• Title/Summary/Keyword: pseudo second order

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Nanoporous carbon synthesized from grass for removal and recovery of hexavalent chromium

  • Pathan, Shahin A.;Pandita, Nancy S.
    • Carbon letters
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    • v.20
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    • pp.10-18
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    • 2016
  • Nanoporous carbon structures were synthesized by pyrolysis of grass as carbon precursor. The synthesized carbon has high surface area and pore volume. The carbon products were acid functionalized and characterized by Fourier transform infrared spectroscopy, X-ray diffraction, Brunauer–Emmett–Teller, transmission electron microscopy, and Energy Dispersive X-ray microanalysis. Acid functionalized nanoporous carbon was explored for use in removal of toxic Cr(VI) ions from aqueous media. An adsorption study was done as a function of initial concentration, pH, contact time, temperature, and interfering ions. The experimental equilibrium data fits well to Langmuir isotherm model with maximum monolayer adsorption capacity of 35.335 mg/g. The results indicated that removal obeys a pseudo-second-order kinetic model, and that equilibrium was reached in 10 min. A desorption study was done using NaOH. The results of the present study imply that acid functionalized nanoporous carbon synthesized from grass is an efficient, renewable, cost-effective adsorbent material for removal of hexavalent chromium due to its faster removal rate and reusability.

Removal of Sr and Cs ions by SAN-Zeolite Beads Prepared by Immobilization of Zeolite with SAN (제올라이트를 SAN으로 고정화한 SAN-Zeolite 비드에 의한 Sr과 Cs 이온 제거)

  • Lee, Chang-Han;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.24 no.11
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    • pp.1331-1341
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    • 2015
  • The removal of Sr ion and Cs ion was investigated to evaluate adsorption properties by using SAN-Zeolite beads immobilized with styrene acrylonitrile (SAN). The adsorption capacities increased with the decrease of SAN/zeolite ratio (SAR) from 2.5 to 0.83. The relationship of adsorption capacity ($q_e$) and SAR was described by experimental equation such as $q_e=20.88+137.81e^{-1.96SAR}$ ($r^2=0.9980$). The adsorption kinetics of Sr ion and Cs ion with SAN-Zeolite beads were fitted well by the pseudo-second-order model. The maximum adsorption capacities of Sr ion and Cs ion calculated from Langmuir isotherm model were 66.97 mg/g and 81.97 mg/g, respectively.

A FPGA implementation of a full-digital code acquisition/Tracking Loop for the CDMA direct-sequence spread-spectrum signals (대역 제한된 직접 시퀀스 CDMA 확산 대역 신호를 위한 전 디지탈 부호 획득 및 추적 루우프 FPGA 구현)

  • 김진천;박홍준;임형수;전경훈
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.5
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    • pp.165-171
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    • 1996
  • A noncoherent full-digital PN(pseudo noise) code acquisition/tracking loop has been presetned and implemented in FPGA for the CDMA band-limited direct-sequence spread-spectrum (DS-SS) signals. It employs a simple decimator to control of local PN code phase to lower the hardware cost, and a second order loop to enable the more accurate tracking. The proposed acquisition/tracking loop has been designed in RTL-level VHDL, synthesized into logic gates using the design analyzer of synopsys software, implemented in an ALTERA FPGA chip, and tested. The number of logic gates used in the implemented FPGA chip is around 7000. The functionality has been verified using a PC interface circuitry and a logic analyzer.

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Adsorption Treatment of Azo Dye Containing Wastewater using Activated Carbon and Glass Fiber as an Adsorbent (활성탄과 유리섬유를 흡착제로 이용한 아조염료 함유 폐수의 처리)

  • Baek, Mi-Hwa;Jeon, Hyein;Lee, Ji-Ae;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.25 no.3
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    • pp.370-374
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    • 2009
  • Adsorption characteristics of glass fibers, obtained from the spent lithium primary batteries recycling process, were investigated for the removal of Acid Red 27 dye from aqueous solution. The batch data clearly showed that increasing the initial sorptive concentration apparently enhanced the amount adsorbed and the uptake process followed the pseudo-second order rate model. The equilibrium adsorption data at different initial sorptive concentrations were fitted well to Freundlich and Langmuir adsorption isotherms. Moreover, the increase in temperature, favored the uptake of dye on this solid, indicated the process was endothermic in nature. Further, using the temperature dependence sorption data obtained at different temperatures was used to estimate various thermodynamic parameters.

Adsorption of Ammonia on Municipal Solid Waste Incinerator Bottom Ash Under the Landfill Circumstance

  • Yao, Jun;Kong, Qingna;Zhu, Huayue;Zhang, Zhen;Long, Yuyang;Shen, Dongsheng
    • Korean Chemical Engineering Research
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    • v.53 no.4
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    • pp.503-508
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    • 2015
  • The adsorption characteristics of ammonia on MSWI bottom ash were investigated. The effect of the variation of the landfill environmental parameters including pH, anions and organic matter on the adsorption process was discussed. Results showed that the adsorption could be well described by pseudo-second-order kinetics and Langmuir model, with a maximum adsorption capacity of 156.2 mg/g. The optimum adsorption of ammonia was observed when the pH was 6.0. High level of ion and organic matter could restrict the adsorption to a low level. The above results suggested that MSWI bottom ash could affect the migration of ammonia in the landfill, which is related to the variation of the landfill circumstance.

