• Corrosion Science and Technology
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• 제23권2호
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• pp.93-103
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• 2024

In the present work, a phase-field model for dendritic solidification is applied to hot-dip ZnAlMg coatings to elucidate the morphology of zinc dendrites and the solute segregation leading to the formation of eutectics. These aspects define the microstructure that conditions the corrosion resistance and the mechanical behaviour of the coating. Along with modelling phase transformation and solute diffusion, the implemented model is partially coupled with the tracking of crystal orientation in solid grains, thus allowing the effects of surface tension anisotropy to be considered in multi-dendrite simulations. For this purpose, the composition of a hot-dip ZnAlMg coating is assimilated to a dilute pseudo-binary system. 1D and 2D simulations of isothermal solidification are performed in a finite element solver by introducing nuclei as initial conditions. The results are qualitatively consistent with existing analytical solutions for growth velocity and concentration profiles, but the spatial domain of the simulations is limited by the required mesh refinement.

• 한국광물학회지
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• 제29권3호
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• pp.155-165
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• 2016

붕소가 포함된 다성분계 규산염 용융체의 원자 구조를 규명하는 것은 화산의 분화 양상을 포함한 다양한 지구화학적 과정의 원자 단위 기작을 밝히는데 중요하다. 붕소를 포함한 소듐 알루미노규산염 용융체의 붕소 및 알루미늄 주위의 원자 환경에 관한 자세한 정보는 수용액과 핵폐기물 유리(nuclear waste glasses)의 반응도(reactivity)에 대한 미시적인 설명을 제공한다. 본 연구에서는 붕소가 포함된 비정질 물질의 원자 구조 규명에 가장 적합한 고상 핵자기 공명 분광분석(solid-state nuclear magnetic resonance, solid-state NMR)을 이용하여 붕소의 함량이 비정질 소듐 보레이트($Na_2O-B_2O_3$)와 붕소를 포함한 다성분계 규산염 용융체[말린코아이트(malinkoite, $NaBSiO_4$)와 네펠린(nepheline, $NaAlSiO_4$)의 유사 이원계]의 원자 구조에 미치는 영향을 규명하였다. 비정질 소듐 보레이트의 $^{11}B$ MAS NMR 스펙트럼을 통해 붕소의 함량이 증가함에 따라 배위수가 3인 붕소($^{[3]}B$)가 증가한다는 것이 확인되었다. 비정질 말린코아이트와 네펠린의 유사 이원계의 $^{11}B$ MAS NMR 스펙트럼을 통해 $X_{Ma}$ [$=NaBSiO_4/(NaBSiO_4+NaAlSiO_4)$]가 증가함에 따라 배위수가 4인 붕소($^{[4]}B$)는 증가하는 반면 $^{[3]}B$는 감소하는 것이 관찰되었다. 다성분계 용융체의 $^{27}Al$ MAS NMR 실험 결과, 모든 조성의 용융체에서 배위수가 4인 알루미늄($^{[4]}Al$) 피크가 지배적으로 나타났다. 또한 네펠린 용융체에 붕소가 첨가되었을때 $^{[4]}Al$ 피크의 폭이 크게 감소하였고, 이는 붕소의 첨가가 네펠린 용융체 내의 알루미늄 주위의 구조적 위상학적 무질서도를 감소시킨다는 것을 지시한다. 붕소를 포함한 이원계 및 다성분계 비정질 물질의 $^{11}B$ MAS NMR 스펙트럼으로부터 시뮬레이션을 하여 붕소의 함량에 따른 붕소 원자 환경의 상대적인 존재비를 정량적으로 분석하였고, 이 결과는 붕소가 포함된 비정질 물질의 거시적 성질 변화에 대한 미시적 기작의 근원을 제시할 가능성을 보여준다.

• 방송공학회논문지
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• 제20권4호
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• pp.580-597
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• 2015

브로드캐스트 암호시스템은 한명의 송신자가 다수의 수신자에게 안전하게 메시지를 전송하는 기법이다. 제안된 브로드캐스트 암호 시스템 중 가장 효율적인 것은 트리구조에서 Subset Difference(SD) 기법을 이용한 것으로, 이를 구체화하기 위해 유사난수생성기(PRG: Pseudo-Random Generator)와 비밀분산(SS: Secret Sharing) 방식을 이용한 두 가지 방법이 존재한다. 2-SD 기법은 SD 기법을 일반화하는 것으로 하나의 집합에서 두 개의 부분집합을 동시에 탈퇴시킬 수 있는 방법이다. 2-SD 기법의 장점으로는 SD 기법에 비해 전송량을 더 줄일 수 있다는 것이다. 그러나 현재까지 PRG나 SS 기반에서 2-SD 기법을 설계한 결과는 알려지지 않았다. 본 논문에서는 2014년 Jae Hwan Lee[9]등이 제시한 SS 기반의 SD 기법을 확장하여 SS 기반의 2-SD 기법을 설계한다. 제안된 기법은 기존 SS 기반의 SD 기법에서 요구하는 암호문 헤더 전송량의 약 25% 줄이는 효과가 있다. 또한 암호 이론적으로 본 논문의 결과는 증명 가능한 2-SD 기법을 최초로 제시한 것이다.

