• 제목/요약/키워드: product gas

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기술자립형 5kW 연료전지 시스템 구축을 위한 고효율 연료변환기 개발 (The development of High efficiency fuel processor for technical independence 5kW class fuel cell system)

  • 이수재;최대현;전희권
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.123.2-123.2
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    • 2010
  • Fuel Cell cogeneration system is a promising technology for generating electricity and heat with high efficiency of low pollutant emission. We have been developed 5kW class fuel cell cogeneration system for commercial and residential application. The fuel processor is a crucial part of producing hydrogen from the fossil fuels such as LNG and LPG. The 5kW class high efficiency fuel processor consists of steam reformer, CO shift converter, CO preferential oxidation(PrOx) reactor, burner and heat exchanger. The one-stage CO shift converter process using a metal oxide catalyst was adopted. The efficiency of 5 kW class fuel processor shows 75% based on LHV. In addition, for the purpose of continuous operation with load fluctuations in the commercial system for residential use, load change of fuel processor was tested. Efficiency of 30%, 50%, 70% and 100% load shows 75%, 75%, 73% and 72%(LHV), respectively. Also, during the load change conditions, the product gas composition was stable and the outlet CO concentration was below 5 ppm. The Fuel processor operation was carried out in residential fuel cell cogeneration system with fuel cell stack under dynamic conditions. The 5kW class fuel processor have been evaluated for long-term durability and reliability test including with improvement in optimal operation logic.

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유전자 알고리즘을 이용한 GMA 필릿 용접 비드형상 예측에 관한 연구 (A Study on Bead Geometry Prediction the GMA Fillet Welding using Genetic Algorithm)

  • 김영수;김일수;이지혜;정성명;이종표;박민호
    • Journal of Welding and Joining
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    • 제30권6호
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    • pp.126-132
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    • 2012
  • The GMA welding process involves large number of interdependent variables which may affect product quality, productivity and cost effectiveness. The relationships between process parameters for a fillet joint and bead geometry are complex because a number of process parameters are involved. To make the automated GMA welding, a method that predicts bead geometry and accomplishes the desired mechanical properties of the weldment should be developed. The developed method should also cover a wide range of material thicknesses and be applicable for all welding position. For the automatic welding system, the data must be available in the form of mathematical equations. In this study a new intelligent model with genetic algorithm has been proposed to investigate interrelationships between welding parameters and bead geometry for the automated GMA welding process. Through the developed model, the correlation between process parameters and bead geometry obtained from the actual experimental results, predicts that data did not show much of a difference, which means that it is quite suitable for the developed genetic algorithm. Progress to be able to control the process parameters in order to obtain the desired bead shape, as well as the systematic study of the genetic algorithm was developed on the basis of the data obtained through the experiments in this study can be applied. In addition, the developed genetic algorithm has the ability to predict the bead shape of the experimental results with satisfactory accuracy.

Volatile compounds and some physico-chemical properties of pastırma produced with different nitrate levels

  • Akkose, Ahmet;Unal, Nazen;Yalinkilic, Baris;Kaban, Guzin;Kaya, Mukerrem
    • Asian-Australasian Journal of Animal Sciences
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    • 제30권8호
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    • pp.1168-1174
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    • 2017
  • Objective: The aim of the study was to evaluate the effects of different nitrate levels (150, 300, 450, and 600 ppm $KNO_3$) on the volatile compounds and some other properties of pastırma. Methods: Pastırma samples were produced under the controlled condition and analyses of volatile compounds, and thiobarbituric acid reactive substances (TBARS) as an indicator of lipid oxidation, non-protein nitrogenous matter content as an indicator of proteolysis, color and residual nitrite were carried out on the final product. The profile of volatile compounds of pastırma samples was analyzed by gas chromatography/mass spectrometry using a solid phase microextraction. Results: Nitrate level had a significant effect on pH value (p<0.05) and a very significant effect on TBARS value (p<0.01). No significant differences were determined in terms of $a_w$ value, non-protein nitrogenous substance content, color and residual nitrite between pastırma groups produced by using different nitrate levels. Nitrate level had a significant (p<0.05) or a very significant (p<0.01) effect on some volatile compounds. It was determined that the amounts and counts of volatile compounds were lower in the 450 and especially 600 ppm nitrate levels than 150 and 300 ppm nitrate levels (p<0.05). While the use of 600 ppm nitrate did not cause an increase in residual nitrite levels, the use of 150 ppm nitrate did not negatively affect the color of pastırma. However, the levels of volatile compounds decreased with an increasing level of nitrate. Conclusion: The use of 600 ppm nitrate is not a risk in terms of residual nitrite in pastırma produced under controlled condition, however, this level is not suitable due to decrease in the amount of volatile compounds.

