• Title/Summary/Keyword: product gas

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New Technology Development for Production of Alternative Fuel Oil from Thermal Degradation of Plastic Waste (폐플라스틱의 열분해에 의한 대체 오일 생산의 신기술 개발)

  • Lee Kyong-Hwan;Roh Nam-Sun;Shin Dae-Hyun
    • Resources Recycling
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    • v.15 no.1 s.69
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    • pp.37-45
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    • 2006
  • For treating a huge amount of plastic waste with the environment problem, pyrolysis of plastic waste into alternative fuel oil is one or important issue in recycling methods. This study was introduced over the trend or generation of plastic waste, in Korea pyrolysis technology in domestic and foreign countries, basic technology in pyrolysis process and new technology of pyrolysis developed in KIER (Korea Institute of Energy research). The characteristics of process developed in KIER are the continuous loading treatment or mixed plastic waste with an automatic control system, the minimization of wax production by circulation pyrolysis system in non-catalytic reactor, the reuse of gas produced and the oil recovery from sludge generated in pyrolysis plant, which have greatly the advantage economically and environmetally. The experiment result data in 300 ton/yr pilot plant showed about $81\;wt\%$ liquid yield for 3 days continuous reaction time, and also the boiling point distribution of light oil (LO) and heavy oil (HO) produced in distillation tower was a little higher than that of commercial gasoline and diesel, respectively.

The Source Identification of Spilled Oil by Pristane/Phytane Ratio

  • Bae, Il-Sang;Kweon Jung;Oh, Hyun-Jung;Shin, Ho-Sang;Lee, Jae-Young
    • Journal of Soil and Groundwater Environment
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    • v.8 no.4
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    • pp.64-67
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    • 2003
  • In order to identify the origin and nature of the spilled oil in the potential source, we analyzed the concentrations of specific fuel constituents in fuel standard and environmental samples. The ratios of pristane/phytane are virtually unaltered because these compounds have the same bolatility in environmental samples. These were useful to identify the source of the fuel oil and to assess the effect of microbial degradation and weathering of the fuel oil. We analyzed the ratios of pristane/phytane in neat white kerosene, boiler kerosene, JP-8 and diesel products from L and S gas station. The ratios of pristane/phytane in L-white kerosene and JP-8 was 3.10 $\pm$0.03 and 1.77 $\pm$ 0.01, respectively. Otherwise, the ratios of pristane/phytane in water phase after distribution of fuel oil and water was 2.97 $\pm$0.02 in case of white kerosene and 1.65 $\pm$ 0.02 in case of JP-8. It is apparent from the results that the ratios of pristane/phytane were as product-specific, especially between kerosene and JP-8, and therefore, can also be used for fuel type identification in free products and groundwater samples which were collected in monitoring wells.

Study on Fuel Specificity and Harmful Air Pollutants Factor of Agglomerated Wood Charcoal (시중에 유통되고 있는 성형목탄의 연료특성과 유해인자에 대한 연구)

  • JEOUNG, Taek Yong;YANG, Seung Min;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.2
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    • pp.253-266
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    • 2020
  • This study selected three types of agglomerated wood charcoal (Agglomerated wood charcoal with charcoal powder, Carbonized wood briquette, Ignition-type of perforated charcoal) that are in circulation in Korea among fuel-type wood products and analyzed the fuel characteristics, harmful substance content, and emissions of air pollutants generated by combustion. The first results showed that charcoal-grilled carbon, which is the raw material of charcoal, produced higher CO than saw-billed carbon. The second result is that the emission standards of air pollutants generated by the combustion of molded wood coal are not up to the emission standards of nitrogen oxides and sulfur oxides in the entire product, compared with the emission criteria of the atmospheric environment preservation method (based on 2019, carbon monoxide: 200 ppm, nitrogen oxides, 150 ppm sulfur oxides: 100 ppm), but the carbon dioxide moulding and carbon dioxide levels were not up. Based on the analysis of combustion gas generated during combustion derived from this study, future research is needed for comparing with the emission standards of pellets, which are wood products for fuel, among the existing biomass burning standards and for reducing carbon monoxide generated during incomplete combustion of agglomerated wood charcoal.

