• Title/Summary/Keyword: propane

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Study on Hepatoprotective and Antioxidant Activities of Korean Red Ginseng-Mixed Formula (홍삼복합제의 보간 및 항산화 작용에 대한 연구)

  • Kang, Chang-Hee;Kim, Dong-Hee;Ryu, Shi-Yong;Kim, Sung-Hoon
    • Korean Journal of Pharmacognosy
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    • v.31 no.4
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    • pp.383-389
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    • 2000
  • GRF (Korean Red Ginseng mixed formula) consists of six herbs such as Ginseng Radix rubra Koreana, Lycii Fructus, Artemisiae Capillaris Herba, Poria, and Glycyrrhizae Radix and Hoveniae Fructus. For the evaluation of hepatoprotective effect of GRF, the study was performed on protective effect against hepatic damage induced by galactosamine in vitro and ccl4 in vivo and also elucidate antioxidant activity. In vitro assay with 1.1 mM galactosamine, protection (%) was 44% (GR), and 58% (GRF-A) at 50 ug/ml. GRF effectively protected fatty degenertion and necrosis in murine hepatic damage induced by ccl4. For the -antioxidant study, GRF inhibited hemolysis of erythrocyte and decolored DPPH (2,2-diphenyl-l-picrylhydrazyl) free radical in a dose dependent manner more effetively than GR alone in vitro. GRF and GR significantly suppressed the time course $(1\;hr{\sim}6\;hr)-level$ of MDA (malondialdehyde) following AAPH (2,2'-azo-bis-(2-amidino -propane) dihydrochloride) treatment in vivo as compared with control data. From the results it can be concluded GR and GRF exerted the hepatoprotective effect by dint of antioxidant activity.

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Soot Formation and Combustion in Turbulent Flames (난류 화염 내에서의 매연 입자의 생성및 재연소)

  • 정종수;신현동;이춘식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.962-978
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    • 1989
  • A new model of the combustion rates of soot particle in turbulent flames has been suggested. This model applies the combustion rate of soot particles in laminar flames and uses local time-averaged quantities in order to consider the effect of the chemical reaction on the soot combustion in turbulent flames. The proposed rate equation has been tested for two propane-air turbulent round-jet diffusion flames and gives better predictions for the soot concentration field of two flames than the model previously used, especially in low temperature regions. A modified Monte carlo Method for analyzing radiative heat transfer of a flame also has been suggested and tested, which reveals good results.

Synthesis and Electrochemical Studies of Cu(II) and Ni(II) Complexes with Tetradentate Schiff Base Ligands

  • 조기형;정병구;김정희;전승원;임채평;최용국
    • Bulletin of the Korean Chemical Society
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    • v.18 no.8
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    • pp.850-856
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    • 1997
  • A series of tetradentate Schiff-base ligands; 1,3-bis(salicylideneimino) propane, 1,4-bis(salicylideneimino)butane, and 1,5-bis(salicylideneimino)pentane, and their Cu(Ⅱ) and Ni(Ⅱ) complexes have been synthesized. The properties of ligands and complexes have been characterized by elemental analysis, IR, NMR, UV-Vis spectra, molar conductance, and thermogravimetric anaylsis. The mole ratio of Schiff base to metal at complexes was found to be 1 : 1. All complexes were four-coordinated configuration and non-ionic compound. The electrochemical redox processes of the ligands and their complexes in DMF solution containing 0.1 M TEAP as supporting electrolyte have been investigated by cyclic voltammetry, chronoamperometry, differential pulse voltammetry at glassy carbon electrode, and by controlled potential coulometry at platinum gauze electrode. The redox process of the ligands was highly irreversible, whereas redox process of Cu(Ⅱ) and Ni(Ⅱ) complexes was observed as one electron transfer process of quasi-reversible and diffusion-controlled reaction. Also the electrochemical redox potentials of complexes were affected by chelate ring size of ligands. The diffusion coefficients of Cu(Ⅱ) and Ni(Ⅱ) complexes in DMF solution were determined to be 4.2-6.6×10-6 cm2/sec. Also the exchange rate constants were determined to be 3.6-9.7×10-2 cm/sec.