Enhancement of Methylene Blue dye adsorption by Fe-Hydroxyapatite composite

  • Cifci, Deniz Izlen
    • Advances in environmental research
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    • v.5 no.4
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    • pp.225-235
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    • 2016
  • Synthesized hydroxyapatite (Hyd) and Fe-hydroxyapatite (Fe-Hyd) composite were used for the removal of Methylene Blue (MB) from aqueous solutions in this study. The effect of adsorbent amount, pH and initial MB concentration were carried out to investigate in the aqueous solution. The kinetic study shows that the MB adsorption process with Hyd or Fe-Hyd follow pseudo-second order kinetic model. Experimental results are well fitted to the Langmuir isotherm model. The maximum adsorption capacities of Hyd and Fe-Hyd were obtained as 2.90 mg/g and 5.64 mg/g for MB according to Langmuir Isotherm models, respectively. Fe-Hyd composite increased the adsorption capacity of Hyd by 1.95 times that Hyd. It is concluded that Fe-Hyd composite is promising and economical adsorbent for MB removal in the aqueous solution.

Multi-Objective Optimal Design of a Single Phase AC Solenoid Actuator Used for Maximum Holding Force and Minimum Eddy Current Loss

  • Yoon, Hee-Sung;Eum, Young-Hwan;Zhang, Yanli;Koh, Chang-Seop
    • Journal of Electrical Engineering and Technology
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    • v.3 no.2
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    • pp.218-223
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    • 2008
  • A new Pareto-optimal design algorithm, requiring least computational work, is proposed for a single phase AC solenoid actuator with multi-design-objectives: maximizing holding force and minimizing eddy current loss simultaneously. In the algorithm, the design space is successively reduced by a suitable factor, as iteration repeats, with the center of pseudo-optimal point. At each iteration, the objective functions are approximated to a simple second-order response surface with the CCD sampling points generated within the reduced design space, and Pareto-optimal solutions are obtained by applying($1+{\lambda}$) evolution strategy with the fitness values of Pareto strength.

Security Properties of Domain Extenders for Cryptographic Hash Functions

  • Andreeva, Elena;Mennink, Bart;Preneel, Bart
    • Journal of Information Processing Systems
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    • v.6 no.4
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    • pp.453-480
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    • 2010
  • Cryptographic hash functions reduce inputs of arbitrary or very large length to a short string of fixed length. All hash function designs start from a compression function with fixed length inputs. The compression function itself is designed from scratch, or derived from a block cipher or a permutation. The most common procedure to extend the domain of a compression function in order to obtain a hash function is a simple linear iteration; however, some variants use multiple iterations or a tree structure that allows for parallelism. This paper presents a survey of 17 extenders in the literature. It considers the natural question whether these preserve the security properties of the compression function, and more in particular collision resistance, second preimage resistance, preimage resistance and the pseudo-random oracle property.

Low concentration cadmium removal using weathered sand of basalt

  • Park, Jae Hong;Lee, Jae Kwan;Shin, Dong Seok
    • Membrane and Water Treatment
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    • v.12 no.2
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    • pp.51-58
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    • 2021
  • The natural weathered sand of basalt (WSB) has been used for the removal of cadmium from aqueous solution. The influence of various parameters i.e., contact time, pH, weathered sand of basalt dosage, particle size of the weathered sand of basalt, temperature and initial cadmium concentration were analyzed. Cadmium adsorption kinetics was well described by the pseudo second order model. Adsorption equilibrium for cadmium was properly well fitted to Langmuir isotherm model with maximum adsorption capacity 0.50 mg/g. Compared with the other experimental results using various kinds of adsorbents at a low concentration (1.0 mg/L or so) similar to that of this study, the cadmium removal efficiency using weathered sand of basalt was higher. It has been demonstrated that weathered sand of basalt has a available alternative adsorbent for cadmium when its initial concentration is low.

Highly efficient adsorptive removal of uranyl ions from aqueous solutions using dicalcium phosphate nanoparticles as a superabsorbent

  • Saghatchi, Hadis;Ansari, Reza;Mousavi, H. Zavvar
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1112-1119
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    • 2018
  • Dicalcium phosphate nanoparticles (DCP-NPs) was synthesized chemically and used for adsorptive removal of uranyl ions from aqueous solutions in a batch system. A commercial grade of DCP (monetite) was also employed for comparison. The synthesized and commercial adsorbents (S-DCP and C-DCP) were characterized by FT-IR, SEM and XRD techniques. The investigation of adsorption isotherms indicated that the maximum adsorption capacities ($q_m$) for C-DCP and S-DCP were 714.3 and $666.7mg\;g^{-1}$ (at 293 K), respectively. The experimental kinetics were well-described by the pseudo-second-order kinetic and the equilibrium data were fitted with both Langmuir and Freundlich adsorption models. Thermodynamic studies indicated that the adsorption of uranyl ions on the monetite surface was a spontaneous exothermic process. The exhausted adsorbents could be regenerated by washing with $0.10mol\;L^{-1}$ NaOH.