• Title/Summary/Keyword: properties UV

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Effect on Functional Properties of the Cotton Fabrics Treated by UV-absorbers with Nanosilver/DMDHEU Treatment (자외선 흡수제 처리 시 은나노/수지 첨가가 면직물의 기능성에 미치는 영향)

  • Kang, Mi-Jung;Kwon, Young-Ah
    • Journal of the Korean Society of Clothing and Textiles
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    • v.33 no.9
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    • pp.1463-1471
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    • 2009
  • Silver ions or silver nanoparticles have multi-functional properties. The cotton fabrics for providing multi-functional properties were treated with a nanosilver powder, UV-absorbers, and dimethyloldi-hydroxyethyleneurea (DMDHEU) alone and mixed solution. The physical properties, UV protection, antibacterial, and deodorizing properties of treated cotton fabrics were evaluated. The results were as a follows. The UV protection of cotton fabrics were increased by the application of a nanosilver and Uv-absorbers mixture. The UV protection of treated fabrics were improved by nanosilver/DMDHEU/UV-absorbers mixed solution. The wrinkle recovery properties of fabrics treated with DMDHEU and nanosilver improved. The stiffness of fabrics are decreased by a nanosilver/DMDHEU/UV-absorbers mixed solution. The antibacterial properties of the fabrics treated with nanosilver/DMDHEU/UV-absorbers mixed solution is 99.99%. The functional properties of cotton fabrics are shown to be better with aanosilver/DMDHEU/UV-absorbers mixed than treated with nanosilver alone.

Surface and Dielectric Properties of Oriental Lacquer Films Modified by UV-Curable Silicone Acrylate

  • Hong, Jin-Who;Kim, Hyun-Kyoung
    • Macromolecular Research
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    • v.14 no.6
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    • pp.617-623
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    • 2006
  • In order to achieve an oriental lacquer (OL) film with a thick consistency, UV-curable silicone acrylate (SA) was added to OL by a dual curing process. The addition of 5 wt% UV-curable SA to the OL fomulation enabled the preparation via a single drying step of a $77{\mu}m-thick$ film exhibiting excellent surface properties. FTIR-ATR was used to investigate the effect of UV-curable SA on the behavior of film formation during curing, and the relaxation behavior of the produced films was investigated by dielectric spectroscopy. Dielectric properties were measured in the frequency range $10^{-2}-10^5\;Hz$ at various temperatures between -100 and $200^{\circ}C$. The results demonstrated that OL modified by UV-curable SA has a higher glass transition temperature and stronger secondary relaxation at a lower temperature than the conventional OL system. The OL film modified with UV-curable SA was presumed to be harder at the surface and tougher than conventional OL film.

Evaluation on Physical and Mechanical Properties of Wood Plastic Composites Treated under Ultraviolet Irradiation (자외선을 처리한 목재 플라스틱 복합재의 물리 및 역학적 성질 평가)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.26 no.4
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    • pp.428-434
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    • 2015
  • In this study, we received each wood plastic composites (WPC) from three manufacturers. These WPCs were evaluated regarding their physical and mechanical properties of both before and after accelerated weathering by ultraviolet (UV) irradiation. The total time of exposure of the WPCs to UV irradiation was 1800 h. The water absorption, volumetric swelling and shrinkage of WPCs did not affected by UV irradiation. Among the mechanical properties, there was no significant differences in bending strength and screw withdrawal resistance of UV treated WPCs compared with those of reference WPCs. However, surface hardness of WPCs showed decrease under UV irradiation. Stereoscopic microscopy observation revealed deterioration of the surface layer polymer in all weathered WPCs by UV. Exposure of the WPCs to UV irradiation caused decomposition and disappearance of the polymer layer. From this result, we can estimate that damage of polymer by UV led to a decrease in the surface hardness of the WPCs. The wood flours retained original shape after accelerated weathering by UV irradiation.