Study on Combustion Stability and Flame Structure of Injectors Through Subscale Combustion Tests (모델 연소시험을 통한 분사기 연소안정성과 화염구조에 대한 연구)

  • Song Ju-Young;Lee Kwang-Jin;Seo Seonghyeon;Han Yeoung-Min;Seol Woo-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.10a
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    • pp.245-250
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    • 2004
  • The objective of the present study is to conduct model combustion tests for various injectors to identify their combustion stability characteristics. Three different double swirl coaxial injectors with variation of a recess number have been tested for the comparative study of stability characteristic and flame structure. Gaseous oxygen and mixture of gaseous methane and propane have been employed for simulating actual propellants used for a fullscale thrust chamber. Upon test results, the direct comparison between various types of injectors can be realized for the selection of the best design among prospective injectors.

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The Study on Performance Characteristics in Refrigeration System using R717 and R22 as working fluid (냉매 R717과 R22를 작동유체로 이용한 냉동장치의 성능특성에 관한 연구)

  • Kim, Jin-Hyun;Kim, Jae-Geun;Kim, Jong-Gil;Kim, Yang-Hyun;Hong, Suk-Ju;Ha, Ok-Nam
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.495-500
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    • 2006
  • Nowadays HCFCs refrigerant are restricted because it cause depletion of ozone layer. However, natural gases such as ammonia as an organic compound, propane and propylene as hydrocarbon are easy and cheap to obtain as well as environmental. Accordingly, this experiment apply the $NH_3$ and R22 to study the performance characteristic from the superheat control and compare the energy efficiency of two refrigerants from the high performance. The condensing pressure of refrigeration system is increased from 15bar to 16bar and degree of superheat is increased from 0 to $10^{\circ}C$ at each condensing pressure. As the result of experiment, when comparing the each COP, we knew the $NH_3$ is suitable as the alternative refrigerant of the R22.

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Exergy Analysis and Optimization of Chiller System in Hydrogen Fueling Station Using R290 Refrigerant (R290 냉매를 이용한 수소 충전소 냉각시스템 엑서지 분석 및 공정 최적화)

  • HYEON, SOOBIN;CHOI, JUNGHO
    • Journal of Hydrogen and New Energy
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    • v.32 no.5
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    • pp.356-364
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    • 2021
  • During the hydrogen fueling process, hydrogen temperature inside the compressed tank were limited below 85℃ due to the allowable pressure of tank material. The chiller system to cool compressed hydrogen used R407C, greenhouse gas with a high global warming potential (GWP), as a refrigerant. To reduce greehouse gas emission, it should be replaced by refrigerant with a low GWP. This study proposes a chiller system for fueling hydrogen with R290, consisted in propane, by applying the C3 pre-cooled system use d in the LNG liquefaction process. The proposed system consisted of hydrogen compression and cooling sections and optimized the operating pressure through exergy analysis. It was also compared to the exergy efficiency with the existing system at the optimal operating pressure. The result showed that the optimal operating pressure is 700 kPa in 2-stage, 840 kPa/490 kPa in 3-stage, and the exergy efficiency increased by 17%.

The effect of blast-induced vibration on the stability of underground water-sealed gas storage caverns

  • Zhou, Yuchun;Wu, Li;Li, Jialong;Yuan, Qing
    • Geosystem Engineering
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    • v.21 no.6
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    • pp.326-334
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    • 2018
  • Underground water-sealed gas storage caverns have become the primary method for strategic storage of LPG. Previous studies of excavation blasting effects on large-scale underground water-sealed gas storage caverns are rare at home and abroad. In this paper, the blasting excavation for underground water-sealed propane storage caverns in Yantai was introduced and field tests of blasting vibration were carried out. Field test data showed that the horizontal radial velocity had a major controlling effect in the blasting vibration and frequencies would not cause the vibration velocity concentration effects. In terms of the influence of blasting vibration on adjacent caverns, the dynamic finite element model in LS-DYNA soft was established, whose reliability was verified by field test data. The numerical results indicated the near-blasting side was primary zone for the structural failure and tensile failure tended to occur in the middle of the curved wall on the near-blasting side. Meanwhile, the safety criterions for adjacent caverns based on stress wave theory and according to statistic relationship between peak effective tensile stress and peak particle velocities were obtained, respectively. Finally, with Safety Regulations for Blasting in China (GB6722-2014) taken into account, a final safety criterion was proposed.

