• 제목/요약/키워드: protection potential

검색결과 1,190건 처리시간 0.027초

해수용액에서 선박용 Al-Mg-Si 합금의 전기화학적 실험에 의한 방식전위 결정 (The Protection Potential Decision by Electrochemical Experiment of Al-Mg-Si Alloy for Ship in Seawater)

  • 정상옥;박재철;한민수;김성종
    • Corrosion Science and Technology
    • /
    • 제9권1호
    • /
    • pp.48-55
    • /
    • 2010
  • The many vessels are built with FRP(Fiber-Reinforced Plastic) material for small boats and medium vessels. However, FRP is impossible to be used for recyclable material owing to environmental problems and causes large proportion of collision accidents because radar reflection wave is so weak that large vessels could not detect FRP ships during the sailing. Hence, Al alloy comes into the spotlight to solve these kinds of problems as a new-material for next generation instead of FRP. Al alloy ships are getting widely introduced for fish and leisure boats to save fuel consumption due to lightweight. In this study, it was selected 6061-T6 Al alloy which are mainly used for Al-ships and carried out various electrochemical experiment such as potential, anodic/cathodic polarization, Tafel analysis, potentiostatic experiment and surface morphologies observation after potentiostatic experiment for 1200 sec by using the SEM equipment to evaluate optimum corrosion protection potential in sea water. It is concluded that the optimum corrosion protection potential range is -1.4 V ~ -0.7 V(Ag/AgCl) for 6061-T6 Al alloy, in the case of application of ICCP(Impressed current cathodic protection), which was shown the lowest current density at the electrochemical experiment and good specimen surface morphologies after potentiostatic experiment for Al-Mg-Si(6061-T6) Al alloy in seawater environment.

Al-황동의 응력부식균열 특성에 미치는 인가전위의 영향 (Effect of Impressed Potential on the SCC of Al-Brass)

  • 정해규;임우조
    • 한국해양공학회지
    • /
    • 제18권1호
    • /
    • pp.69-74
    • /
    • 2004
  • In general, the protection method of Shell and Tube Type heat exchanger for a vessel has been applied as a sacrificial anode, which is attached at the inner side of the shell. However, this is an insufficient protection method for tube. Therefore, a more suitable method, such as the impressed current cathodic protection for tube protection, is required. Al-brass is the raw material of tubes for heat exchanger of a vessel where seawater is used for cooling the water. It has a high level of heat conductivity, excellent mechanical properties, and a high level of corrosion resistance, due to a cuprous oxide (Cu$_2$O) layer against th seawater. However, in actuality, it has been reported that Al-brass tubes for heat exchanger of a vessel can produce local corrosion, such as stress corrosion cracking (SCC). This paper studied the effect of impressed potential on the stress corrosion cracking of Al-brass for impressed current cathodic protection in 3.5% NaCl +0.1% NH$_4$OH solution, under flow by a constant displacement tester. Based on the test results, the latent time of SCC, stress corrosion crack propagation, and the dezincification phase of Al-brass are investigated.

정전위 SSRT법에 의한 해양구조물용 Cu함유 고장력저합금강의 수소취성한계전위 규명에 관한 연구 (A Study of Hydrogen Embrittlement Limit Potential of Cu-Containing High Strength Low Alloy Steel for Marine Structure by Potentiostatic SSRT Method)

  • 김성종;박태원;심인옥;김종호;김영식;문경만
    • Journal of Welding and Joining
    • /
    • 제19권2호
    • /
    • pp.182-190
    • /
    • 2001
  • A marine structural material was well known to have high tensile strength, good weldability and proper corrosion resistance. Cu-containing high strength low alloy(HSLA) steel was recently developed for their purposes mentioned above. And the steel is free about preheating for welding, therefore it is reported that shipbuilding cost by using it can be saved more or less. However the marine structural materials like Cu-containing HSLA steel are being generally adopted with cathodic protection method in severe corrosive environment like natural sea water but the high strength steel may give rise to Hydrogen Embrittlement due to over protection at high cathodic current density for cathodic protection. In this study Cu-containing HSLA steel using well for marine atructure was investigated about the susceptibility of Hydrogen Embrittlement as functions of tensile strength, strain ratio, fracture time, and fracture mode, etc. and an optimum cathodic protection potential by slow strain rate test(SSRT) method as well as corrosion properties in natural sea water. And its corrosion resistance was superior to SS400 steel, but Hydrogen Embrittlement susceptibility of Cu-containing HSLA steel was higer than that of SS400 steel. However Hydrogen Embrittlement of its steel by SSRT method was showed with pheonomena such as decreasing of fracture time, strain ratio and fracture mode of QC(quasi-cleavage). Eventually it is suggested that an optimum cathodic protection potential not presenting Hydrogen Embrittlement of Cu-containing of HSLA steel by SSRT method was from-770mv(SCE) to - 900mV(SCE)under natural sea water.