Curing Properties of UV-ccurable Acrylate/Alkyd Resin Blends II (UV-curable Acrylate/Alkyd Resin 혼합계의 경화특성 II)

  • 남수용;이경옥;대평태문;구철회
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.157-166
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    • 2000
  • UV-curable resins have adventages of quick set, space saving, clean environment, and efficient use of energy. The polymerization induced phase separation has been studied to solve the problem in UV-curing of thick films and develop the new functional materials. On the exposure to UV irradiation, the dynamic elasticity properties were mesured for mixtures of alkyd resin and UV-cruable monomers which have different molecular structures and molecular weights. The curing rate increases with increasing temperature and UV intensity. In addition, The gel point is strongly influenced by temperature and UV intensity

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Physical and Optical Properties of Hydrophilic Tinted Lens Materials with the Fluoro-substituted Aniline Group

  • Park, Se-Young;Lee, Min-Jae;Sung, A-Young
    • Journal of Integrative Natural Science
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    • v.8 no.1
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    • pp.60-66
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    • 2015
  • The physical and optical properties of polymers with 2-fluoroaniline and 4-fluoroaniline added, which can be used for hydrophilic ophthalmic lenses, were investigated in this study. The UV-blocking properties of 2- and 4-fluoroaniline were also investigated by measuring their UV transmissibility. 2- and 4-Fluoroaniline were used as additives for the basic combination of HEMA, 5% AA, and 1% MMA, and the materials were copolymerized with EGDMA as the cross-linking agent and AIBN as the initiator. The refractive index, water content, optical transmittance, tensile strength, and contact angle were measured to evaluate the physical properties of the produced hydrogel lens. The measured physical properties of the hydrogel contact lens produced with the copolymerized polymer showed a refractive index of 1.425-1.436; a water content of 36.95-44.65%; a visual light transmittance of 66.0-81.0%; a tensile strength of 0.138-0.281 kgf; and a contact angle of $55.02-57.87^{\circ}$. The UV transmissibility was significantly reduced, which indicates that 2-fluoroaniline and 4-fluoroaniline have UV-blocking properties. This study showed that 2- and 4-fluoroaniline are expected to be used as UV-blocking materials in hydrogel ophthalmic lenses whose physical properties, such as their refractive index and water content, do not change.

Relationship between Printability and Rheological Properties of UV-curable Flexographic Ink

  • Jeong, Kyoung-Mo;Koseki, Ken'ichi
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.209-213
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    • 2006
  • Relationship between printability and rheological properties of UV flexographic (flexo) inks were investigated. UV flexo suspensions of carbon black in liquid medium having various binding materials such as acylate pre-polymer, di/multi-functional monomer, and diluents, were used as sample inks. Inks were characterized on a rheometer in terms of steady and dynamic behaviors. To understand the rheological properties of UV flexo inks, we must determine the specific rheological properties of chemical and/or physical interactions of their components (pigments, functional monomers, and pre-polymers). In particular, we discussed the influence of multi-functional monomers and the relationship between the rheological properties and transient networks formed by carbon black. In this study, we investigated the interrelationships between rheological properties of UV flexo inks and chemical and/or physical interactions of their components. To investigate correlations between the printability and the rheological behaviors induced by interfacial interactions between ink compositions, we carried out rheological tests of UV ink suspensions. The results were compared with printing tests so as to find out the relationship between printability and rheological properties of ink.

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Effect of UV Irradiation on the Color and Mechanical Properties of Catechu Dyed Fabrics (자외선 조사가 아선약 염색 직물의 색상 및 역학적 특성에 미치는 영향)