• 천문학회지
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• 제38권2호
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• pp.237-240
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• 2005

We present images of L1551 IRS5 at angular resolutions as high as ${\~}$30 mas, corresponding to a spatial resolution of ${\~}$5 AU, made at 7 mm with the VLA. Previously known to be a binary protostellar system, we show that L1551 IRS5 is likely a triple protostellar system. The primary and secondary components have a projected separation of ${\~}$46 AU, whereas the tertiary component has a projected separation of ${\~}$11 AU from the primary component. The circumstellar dust disks of the primary and secondary components have dimensions of ${\~}$15 AU, whereas that of the tertiary component has a dimension of ${\~}$10 AU. Their major axes are closely, but not perfectly, aligned with each other, as well as the major axis of the surrounding flattened, rotating, and contracting molecular condensation (pseudodisk). Furthermore, the orbital motion of the primary and secondary components is in the same direction as the rotational motion of this pseudodisk. We suggest that all three protostellar components formed as a result of the fragmentation of the central region of the molecular pseudo disk. The primary and secondary components, but apparently not the tertiary component, each exhibits a bipolar ionized jet that is centered on and which emergers perpendicular to its associated dust disk. Neither jets are resolved along their base, implying that they are driven within a radial distance of ${\~}$2.5 AU from their central protostars. Finally, we show evidence for what may be dusty matter streams feeding the two main protostellar components.

• 한국전기전자재료학회논문지
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• 제23권6호
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• pp.502-507
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• 2010

In order to design nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system are investigated for their micro structure properties. For this synthesis, the liquid alloys are cooled by the water quenching method. Micro structure images are obtained by using an electron probe micro analyzer(EPMA). Dendritic and lamellar structures are clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. The increase in the $Bi_2Te_3$ composition ratio causes to change of the structure from dendritic to lamellar. The Seebeck coefficient of sample 5, in which the mixture rate of $Bi_2Te_3$ is 83%, is measured as the highest value. In contrast, the others decrease with the increase of the $Bi_2Te_3$ composition ratio. Meanwhile, p-type characteristics are observed in sample 6, at 91%-$Bi_2Te_3$ mixture rate. The power factors of the all samples are calculated with the Seebeck coefficient and resistivity.

• Journal of Advanced Marine Engineering and Technology
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• 제3권1호
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• pp.19-31
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• 1979

Recently the adaptive control system, which keeps the control system always optimal by adjusting the control parameters automatically according to the variations of the plant parameters, have become very important in the field of control engineering. The adaptive control systems are usally composed of the plant identification, the decision of the optimal control parameters, and the adjustment of the control parameters. This paper deals with a method of the adaptive control system when PI or PID controller is used in the feed back control system. Its controlled object (the plant) is assumed to be described by the transfer function of $\frac{ke^{-LS}}{1+TS}$ where k, T and L are steady state gain, time constant and pure dead time respectively, and their values are variable in accordance with the change of environmental circumstance. It has been known that a pseudo-random binary signal is quite effective for the measurement of an impulse response of a plant. In adaptive control systems, however, the impulse response itself is not appropriate to determine the control parameters. In this paper, the authors propose a method to estimate directly the parameters of the plant k, T and L by means of the correlation technique using 3 level M-sequence signal as a test signal. The authors also propose a method to determine the optimal parameters of the PI or PID controller in the sense of minimizing the square integral of the control error in the feed back control system, and the values of the optimal parameters are computed numerically for various values of T and L, and the results are examined and compared with those of the conventional methods. Finally the above-mentioned two methods are combined and an algorithm to struct an adaptive control system is suggested. The experiments for the indicial responses by means of both the model of the temperature control system using SCR actuater and the analog simulations have shown good results as expected, and the effectiveness of the proposed method is verified. The M-sequence generator and the time delay circuit, which are manufactured for the experiments, are operated in quite a good condition.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2010년도 춘계학술회의 초록집
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• pp.11-11
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• 2010

In order to design for nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system were investigated for their micro structure and thermal properties. For this synthesis the liquid alloys were cooled by water quenching method. The micro structure images were taken by using electron probe micro analyzer (EPMA). Dendritic and lamellar structures were clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. It was confirmed that a metastable compounds is $PbBi_2Te_4$ in the The $Bi_2Te_3$-PbTe system. The change in the composition increasing $Bi_2Te_3$ ratio causes to change structure from dendritic to lamellar. Seebeck coefficient of alloys 5 which the mixture rate of $Bi_2Te_3$ is 83% was measured as the highest value. In contrast, the others decreased by increasing $Bi_2Te_3$. n-type characteristics was observed at all condition except alloy 6 which $Bi_2Te_3$ ration is 91%. The power factors of all samples were calculated with Seebeck coefficient and resistivity. Also the thermal conductivity was measured by using laser flash analyzer (LFA). In this work, the microstructures and thermal properties have been measured as a function of ratio of $Bi_2Te_3$ in the $Bi_2Te_3$-PbTe system.