Synthesis and Electrochemical Studies of Ni(Ⅱ) Complexes with Tetradentate Schiff Base Ligands

  • 정병구;임채평;국성근;조기형;최용국
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.173-179
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    • 1996
  • A series of tetradentate Schiff base ligands; [1,2-bis(naphthylideneimino)ethane, 1,3-bis(naphthylideneimino)propane, 1,4-bis(naphthylideneimino)butane, and 1,5-bis(naphthylideneimino)pentane] and their Ni(Ⅱ) complexes have been synthesized. The properties of these ligands and their Ni(Ⅱ) complexes have been characterized by elemental analysis, IR, NMR, UV-vis spectra, molar conductance, and thermogravimetric analysis. The mole ratio of Schiff base to Ni(Ⅱ) metal was found to be 1:1. The electrochemical redox process of the ligands and their Ni(Ⅱ) complexes in DMF and DMSO solution containing 0.1 M tetraethyl ammonium perchlorate (TEAP) as a supporting electrolyte have been investigated by cyclic voltammetry, chronoamperometry, differential pulse voltammetry, and controlled potential coulometry at glassy carbon electrode. The redox process of the ligands was highly irreversible, whereas redox process of Ni(Ⅱ) complexes were observed as one electron transfer process in quasi-reversible and diffusion-controlled reaction. The electrochemical redox potentials of the Ni(Ⅱ) complexes were affected by the chelate ring size of ligands. The diffusion coefficients of Ni(Ⅱ) complexes containing 0.1 M TEAP in DMSO solution were determined to be 5.7-6.9 × 10-6 cm2/sec. Also the exchange rate constants were determined to be 1.8-9.5 × 10-2 cm2/sec. These values were affected by the chelate ring size of ligands.

Preliminary Results of Tissue-Equivalent Proportional Counter (TEPC) Dosimeter for Measuring In-Situ Aviation Radiation

  • Nam, Uk-won;Park, Won-kee;Hwang, Junga;Sohn, Jongdae;Moon, Bongkon;Kim, Sunghwan
    • Journal of Astronomy and Space Sciences
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    • v.37 no.4
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    • pp.249-255
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    • 2020
  • We develop the tissue-equivalent proportional counter (TEPC) type's space radiation dosimeter to measure in-situ aviation radiation. That was originally developed as a payload of small satellite in the low-earth orbit. This dosimeter is based on a TEPC. It is made of an A-150 tissue-equivalent plastic shell of an internal diameter of 6 cm and a thickness of 0.3 cm. TEPC is filled with pure propane at 13.9 torrs to simulate a cell diameter of 2 ㎛. And the associated portable and low power electronics are also implemented. The verification experiments have been performed by the calibration experiments at ground level and compared with Liulin observation at aircraft altitude during the flight between Incheon airport (ICN) and John F. Kennedy airport (JFK). We found that the TEPC dosimeter can be used as a monitor for space radiation dosimeter at aviation altitude based on the verification with Liulin observation.

A Study on Hydrogen Energy Safety according to the Revitalization of the Hydrogen Economy (수소경제 활성화에 따른 수소에너지 안전성 고찰)

  • Park, Woo-Il;Tak, Song-Su;Lee, In-Woo;Hong, Soon-Pa
    • Journal of the Korean Institute of Gas
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    • v.25 no.6
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    • pp.74-79
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    • 2021
  • This study analyzed the current status of the global hydrogen economy and the safety of energy sources currently in use due to the activation of the hydrogen economy. Understanding the hydrogen economy, identifying government policy trends, comparing and analyzing characteristics with existing energy sources such as gasoline, propane, and methane, and evaluating damage impact for each energy source using PHAST, a quantitative damage impact assessment program. Using the analysis results, this study analyzes the safety of hydrogen energy to revitalize the hydrogen economy and suggests ways to improve safety.