+} + Cl^{-} + CIO_3^{-}$ was the main reaction contributing to the formation of chlorate. Based on this above opinion, the contrary results of chlorine dioxide ionization from different researchers were discussed and explained.

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Deinking efficiency of ONP with enzyme blended deinking agent (복합탈묵제의 ONP 탈묵 적성)

  • Yun, Kyong-Dong;Park, Heon-Sin;Eom, Tae-Jin
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.04a
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    • pp.167-173
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    • 2006
  • Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently - often much more efficiently. We propose the blended deinking agent with cellulolutic enzymes and synthetic collector in deinking pulp of conventional alkaline method. The deinking efficiency of old news print in alkaline pH was enhanced with enzyme treatments. The brightness of deinked pulp was increased with less residual ink particles and yield of enzymatic deinked pulp was improved compared to the deinked pulp of conventional alkaline method. Enzymes in biomass were use to Chemical Deinking for reduce environment pollution through surfactant and improve surfactants. examining into compatibility Enzymes and surfactants, these new materials are studied efficiency of deinking efficiency.

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Manufacture of Low Density Paper by Cationic Fatty Acid Amine Bulky Promotor Treatment (3) - Effect of Pulp Beating Degree and Bulky Promotor Concentration - (양이온성 지방산아민 벌키화제를 이용한 저밀도 종이 제조 (3) - 펄프 고해도 및 벌키화제 처리 농도에 따른 영향 -)

  • Nam, Yun-Seok;Choi, Kyoung-Hwa;Jin, Hai-Lan;Cho, Jun-Hyung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.111-118
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    • 2016
  • The effects of pulp beating degree and bulky promotor concentration on the properties of handsheet including a bulk and strength have been investigated during manufacturing of low density paper (high bulk paper) with cationic fatty acid bulky promotor. It was found that paper bulk increased with increasing cationic fatty acid bulky agent concentration, while tensile strength decreased. On the other hand the opacity of handseets also increased with increasing cationic fatty acid bulky agent concentration, while brightness decreased slightly. With increasing pulp beating degree, paper bulk as well as tensile strength increased, while opacity decreased. Brightness did not show a significant difference with increasing pulp beating degree. The highest bulk and strength values were observed when 1.5% (SwBKP) and 2% (HwBKP) of bulky promotor was treated into the 450 mL CSF pulp slurry.

Studies on the Adsorption of Cationic Starches onto BCTMP, BKP and Talc and Their Responses to Compozil System(I)-Adsorption Characteristics of Cationic Starches (BCTMP, BKP 및 활석의 양성전분 흡착특성과 콤포질 시스템에 대한 거동 연구 (제1보)-양성전분의 흡착특성-)

  • 이학래;허동명
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.45-52
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    • 1997
  • This study was carried out to investigate the adsorption characteristics of cationic starches onto BKP, BCTMP and talc. Concentration of the unadsorbed cationic starch contained in the supernatant of the pulp or talc slurries was determined using a spectoscopy method and the adsorption isotherm of cationc starch was constructed. When the equilibrium concentration of the cationic starch was low, almost complete adsorption of the starch onto BKP and BCTMP was observed. This indicates that electrostatic attraction is the main driving force for the adsorption of cationc starches onto pulps. BCTMP adsorbed greater amount of cationic starches than BKP since it contained more anionc functional groups on its surface. The adsorption amount of the cationic starch increased as the cationicity of the starches decreased. Surface charge density of the pulp and starch adsorption increased as the pH of the pulp slurry increased. Adsorption amount of the cationic starch onto talc was lower than that onto the pulp due to its low charge density and hydrophobic surface property.

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Effects of Kneading Concentration on Characteristics of HwBKP Fibers (니딩 처리 시 지료농도에 따른 활엽수표백크라프트펄프의 섬유특성 변화)

  • Seo, Ji-Hye;Choi, Kyoung-Hwa;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.4
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    • pp.54-59
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    • 2015
  • In this study, effects of kneading concentration on characteristics of hardwood bleached kraft pulp (HwBKP) fibers were elucidated. A laboratory two-shaft kneader was utilized for kneading. Kneading concentration was varied in the range of 15-30% (w/w) and the number of kneading treatment was adjusted between 0 and 6 passes. It was found that kneading concentration influenced fiber characteristics. At 15% of pulp concentration, fiber length slightly increased with increasing the number of kneading passes, while other morphological properties such as fiber width and curl decreased: fiber straightening occurred. In addition, the increase in WRV and the decrease in CSF were the largest at 15% kneading concentration, meanings that fibrillation mainly occurred. In contrast, at higher kneading concentration exceeding 20%, fiber deformation like curl was mainly occurred. Also, at kneading concentration of 20% and 30%, fiber length decreased with the number of kneading passes while other morphological properties such as fiber width, and WRV increased. Severe fiber entanglement was found at 30% kneading, which shall be removed during papermaking.