탈황석고를 사용한 미네랄 하이드레이트 단열소재의 물리적 특성 연구 (Physical Properties of Mineral Hydrate Insulation Used Desulfurization Gypsum)

  • 박재완;라윤호;추용식
    • 한국건설순환자원학회논문집
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    • 제2권4호
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    • pp.291-296
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    • 2014
  • 건축물 에너지 사용량과 온실가스 배출량 감소를 목적으로, 열적 물성 등이 향상된 새로운 단열소재가 개발 사용되는 추세이다. 이중 기존 단열소재의 문제점 (가연성, 처짐, 수분 취약성, 단열성능 저하 등)을 보완한 미네랄 하이드레이트 소재가 새롭게 사용되고 있다. 미네랄 하이드레이트는 건축물 구조체로 사용되는 ALC의 제조방법과 유사하나, 구조체가 아닌 단열소재만으로 사용된다는 특징을 갖는다. 미네랄 하이드레이트 제조를 위해서는 시멘트, 생석회 및 무수석고 등이 사용되며, 무수석고는 전량 수입에 의존하고 있다. 따라서 본 연구에서는 수입대체효과 뿐만 아니라, 폐기물 재활용 측면에서 무수석고를 대체하여 석유제조 공정 부산 탈황석고를 사용하고자 하였다. 탈황석고를 미네랄 하이드레이트 원료로 사용할 경우, 무수석고 전량과 생석회 일부를 대체할 수 있었다. 더불어 탈황석고를 사용한 미네랄 하이드레이트는 기존 무수석고 사용시와 유사한 열적, 물리적 특성도 발현되었다.

Analysis of Essential oil, Quantification of Six Glycosides, and Nitric Oxide Synthase Inhibition Activity in Caryopteris incana

  • Nugroho, Agung;Lee, Sang Kook;Kim, Donghwa;Choi, Jae Sue;Park, Kyoung-Sik;Song, Byong-Min;Park, Hee-Juhn
    • Natural Product Sciences
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    • 제24권3호
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    • pp.181-188
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    • 2018
  • Caryopteris incana (Verbenaceae) has been used to treat cough, arthritis, and eczema in Oriental medicine. The two fractions ($CHCl_3-$ and BuOH fractions) and the essential oil of the plant material were subjected to the inducible nitric oxide synthase (iNOS) assay. The $IC_{50}$ of the $CHCl_3$ fraction and the essential oil on LPS-induced macrophage RAW 264.7 cells were $16.4{\mu}g/mL$ and $23.08{\mu}g/mL$, respectively. On gas chromatography (GC)-mass spectroscopy (MS) analysis, twenty-five components representing 85.5% amount of total essential oil were identified. On the chromatogram, three main substances, trans-pinocarveol, cis-citral, and pinocarvone, occupied 18.8%, 13.5% and 18.37% of total peak area. Furthermore, by HPLC-UV analysis, six compounds including one iridoid (8-O-acetylharpagide)- and five phenylethanoid glycosides (caryopteroside, acteoside, phlinoside A, 6-O-caffeoylphlinoside, and leucosceptoside A) isolated from the BuOH fraction were quantified. The content of six compounds were shown as the following order: caryopteroside (162.35 mg/g) > 8-O-acetylharpagide (93.28 mg/g) > 6-O-caffeoylphlinoside (28.15 mg/g) > phlinoside (22.60 mg/g) > leucosceptoside A (16.87 mg) > acteoside (7.05 mg/g).