The Doubtful Existence of Resource Curse (자원의 저주에 대한 비판적 고찰)

  • Kim, Dong Koo
    • Environmental and Resource Economics Review
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    • v.22 no.2
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    • pp.215-250
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    • 2013
  • The term, "resource curse", is widely used to describe how countries rich in natural resources, such as oil, natural gas, and certain minerals, are unable to utilize that wealth to boost their economies. Contrary to previous research on the topic, this study has demonstrated that natural resources have a strong positive correlation with a country's economy. It likewise confirmed that this result is robust with broad sets of exogenous variables, and that the positive impact of natural resources on the economy remains significant with the inclusion of capital stock per worker. In this sense, it is doubtful that resource curse actually exists in the long-run. On the other hand, this study tested whether the quality of institutions has any relation with natural resource endowments if the positive effect of natural resource endowments on the gross domestic product (GDP) is adequately controlled for. In contrast to findings of Alexeev and Conrad (2009), if the former Soviet Union (FSU) countries are included, it seems that there might be a negative and statistically significant relationship between large endowments of natural resources and the quality of institutions. However, this negative relationship loses its significance and some positive albeit insignificant relationships are confirmed in a considerable number of cases when the FSU countries are excluded in the sample. That is, the negative relationship results from the inclusion of the FSU countries. This result is believed to happen by a temporary coincidence of events, a natural resource windfall and political and economic instability during the transition of the FSU countries. Therefore, the argument that resource abundance harms the institutional quality is confirmed to be a little groundless.

A Study of the Microstructure and Impurity Characteristics of Cast Bronze in Koryo Period (고려시대의 청동 주물에서 관찰되는 불순물(Cu2S) 특성 연구)

  • Choi, Jung Eun
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.313-320
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    • 2016
  • The aim of this study was to obtain information on the ancient material of cast bronze through an investigation of the microstructure and impurity characteristics of the casting. Three Koryo bronze coins were analyzed using an optical microscope, scanning electron microscope, and electron dispersive X-ray analyses were used to determine the composition of the specimens. The three coins had 4 phases: ${\alpha}phase$, ${\delta}phase$, Pb, and impurities ($Cu_2S$). $Cu_2S$ was found to exist near Pb or in ${\delta}phase$. $Cu_2S$ is the inter mediate product of copper ore refining. Therefore, the copper ore was not completely refined. To find out the characteristic of $Cu_2S$, we melt 1)Koryo bronze coin and 2)$Cu_2S$ and Pb powder at 1273 K. The reaction between $Cu_2S$ and Pb at 1273 K yielded fine Cu and black gas, which was identified to be PbS and is presented below: $Cu_2S+Pb{\rightarrow}PbS{\uparrow}+2Cu$.

Derivatization and Residual Determination of MCPP in Soil Leachate (토양 침투수중 MCPP의 유도체화 및 잔류분석)

  • Hong, Moo-Ki;Smith, Albert E.
    • Korean Journal of Environmental Agriculture
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    • v.13 no.2
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    • pp.199-208
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    • 1994
  • Analytical methods for the determination of the derivatives of the herbicide (${\pm}$)-2-(4-chloro-2-methylphenoxy)propionic acid (MCPP) by capillary column gas chromatography with mass spectrometer (GC-MS) and electron-capture detection (GC-ECD) were studied. A successful procedure was introduced for the ester preparation using $H_2SO_4$, as the catalyst and the alcohol 2,2,2-trichloroethanol (TCE) or 2,2,2-trifluoroethanol (TFE). The identificaiton and elucidation of MCPP by GC-MS spectrometry following the esterification with diazomethane, $BF_3$/methanol, $H_2SO_4$/methanol, TCE, TFE, or pentafluorobenzyl bromide (PFB) were carried out. A comparison of the response-sensitivities among those MCPP esters was made with GC-ECD. Although the methylation product of MCPP was confirmed by GC-MS, its low sensitivity to the ECD limited the detection of MCPP. TCE, TFE, and PFB derivatization methods resulted in a high rate of MCPP esterifications and very sensitive ECD molecular responses. Based on efficiency, convenience, worker safety, and least sample contamination, TFE esterificaiton was considered as the superior method for MCPP analysis to the other methods of derivatization. An accurate method is described for quantifying MCPP in soil leachates by GC-ECD at very low concentrations without the requirement of a complicated clean-up process. As a result, MCPP residues at concentrations of less than $0.1{\mu}g$ in 100ml soil leachate were detected.