• 한국통신학회논문지
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• 제34권1C호
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• pp.131-137
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• 2009

Bin offset carrier (BOC) 신호 동기화 과정은 GPS, Galileo와 같은 위성항법시스템에서 가장 중요한 단계이다. BOC 신호 동기화 과정은 일반적으로, 수신 BOC 신호와 단말기의 BOC 신호 사이의 상관함수를 이용하여 이루서진다. 따라서 BOC 자기상관함수의 다중 첨두 문제는 동기화 오차의 주요한 원인이 된다. 최근 Julien에 의해 BOC 상관함수 상의 주변 첨두 크기를 줄일 수 있는 기법이 제안되었다. 그러나 이 기법은 주변 첨두를 완벽히 제거하지 못하며, 적용할 수 있는 신호도 제한적이다. 본 논문에서는 주변 첨두가 완벽히 제거된 새로운 상관함수를 제안하였다. 제안한 상관함수는 sine 위상 및 cosine 위상의 BOC 신호 모두에 적용할 수 있으며, 주변 첨두를 완벽히 제거할 수 있다. 또한 제안한 상관함수를 효율적으로 구현할 수 있는 상관기 구조도 제안하였다.

• 상하수도학회지
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• 제37권6호
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• pp.375-382
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• 2023

The binary oxide adsorbent using Fe and Mn (Fe-Mn) has been prepared by precipitation method to enhance the removal of phosphate. Different amounts of chitosan, a natural organic polymer, were used during preparation of Fe-Mn as a stabilizer to protect an aggregation of Fe-Mn particles. The optimal amount of chitosan has been determined considering the separation of the Fe-Mn particles by gravity from solution and highest removal efficiency of phosphate (Fe-Mn10). The application of Fe-Mn10 increased removal efficiency at least 15% compared to bare Fe-Mn. According to the Langmuir isotherm model, the maximum uptake (q_m) and affinity coefficient (b) were calculated to be 184 and 240 mg/g, and 4.28 and 7.30 L/mg for Fe-Mn and Fe-Mn10, respectively, indicating 30% and 70% increase. The effect of pH showed that the removal efficiency of phosphate was decrease with increase of pH regardless of type of adsorbent. The enhanced removal efficiency for Fe-Mn10 was maintained in entire range of pH. In the kinetics, both adsorbents obtained 70% removal efficiency within 5 min and 90% removal efficiency was achieved at 1 h. Pseudo second order (PSO) kinetic model showed higher correlation of determination (R²), suggesting chemisorption was the primary phosphate adsorption for both Fe-Mn and Fe-Mn10.

• 한국자기학회지
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• 제1권1호
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• pp.17-24
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• 1991

$NdFe_2$, $Nd{(Fe_{0.5})}_2$, $SmCo_2$ 및 $Sm{(Fe_{0.5}Co_{0.5})}_2$ 조성의 Laves 화합물을 급속냉각기술에 의하여 제조하였다. 저온자기특성을 조사한 결과 $Nd{(Fe_{0.5}Co_{0.5})}_2$, $SmCo_2$와 $Sm{(Fe_{0.5}Co_{0.5})}_2$ 조성의 Laves 화합물은 강자성의 거동을 보이며 결정구조는 모두 C15의 단일상으로 존재하였으며, $NdFe_2$ 조성의 급냉합금은 일종의 spin reorientation 거동을 보였다. $NdFe_2$ 조성의 급냉합금은 화학조성식 $NdFe_7$의 준안정상과 Nd-rich상으로 구성됨을 알았다. $NdFe_2$ 급냉합금을 열처리 하면 $NdFe_7$은 $Nd_2Fe_{17}$과 Nd-Fe-O상으로 변태하였다. $Sm{(Fe_{0.5}Co_{0.5})}_2$ Laves 화합물의 보자력은 상온에서 4kOe이며 큐리온도는 $400^{\circ}C$로 측정된다. 또한 $Nd{(Fe_{0.5}Co_{0.5})}_2$ Laves 화합물은 상온에서 $2.8\;{\mu}_B/f.u.의$ 자기모멘트를 보유한다.