  • PDF

3% NaCl용액중에 있어서 4340강의 부식거동과 과방식에 의한 수소포화거동에 미치는 인히비타의 영향 (The effect of inhibitors affecting to corrosion behaviors and hydrogen embrittlement behaviors due to over-propection of a 4340 steel in 3% NaCl solution)

  • 문경만;백태실;이상태
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제13권4호
    • /
    • pp.54-62
    • /
    • 1989
  • When some kinds of inhibitors, i.e. $1{\times}10{-3}mol/l$ arsenic trioxide, 0.2 mol/l 2-mercaptoethanol, 0.2mol/l thiourea were added to 3% NaCl solution, there were some considererable effects to decrease corrosion current density in natural potential condition and the effect fo solution temperature increasing corrosion rate was smaller than that of no addition to 3% NaCl solution. However the susceptibility of hydrogen embrittlement due to over-protection in case of cathodic protection was much greater than that of no addition, especially was the greatest in case of addition of 2-mercaptoethanol. Therefore adding inhibitors for anti-corrosion effect, it is suggested that selection of the optimum protection potential is important from the view point of prevention against hydrogen embrittlement due to over-protection in case of cathodic protection.

  • PDF

EFFECT OF POST-WELD HEAT TREATMENT OF MARINE STRUCTURE STEEL DURING CATHODIC PROTECTION

  • Kim, Seong-Jong;Masazumi Okido;Kim, Jin-Gyeong;Moon, Kyung-Man
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
    • /
    • pp.273-275
    • /
    • 2002
  • The effect of post-weld heat treatment (PWHT) of marine structures steel was investigated at electrochemical viewpoint. In addition, slow strain rate test (SSRT) was carried out to investigate both electrochemical and mechanical properties by PWHT effect during impressed current cathodic protection. The optimum cathodic protection potential by SSRT was -770 mV(SCE). At the applied cathodic protection potential of -770 mV -850 mV(SCE), the fracture morphology was dimple pattern with ductile fracture, while it was transgranular pattern (Q.C: quasi cleavage) under -875 mV(SCE).

  • PDF

Fracture Toughness Evaluation of Natural Gas Pipeline under the Cathodic Protection

  • Kim, Cheol-Man;Baek, Jong-Hyun;Kim, Young-Pyo;Kim, Woo-Sik
    • Corrosion Science and Technology
    • /
    • 제8권4호
    • /
    • pp.133-138
    • /
    • 2009
  • For the corrosion protection of the natural gas transmission pipelines, two methods are used, cathodic protection and coating technique. In the case of cathodic protection, defects are embrittled by occurring hydrogen at the crack tip or material surface. It is however very important to evaluate whether cracks in the embrittled area can grow or not, especially in weld metal. In this work, on the basis of elastic plastic fracture mechanics, we performed the CTOD testing with various test conditions, such as testing rate and potential. The CTOD of the base metal and the weld metal showed a strong dependence of the test conditions. The CTOD decreased with decreasing testing rate and with increasing cathodic potential. The morphology of the fracture surface showed the quasi-cleavage at low testing rate and cathodic overprotection. The low CTOD was caused by hydrogen embrittlement at crack tip.

350km/h급 고속전차선로 보호선의 선종결정 기법에 관한 연구 (A Study on the Protection Wire Type Decision of Catenary System in the 350km/h High Speed Line)

  • 이학표;서기범;박재영
    • 전기학회논문지
    • /
    • 제64권12호
    • /
    • pp.1818-1823
    • /
    • 2015
  • In this paper, we analyzed the optimal configuration of protection wire that have been installed in the electric railway power supply system. Protection wires are to suppress the ground potential rise when the short circuit fault between contact wire-rail(C-F), and protect the electronics equipments(signalling and communication) that are facility the wayside. The role of protection wires must be feed back quickly the fault current to the substation when a short circuit fault occurs. In this paper, we proposed that only one line to install the protection wire. Comparing how to newly proposed and existing system, most of the performance is similar. The reason is that most of the current flowing in the protection wire near the location where the fault occurred. There is no problem even if in one line for human safe and the low impedance of the return circuit in dimension to ensure the safety of the facility during the fault. To ensure safety during an fault occurs, it is sufficient even by one line. But, In the protection wire of facilities planning it is necessary to design taking into account the potential utility.