Characteristics of the Vegetation Mat Prepared from Miscanthus Sinensis var. Purpurascens (거대억새(Miscanthus sinensis var. purpurascens)를 이용하여 제조된 식생기반재의 특성)

  • Kwon, Gu-Joong;Kim, Eun-Ji;Park, Hee-Jun;Kim, Dae-Young
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.1
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    • pp.27-33
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    • 2014
  • The characteristic of vegetation mat prepared from miscanthus, waste wood chip, perlite and pulp slurry was investigated. The pore rate was increased with amount of pulp slurry. The hydraulic conductivity decreased with the amount of miscanthus in the condition mixed with each other raw materials. With the miscanthus amount, the soil hardness was increased. The peel strength decreased with the mount of miscanthus amount in all case. Hydrogen ion concentration (pH) was the overall alkaline. The MOR of miscanthus based vegetation mat was decreased with the amount miscanthust.

Improvements of Strength and Retention of Cotton Handsheet by Additives(I) - Characteristics of Strength and Retention by Additives - (면 수초지의 지력 및 보류 향상을 위한 첨가제의 적용(제 1보) - 첨가제에 따른 지력 및 보류도 특성 -)

  • Cho, Yu-Je;Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.5
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    • pp.23-29
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    • 2013
  • Various properties of cotton handsheet were measured to solve the problem of deformation while storing guar gum(natural polymer) and to improve strength and retention by synthetic polymers(A-PAM, C-PAM, CMC). The results of this study were summarized as follow. The cotton handsheet with 0.2% of A-PAM showed the best tensile index and folding endurance. Retention of fines and fillers in pulp slurry with 0.2% and 0.3% of A-PAM were more excellent than that with guar gum.

Effect of Operating Parameters on Microbial Desulfurization of Coal by Acidithiobacillus ferrooxidans. (Acidithiobacillus ferrooxidans에 의한 생물학적 석탄탈황에 미치는 조업인자의 영향)

    • Microbiology and Biotechnology Letters
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    • v.31 no.4
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    • pp.400-407
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    • 2003
  • In microbial coal desulfurization process (MCDP) by using Acidithiobacillus ferrooxidans, the effect of process variables on pyritic sulfur removal efficiency has been investigated. The inhibitory effect of toxic materials contained in coal matrix on the activity of desulfurizing bacteria have been evaluated in coal extracts, and the results showed that the method was useful to evaluate the applicability of a coal which is to be desulfurization to MCDP. The removal efficiency increased with decreasing particle size and decreases with increasing pulp density, but has no significant influence of particle size and pup densities at high pulp densities over 20 wt%. The mass transfers of gaseous nutrients such as oxygen and carbon dioxide into coal slurry with various pulp densities and coal particle size has been studied in an airlift bioreactor. Mass transfer coefficient was independent of pulp density in coal slurry with fine particle below 175 $\mu\textrm{m}$, but significantly decreased with increasing pulp density over 225 $\mu\textrm{m}$. The coal particles over 575 $\mu\textrm{m}$ were significantly settled to the bottom of bioreactor resulting in poor mixing. Considering mass transfer, pulp density and coal mixing, an optimal size of coal particle for the microbial coal desulfurization process seems to be about 500 $\mu\textrm{m}$.

Development of On-line Technology for Measuring Stock Consistency Using Optical Sensor (Part 1) - A study on the relationship between the turbidity and transmittance of stocks and their consistency - (광학센서를 이용한 지료의 농도 평가 기술 개발(제1보) - 펄프 슬러리 및 충전물 농도와 탁도 및 투과율의 상관관계 분석 -)

  • Lee Hak-Lae;Lee Ji-Young;Youn Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.1 s.113
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    • pp.9-15
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    • 2006
  • To develop an efficient and cost effective on-line method to determine the stock consistency a study on the relationship between the turbidity and transmittance of stocks and their consistency was carried out using a system consisted of a dynamic drainage jar, pump and turbidometer. Results shooed that the wavelength of 525 nm was most effective for measuring turbidity. As the consistency increases the turbidity increases, and their relationship can be depicted in the second order equations. On the other hand the relationship between consistency and transmittance can be described in exponential equations. From these equations the consistencies of stock samples can be determined using the measured values of turbidity or transmittance.

A study on the removal of the water from the anthracite slurry by Oil Agglomeration Prosess(partI) (Oil Agglomeration Process에 의한 무연탄 슬러리의 탈수에 관한 연구(제1보))

  • 권이동;신강호;조동성
    • Resources Recycling
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    • v.2 no.2
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    • pp.39-44
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    • 1993
  • This study was carried out to remove the water from low grade anthracite slurry produced at Eoryong coal mine by the oil agglomeration process. 80% of Anthracite as a coal oil mixture (COM) was separated from water by the difference of specific gravity. Then, the amount of kerosene, diesel oil, and heavy oil forming COM was 10% of the amount of sample, respectively. The recovery rate of combustibles and ash content of agglomerated anthracite were affected largely by the amount of added oil, pulp density, particle size, mixing time, and impeller speed. The recovery rate of combustibles was increased to 95% and ash content was decrea-sed from 30% to 13.5% under the optimum conditions.

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