• Title/Summary/Keyword: proton exchange membrane fuel Cell

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Topology of High Efficiency Power Conversion with Fuel Cell Generation System (고효율 전력변환장치를 사용한 연료전지 시스템의 토폴로지)

  • Mun, S.P.;Suh, K.Y.;Lee, H.W.;Kwon, S.K.;Nakaoko, M.;Shin, H.B.
    • Proceedings of the KIEE Conference
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    • 2005.10c
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    • pp.329-333
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    • 2005
  • In this study paper, a 3[kW] Fuel Cell Generation (FCG)system with Fuel Cell(FC)simulator has been proposed. The developed FC simulator generates the actual voltage and current output characteristics of the Proton Exchange Membrane Fuel Cell (PEMFC), so that the overall performance and the dynamics of the proposed system could be effectively examined and tested. In this paper, at first, the system configuration and operational principle of the developed FC simulator has been investigated and the design process of the FCG system is explained in detail. In addition, the validity of the proposed system has been verified by the informative simulation and experimental results.

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Comparison between CFD analysis and experiments according to various PEMFC flow-field designs (유로 형상 변화에 따른 CFD 해석 결과와 PEM 연료전지 성능 비교)

  • Lee, Kang-In;Park, Min-Soo;Lee, Se-Won;Chu, Chong-Nam
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.572-575
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    • 2008
  • Flow-field design has much influence over the performance of proton exchange membrane fuel cell (PEMFC) because it affects the pressure magnitude and distribution of the reactant gases. To obtain the pressure magnitude and distribution of reactant gases in four kinds of flow-field designs without additional measurement equipment, computational fluid dynamics (CFD) analysis was performed. After the CFD analysis, the performance values of PEMFC according to the flow-field configurations were measured via a single cell test. As expected, the pressure differences due to different flow-field configurations were related to the PEMFC performance because the actual performance results showed the same tendency as the results of the CFD analysis. A large pressure drop resulted in high PEMFC performance. So, the single serpentine configuration gave the highest performance. On the other hand, the parallel flow-field configuration gave the lowest performance because the pressure difference between inlet and outlet was the lowest.

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Electrospun $SiO_2$ membrane using covalently cross-linked SPEEK/HPA by impregnation for high temperature PEMFC

  • Na, Heesoo;Hwang, Hyungkwon;Lee, Chanmin;Shul, Yonggun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.85.2-85.2
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    • 2010
  • There is widespread effort to develop polymer membranes in place of Nafion for high temperature polymer electrolyte membrane fuel cell(PEMFC). In our study, SiO2 membranes are arranged by electrospinning method. For impregnation solution, the modified sulfonated poly(ether ether ketone)(SPEEK) polymer is prepared from sulfonation, sulfochlorination, partial reduction and lithiation reaction. The modified polymer is cross-linked with 1,4-diiodobetane in NMP solvent and then blended with Heteropoly acid(HPA). The characterization of membranes is confimed by FT-IR, Thermogravimetry(TGA), water uptake test and single cell performance test for PEMFC, etc. The composite membrane shows satisfactory thermal and mechanical properties. Beside, The membrane exhibits good ion exchange capacity and high proton conductivity. As a result, The composite membrane is promising as an alternative membrane in high temperature PEMFC.

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Numerical Study of Effects of Operating Conditions on the Performance of High Temperature PEMFC (작동 조건에 따른 고온 고분자 전해질 연료전지의 성능 변화에 대한 전산해석 연구)

  • Kim, Kyoung-Youn;Sohn, Young-Jun;Kim, Min-Jin;Yang, Tae-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.13 no.4
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    • pp.283-289
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    • 2010
  • A two-dimensional isothermal model has been employed for numerical simulations of a high temperature hydrogen fuel cell with proton exchange membrane. The model is validated with existing experimental data and used for examination on the effects of various operating conditions on the fuel cell performance. The present numerical results show that the cell performance increases with increasing exchange current density, ion conductivity of the membrane, inlet gas flow rate as well as operating pressure. Also, higher porosity of gas diffusion layer (GDL) results in higher cell performance due to enhancement of the diffusion through the GDL, where the cathode GDL porosity more influences on the performance as compared with the anode one.

Experimental Investigation of the Effect of Composition on the Performance and Characteristics of PEM Fuel Cell Catalyst Layers

  • Baik, Jung-Shik;Seong, Dong-Mug;Kim, Tae-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.157-160
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    • 2007
  • The catalyst layer of a proton exchange membrane (PEM) fuel cell is a mixture of polymer, carbon, and platinum. The characteristics of the catalyst layer play critical role in determining the performance of the PEM fuel cell. This research investigates the role of catalyst layer composition using a Central Composite Design (CCD) experiment with two factors which are Nafion content and carbon loading while the platinum catalyst surface area is held constant. For each catalyst layer composition, polarization curves are measured to evaluate cell performance at common operating conditions, Electrochemical Impedance Spectroscopy (EIS), and Cyclic Voltammetry (CV) are then applied to investigate the cause of the observed variations in performance. The results show that both Nafion and carbon content significantly affect MEA performance. The ohmic resistance and active catalyst area of the cell do not correlate with catalyst layer composition, and observed variations in the cell resistance and active catalyst area produced changes in performance that were not significant relative to compositions of catalyst layers.