  • Nam, Ki-Yeon;Lee, Jung-Soon
    • Korean Journal of Human Ecology
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    • v.20 no.5
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    • pp.1009-1023
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    • 2011
  • This study was carried out to investigate the variations of catechu dyed fabrics under UV irradiation. Catechu dyed cotton and silk fabrics mordanted with Fe and Cu were irradiated with UV under dry and wet conditions, and then were evaluated on color changes and mechanical properties. Owing to UV irradiation, the K/S values of catechu dyed cotton fabrics increased until a certain amount of time but those of catechu-dyed silk fabrics increased continuously. Cu mordanting cotton fabrics showed the smallest changes due to the UV treatment, and silk fabrics mordanted with Fe showed the largest changes. Wetted fabrics were accelerated maillard browning by UV. Un-mordanted cotton fabrics treated with UV under dry conditions changed its YR color to Y, but changed its Y color to YR under wet conditions. However, mordanted cotton fabrics treated with UV didn't change their color. Dyed silk fabrics except those Fe mordanted and in wet conditions continued to keep their color after UV irradiation. Silk fabric mordanted with Fe under wet conditions changed its Y color to YR by UV irradiation. UV irradiation didn't affect the mechanical properties of catechu-dyed cotton and silk fabrics in any significant way.

Physicochemical Changes in UV-Exposed Low-Density Polyethylene Films

  • Salem, M.A.;Farouk, H.;Kashif, I.
    • Macromolecular Research
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    • v.10 no.3
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    • pp.168-173
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    • 2002
  • Unstabilized low-density polyethylene (LDPE) films and films formulated with hindered amine light stabilizer (HALS) were exposed to UV-radiation; and the physicochemical changes during photooxidation processes have been investigated using tensile, FTIR spectre-photometric and thermal analytical (DSC) techniques. The dependence of tensile properties (elongation- and stress-at-break), carboxyl index and heat of fusion on UV-irradiation time have been discussed. The use of HALS is found to be effective in maintaining the UV-mechanical properties of the LDPE films. The experimental results showed that there exists no correlation between mechanical properties and carbonyl index, whereas crystallinity correlates well with carbonyl index in unstabilized and stabilized films for irradiation times greater than 100 h. The rate of formation of carbonyl groups is found to be dependent on UV exposure time. Crystallinity of the film samples is strongly influenced by both exposure time and presence of HALS.

Preparation and Properties of UV Curable Hard Coating Materials on PET (자외선 경화형 고경도 PET 필름의 제조 및 특성)

  • Kim, Hyunjoon
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.1
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    • pp.35-41
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    • 2014
  • UV curable transparent hard coating materials have been developed to improve the mechanical and optical properties of PET substrate. The coating materials were synthesized using various urethane acrylate oligomers, monomers, photo initiators, and leveling agents. The materials were coated on PET substrates and UV cured. The hard coated PET films were shown to have the good scratch resistance and transparency. When the urethane acrylate oligomer with more functional groups was introduced into the coating solution, the mechanical and optical properties were improved. However the higher concentration of 9-functional oligomer resulted in the decrease of workability. The addition of trimethylolpropane ethoxylate$(EO/OH)_9$ triacrylate(TMPETA) to coating solution improved the workability and properties. As a result, the UV cured film from the formulation of urethane acrylate oligomer with 9-functional groups, TMPETA as a monomer, IRACURE 754 as a photo initiator and BYK-340 as a leveling agent showed the best mechanical and optical properties in this study.

UV-curing Behaviors and Mechanical Properties of UV-cured Polylactic Acid (PLA)

  • Lee, Seung-Woo;Park, Ji-Won;Park, Cho-Hee;Kim, Hyun-Joong;Eom, Young-Geun
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.2
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    • pp.134-140
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    • 2013
  • UV curing was introduced via a chemical treatment by adding small amounts of a hexafunctional acrylic monomer and a photoinitiator to improve the mechanical properties of PLA. This study also employed a semi-interpenetrated structured polymer network through the process of UV-curing. The UV curing behaviors were investigated using FTIR-ATR spectroscopy and gel fraction determination. Also, the tensile strength was investigated with different hexafunctional acrylic monomer contents and UV doses. The results showed that the crosslinking of UV-induced chemically treated PLA started at a low content of hexafunctional acrylic monomer, resulting in a significant improvement of the mechanical properties compared to those of neat PLA due to crosslinking.