고농도 알코올 혼합 석유제품이 자동차 성능 및 배출가스에 미치는 영향 연구 (The Study on Effect of Emissions and Performance of a Conventional Vehicle using the High Concentration Alcohol Blended Petroleum Product)

  • 김성우;도진우;김기호;하종한
    • 한국수소및신에너지학회논문집
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    • 제26권6호
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    • pp.629-637
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    • 2015
  • As concern about energy security and global warming many countries have been making effort to reduce fossil fuel. In the case of US, as one of the efforts, the standards of the alcohol vehicle fuels(including blended with gasoline) have been established. Alcohol is known that make some trouble concerning startability, durability and corrosion when using as fuel of a conventional vehicle. For these reason, alcohol usage needs not only the fuel standard, but also a modified car. In the case of Korea, although there are no the standard and the modified vehicle yet, high concentration alcohol blended fuel has being sold at illegal market. In this study, exhaust gas and performance of the conventional vehicle that alcohol(methanol and isopropyl alcohol) blends were fueled were measured to notify danger of using them without preparation of institutional arrangements. Also, to analyze correlation characteristics of the fuels and them, property test of the fuels was conducted. The test result show that bad-startability caused by low RVP and high T10 affected increase in NMOG and CO. NOx was increased under the highest short term fuel trim caused by high Oxygen content and low NHV of alcohol. According to increasing as alcohol content, fuel economy and acceleration ability were decreased but $CO_2$ was not significantly decreased.

Tetrafluoroethylene 흡입에 의한 급성폐손상 1예 (A Case of Acute Lung Injury Caused by Tetrafluoroethylene Inhalation)

  • 이수옥;최은정;김가영;김준철;박정철;정치영;김연재;이병기
    • Tuberculosis and Respiratory Diseases
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    • 제62권3호
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    • pp.223-226
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    • 2007
  • 저자들은 도색공장에서 작업 도중 우연히 누출된 tetrafluoroethylene 가스의 흡입으로 인하여 급성폐손상을 받았으나 보존적 치료로 별다른 합병증 없이 비교적 짧은 기간에 치유된 남자 환자 1예를 경험하였기에 문헌고찰과 함께 보고하는 바이다.

김치의 위생학적 우수성 (Hygienic Superiority of Kimchi)

  • 김용석;신동화
    • 한국식품위생안전성학회지
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    • 제23권2호
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    • pp.91-97
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    • 2008
  • Kimchi is a representative traditional food in Korea and a type of vegetable product that is the unique complex lactic acid fermentation in the world. It can be considered as a unique fermented food generated by various flavors, which are not included in raw materials, that can be generated by mixing and fermenting various spices and seasonings, such as red pepper powder, garlic, ginger, and salted fish, added to Chinese cabbages. Functionalities in Kimchi have been approved through several studies and the probiotic function that is mainly based on lactic acid bacteria including their physical functions in its contents has also verified. Studies on the verification of the safety of Kimchi including its physiological functions have been conducted. In particular, the function of lactic acid bacteria, which is a caused of the fermentation of Kimchi. Although the lactic acid bacteria contributed to the fermentation of Kimchi is generated from raw and sub-materials, the lactic acid bacteria attached on Chinese cabbages has a major role in the process in which the fermentation temperature and dominant bacteria are also related to the process. The salt used in a salt pickling process inhibits the growth of the putrefactive and food poisoning bacteria included in the fermentation process of Kimchi and of other bacteria except for such lactic acid bacteria due to the lactic acid and several antimicrobial substances generated in the fermentation process, such as bacteriocin and hydrogen peroxide. In addition, the carbon dioxide gas caused by heterolactic acid bacteria contributes to the inhibition of aerobic bacteria. Furthermore, special ingredients included in sub-materials, such as garlic, ginger, and red pepper powder, contribute to the inhibition of putrefactive and food poisoning bacteria. The induction of the change in the intestinal bacteria as taking Kimchi have already verified. In conclusion, Kimchi has been approved as a safety food due to the fact that the inhibition of food poisoning bacteria occurs in the fermentation process of Kimchi and the extinction of such bacteria.