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Dynamic Simulation of Proton Exchange Membrane Fuel Cell Stack under Various Operating Pattern of Fuel Cell Powered Heavy Duty Truck (연료전지 트럭의 운전 부하 패턴에 따른 고분자 연료전지 스택의 동특성 시뮬레이션 )

  • NAMIN SON;MUJAHID NASEEM;UIYEON KIM;YOUNG DUK LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.121-128
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    • 2024
  • In this study, a dynamic simulation model of a heavy-duty truck, equipped with a fuel cell power-train, has been developed and the dynamic behavior of the fuel cell stack has bee investigated using. Output change simulations were performed according to several drive cycle load change of a fuel cell truck. Mathworks' Simulink and Simscape program were used to develop the model. The model is comprised of fuel cell power train, power converter system and truck vehicle part. The vehicle runs at targeted speed of the truck, which is set as the load of the system. The dynamic behavior of the fuel cell stack according to the weight difference were analyzed, and based on this, the dynamic characteristics of the fuel cell output power and battery state with simple load was analyzed.

OXYGEN CONCENTRATION IN THE CATHODE CHANNEL OF PEM FUEL CELL USING GAS CHROMATOGRAPH

  • Ha, T.H.;Kim, H.S.;Min, K.D.
    • International Journal of Automotive Technology
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    • v.8 no.1
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    • pp.119-126
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    • 2007
  • Because of the low temperature operation, proton exchange membrane (PEM) fuel cell has a water phase transition. Therefore, water management is an important operation issue in a PEM fuel cell because the liquid water in the fuel cell causes electrode flooding that can lower the cell performance under high current density conditions. In this study, in order to understand the reactant distributions in the cathode channels of the PEM fuel cell, an experimental technique that can measure the species concentrations of reactant gases by using gas chromatograph (GC) is applied for an operating PEM fuel cell. The oxygen distribution along the cathode flow channels of PEM fuel cell is mainly investigated with various operating conditions. Also, the relations between cathode flooding and oxygen concentrations and oxygen consumption pattern along the cathode channel configurations of the unit cell adopted for this study are discussed using GC measurement and visualization experiment of cathode flooding. It is found that the amount of oxygen consumption is very sensitive to various operating conditions of the fuel cell and was much affected by the flooding occurrence in cathode channels.

A Study of Modeling PEM Fuel Cell System Using Multi-Variable Optimization Technique for Automotive Applications (다변수 최적화 기법을 이용한 자동차용 고분자 전해질형 연료전지 시스템 모델링에 관한 연구)

  • Kim, Han-Sang;Min, Kyoung-Doug;Jeon, Soon-Il;Kim, Soo-Whan;Lim, Tae-Won;Park, Jin-Ho
    • New & Renewable Energy
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    • v.1 no.4 s.4
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    • pp.43-48
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    • 2005
  • This study presents the integrated modeling approach to simulate the proton exchange membrane [PEM] fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cell system, multi-variable optimization code was adopted. Using this method, the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study can be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

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A Study of Modeling PEM Fuel Cell System Using Multi-Variable Optimization Technique for Automotive Applications (다변수 최적화 기법을 이용한 자동차용 고분자전해질형 연료전지 시스템 모델링에 관한 연구)

  • Kim, Han-Sang;Min, Kyoung-Doug;Jeon, Soon-Il;Kim, Soo-Whan;Lim, Tae-Won;Park, Jin-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.541-544
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    • 2005
  • This study presents the integrated modeling approach to simulate the proton exchange membrane (PEM) fuel cell system for vehicle application. The fuel cell system consisting of stack and balance of plant (BOP) was simulated with MATLAB/Simulink environment to estimate the maximum system power and investigate the effect of BOP component sizing on system performance and efficiency. The PEM fuel cell stack model was established by using a semi-empirical modeling. To maximize the net efficiency of fuel cel1 system, multi-variable optimization code was adopted. Using this method the optimized operating values were obtained according to various system net power levels. The fuel cell model established was co-linked to AVL CRUISE, a vehicle simulation package. Through the vehicle simulation software, the fuel economy of fuel cell powered electric vehicle for two types of driving cycles was presented and compared. It is expected that this study tan be effectively employed in the basic BOP component sizing and in establishing system operation map with respect to net power level of fuel cell system.

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Effect of Humidity and Flooding on the Performance of Proton Exchange Membrane Fuel Cell (고분자전해질 연료전지의 성능에 미치는 습도와 플러딩의 영향)

  • Hwang, Byungchan;Chung, Hoi-Bum;Song, Myung-Hyun;Oh, Sung-June;Na, Il-Chai;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.55 no.3
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    • pp.302-306
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    • 2017
  • Humidity affect performance and durability of proton exchange membrane fuel cell (PEMFC). High humidity of gases generally enhance the performance, but high humidity have the danger of flooding. I-V performance, linear sweep voltammetry, cyclo voltammetry, and impedance of micro-channel cell measured with change of relative humidity (RH). Flooding phenomena started at RH 70%. Ion conductivity of membrane reached maximum value at RH 80%. Maximum current density of $1,700mA/cm^2$ (at 0.6 V) was obtained at RH 80%. Therefore the effect of ion conductivity increasement was higher than that of mass transfer decrease by flooding at RH 80%.