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Development of Breakfast Sausage Prepared with Freeze-Dried Kimchi Powder (동결김치분말을 첨가한 Breakfast sausage의 개발)

  • Cho, Yong-Bum
    • Journal of the Korean Society of Food Culture
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    • v.20 no.4
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    • pp.391-396
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    • 2005
  • This study investigated the optimal amount of FDKP(Freeze Dried Kimchi powder) to be added in BFS(breakfast sausage) in order to develop a new Korean style processed food, which can be used as a useful export item. The results of the study suggested that BFSs prepared with FDKP were more favored than BFS without FDKP. The specific findings are as follows: The BFS added with 3% FDKP was favored most in color, taste, softness and overall acceptability by the trained sensory panels. However, in case of unbaked BFS, 9% addition of FDKP was found to have preferred color. Overall, this study suggests that 3% of FDKP was optimal for the newly developed Kimchi BFS. On top of that this study also showed possibility of standardization of product using Korean traditional Kimchi.

The development of the Ionizer using clean room (청정환경용 정전기 제거장치 개발)

  • Jeong, Jong-Hyeog;Woo, Dong Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.603-608
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    • 2018
  • Although the voltage-applied discharge method is most widely used in the semiconductor and display industries, periodic management costs are incurred because the method causes defects due to the absorption of ambient fine dust and causes emitter tip contamination due to the discharge. The emitter tip contamination problem is caused by the accumulation of fine particles in ambient air due to the corona discharge of the ionizer. Fuzzy ball generation accelerates the wear of the emitter tip and deteriorates the performance of the ionizer. Although a mechanical cleaning method using a manual brush or an automatic brush is effective for contaminant removal, it requires management of additional mechanical parts by the user. In some cases, contaminants accumulated in the emitter may be transferred to the wafer or product. In order to solve this problem, we developed an ionizer for a clean environment that can remove the pencil-type emitter tip and directly ionize the surrounding gas molecules using the tungsten wire located inside the ion tank. As a result of testing and certification by the Korea Institute of Machinery and Materials, the average concentration was $0.7572particles/ft^3$, the decay time was less than two seconds, and the ion valance was 7.6 V, which is satisfactory.

Studies on the Interaction of Biocides and Ethylsilicate Consolidants for Stone Monument (석조문화재 살생물제와 에틸실리게이트 강화제의 상호작용에 관한 연구)

  • Do, Jin-Young;Yun, Yun-Kyung;Lee, Tae-Jong;Kyung, Hye-Sun
    • Journal of Conservation Science
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    • v.21
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    • pp.73-88
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    • 2007
  • In this paper, the interaction between five biocides(commercial) and two ethylsilicate consolidants for stone monuments, reacted in different sequence, has been studied. Through the structures, weight and gelation time of mixture of biocides and consolidants have been evaluated the reactivity of biocide alone, the reactivity of consolidants and biocides, the reactivity of consolidants and dried biocide, and the reactivity of ethylsilicate gel and biocides. The tested biocides show quite different properties from those of consolidants; after evaporation, some biocides are remained white salt crystals, another need the long time for evaporation and one biocide shows pale brown color. The results have shown an interaction of the tested products each other in some application sequences of the products. When the application of liquid state biocides with consolidants, it was noted that some biocide seem to interfere with the formation of gel due to reaction of consolidants and water and salts in biocides. In the reaction of ethylsilicate with dried biocides have shown a heterogenous gel(transparent layer with ethylsilicate alone and white layer which is mixed biocide and ethylsilicate) and many cracks in product due to the different shrinkage, thus the products don't play a role as consolidants. There is no change in structures and color in reaction of the gas state biocide and ethylsilicate gel.

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Evaluation of high concentration carbon dioxide reduction efficiency using L-alanine·salt scrubber in Liquor factory (주류공정 내 L-alanine·염 스크러버를 이용한 고농도 이산화탄소 저감 효율 평가)

  • Kim, Heung-Rae;Lee, June-Hyung;Park, Hyung-June;Park, Ki-Tae;Park, Il-Gun
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.2
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    • pp.214-223
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    • 2020
  • This study evaluated CO2 removal efficiency, monitoring data analysis / evaluation efficiency and energy reduction efficiency in the liquor factory by L-alanine applied scrubber. The average removal rate of the scrubber was 90.45%, and it was confirmed that the removal efficiency was excellent above 10,000ppm of inlet CO2 concentration. After the scrubber operation, the CO2 concentration in the workplace was maintained under 2,000ppm(the carbon dioxide reduction efficiency was about 74%). and the energy saving efficiency was calculated to 7.26% by reducing the power consumption. As a result of applying the developed product, it was possible to improve the working environment of workers by reducing the carbon dioxide concentration in the workplace at low concentration without ventilation, and to reduce the energy consumption. Therefore, it is expected that the scrubber will be useful as a high CO2 removal process in food and liquor factories.