Photoproduction of Hydrogen from Acetate by Rhodopseudomonas: Effect of Culture Conditions and Sequential Dark/Light Fermentation

  • Oh, You-Kwan;Seol, Eun-Hee;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XIII)
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    • pp.422-427
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    • 2003
  • Rhodopseudomonas palustris P4 can produce $H_2$ either from CO by water-gas shift reaction or from various sugars by anaerobic fermentation. Fermentative $H_2$ production by P4 is fast, but its yield is relatively low due to the formation of various organic acids. In order to increase $H_2$ production yield from glucose, P4 was investigated for the photo-fermentation of acetate which is a major by-product of fermentative $H_2$ production. Experiments were performed in batch modes using both light-grown and dark-grown cells. When the dark-grown P4 was challenged with light and acetate, $H_2$ was produced with the consumption of acetate after a lag period of 25 h. $H_2$ production was inhibited when a nitrogen source, especially ammonium, is present. When the dark-fermentation broth containing acetate was adopted for photo-fermentation with light-grown cells, $H_2$ production and concomitant acetate consumption occurred without a lag period. The $H_2$ yield was estimated as 2.4 - 2.8 mol $H_2/mol$ acetate and the specific $H_2$ production rate was as 9.8 ml $H_2/g$ cell${\cdot}$h, The fact that a single strain can perform both dark- and light-fermentation gives a great advantage in process development Compared to a one-step dark-fermentation, the combined dark- and light-fermentation can increase the $H_2$ production yield on glucose by two-fold.

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산부인과용 $CO_2$ 연속형 레이저의 고압출력 모듈에 따른 펄스트랜스 안정화 특성연구(II) (Special quality research by pulse transformer stabilization by high tension output module of medical ultra series laser II)

  • 김휘영
    • 한국컴퓨터산업학회논문지
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    • 제8권1호
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    • pp.49-56
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    • 2007
  • 빔의 열적효과는 세포조직의 서로 다른 구성성분과 레이저 빔의 서로 다른 파장에서 다른결과를 나타내며 세포조직에서 온도증가는 먼저 응고가 이루어지고, 절단이나 탄화과정이 일어나며 $300^{\circ}$이상에서는 세포조직의 파괴에 의한 증발이 발생하게 된다. $CO_2$ 레이저는 최소한 조직손상으로 이러한 효과를 얻는데 최적이라고 보며 0.1mm의 최소한의 세포조직 깊이에서 일어나는 효과의 근본적인 장점은 생체조직이나 내장기관에 안정적이다. $CO_2$레이저사용에 있어서 단점은 무엇보다도 세포파괴에서 생성되는 입자들의 부품흡착 등으로 결과적으로 레이저의 출력감소가 일어나는데, 영 전압, 영 전류 스위칭 포워드 컨버터를 도입하여 기존의 하드 스위칭 포워드 컨버터에 있어서 Turn-off, on시 발생되는 스위칭 방식을, 적용함으로써 1차 측 스위칭 소자의 Turn-off, on시 영전압, 영전류 스위칭을 이루어 정밀도가 요구되는 산부인과용 $CO_2$ 연속 형 레이저의 고압출력 모듈에 따른 펄스 트랜스의 안정화에 필수적으로 기여하며, 레이저 출력과 안정화가 되도록 설계 및 제작한 결과, 기존제품보다 향상된 결과를 가져왔다. 추후 시스템적으로 보완을 하면 우수한 결과가 될 것으로 사려된다.

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