고무차륜시스템에서의 지락보호를 위한 급전선로 절연과 부극전위와의 영향 분석 (An Analysis of Influence Between the Power Feeding Line Insulation and Negative Rail Potential for the DC Ground Fault Protection in the Rubber Wheel System)

  • 정호성;신승권;김형철;박영;조상훈
    • 전기학회논문지
    • /
    • 제62권4호
    • /
    • pp.577-583
    • /
    • 2013
  • We have analyzed influence of potential rise in negative bus, which caused by decrease of power feeding line insulation, upon protecting method of DC ground protection device which detecting potential rise between negative bus and ground in order to detect ground fault in the rubber wheel system. For this purpose, we proposed negative potential equation between negative bus and ground and calculated negative potential according to system condition changes by estimating power feeding line insulation changes in steel wheel system and rubber wheel system, and equalizing DC power feeding system when ground fault occurred. Also, in order to estimate negative potential of real system, we modeled the rubber wheel system, and simulated normal status, grounding fault occurrence and power feeding line insulation changes. In normal status, negative potential did not rise significantly regardless of vehicle operation. When ground fault occurred, negative potential rose up over 300V regardless of fault resistance. However, we also observed that negative potential rose when power feeding line insulation dropped down under $1M{\Omega}$. In conclusion, our result shows that in case of rubber wheel system unlike steel wheel system, relay will be prevented maloperation and insulation status observation can be ensured when ground over voltage relay will be set 200V ~ 300V.

포텐셜함수 기반 초공동 수중운동체 플레이닝 회피 제어 연구 (Planing Avoidance Control for a Supercavitating Underwater Vehicle Based on Potential Functions)

  • 김선홍;김낙완;김민재;김종혁;이건철
    • 한국해양공학회지
    • /
    • 제32권3호
    • /
    • pp.208-212
    • /
    • 2018
  • In this paper, we focus on planing avoidance control for a supercavitating underwater vehicle based on the potential function method. The planing margin can be calculated using the relative position between the cavity center and vehicle center at the end of the vehicle. The planing margin was transformed into a limit variable such as the pitch angle and yaw angle limit. To prevent the vehicle attitude from exceeding the limit variable, a potential function based planing envelope protection method was proposed. The planing envelope protection system overrides commands from the tracking controller, and the vehicle attitude converges to a desired angle, in which the potential function is minimized. Numerical simulations were performed to analyze the physical feasibility and performance of the proposed method. The results showed that the proposed methods eliminated the planing, allowing the vehicle to follow tracking commands.

Mg 합금유전양긍에 의한 온수보일러의 음극방식거동에 관한 연구 (Study on the Cathodic Protectioin Behavior of Hot Water Boiler by Mg-Alloy Galvanic Anode)

  • 정기철
    • 한국마린엔지니어링학회:학술대회논문집
    • /
    • 한국마린엔지니어링학회 2000년도 춘계학술대회 논문집(Proceeding of the KOSME 2000 Spring Annual Meeting)
    • /
    • pp.115-121
    • /
    • 2000
  • As the development of industry water quality of river is going to bad because of waste water of an industrial complex and general home agricultural chemicals exhaust of $SO_3$ and CO gas acid rain and so on. Corrosion damage of boiler factory equipment and so forth occur quickly due to using of the polluted water resulting in increasing leak accident. Especially working life of hot water boiler using the polluted water becomes more short and energy loss increases. The cathodic protection method is the most economical and reliable one to prevent corrosion damage of steel structures. Mg-base alloys galvanic anode protection of cathodic protection method is suitable for than application of hot water boiler using water with high specific resistance such as tap water. This paper is studied on the cathodic protection characteristics of how water boiler. In tap water and 0.001mol/$\ell$ NaCl solution the characteristics of anodic polarization of Mg-base alloys galvanic anode and tube material is investigated the measurement of cathodic protection potential according to the time elaspsed is carried out.

  • PDF