• Title/Summary/Keyword: product gas

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Studies on the Spatial Analysis for Distribution Estimation of Radon Concentration at the Seoul Area (서울지역 라돈농도의 분포예측을 위한 공간분석법 연구)

  • Baek, Seung-A;Lee, Tae-Jung;Kim, Shin-Do;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.5
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    • pp.538-550
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    • 2008
  • Radon is an invisible, odorless, and radioactive gas. It is formed by the disintegration of radium, which is a decay product of uranium. Some amounts of radon gas and its products are present ubiquitously in the soil, water, and air. Particularly high radon levels occur in regions of high uranium content. Although radon is permeable into indoor environment not only through geological features (bed rock and permeability) but also through the construction materials and underground water, the radiation from the geological features is generally main exposure factor. So there can be a problem in a certain space such as the underground and/or relatively poor ventilation condition. In this study, a GIS technique was used in order to investigate spatial distribution of radon measured from sub- way stations of 1 thru 8 in Seoul, Korea in 1991, 1998, 2001, and 2006. Spatial analysis was applied to reproduce the radon distribution. We utilized spatial analysis techniques such as inverse distance weighted averaging (IDW) and kriging techniques which are widely used to relate between different spatial points. To validate the results from the analyses, the jackknife technique for an uncertainty test was performed. When the number of measuring sites was less than 100 and also when the number of omitted sites increased, the kriging technique was better than IDW. On the other hand, when the number of sites was over 100, IDW technique was better than kriging technique. Thus the selection of analytical tool was affected sensitives by the analysis based on the number of measuring sites.

Development of 25.8kV class solid insulated switchgear (25.8kV 고체절연스위치기어 개발)

  • Lee, J.H.;Ma, J.H.;Yu, L.;Lee, J.G.;Won, S.Y.;Lee, S.W.;Kim, Y.G.;Kil, G.S.
    • Proceedings of the KIEE Conference
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    • 2008.10c
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    • pp.226-228
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    • 2008
  • In recent years, the companies of electric power equipment for MV and HV classes trend to develop the eco-friendly insulated(solid, eco-gas, air etc.) switchgear which replaces existent SF6 gas insulated switchgear due to environmental problems such as global warming and so on. This paper makes reference to the newly developed Solid Insulated Switchgear (SIS) which uses the eco-friendly material such as epoxy for insulation. The insulation of the solid insulated switchgear (SIS) is composed of an epoxy, vacuum and air. The solid insulated switchgear (SIS) is a slate of the art product. The advantages of SIS are advanced reliability, economical efficiency, safety, maintenance free, reduction of installation area and the protection of environment. The solid insulated switchgear (SIS) is FE Analyzed such as electromagnetic, mechanical, thermal and fluid in order to find the optimal design. Thens SIS has been verified by international standard test. (IEC 62271 - 100 and so on.) As a result of this, the solid insulated switchgear (SIS) has been estimated as an alternative for eco-friendly MV class switchgear.

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Storage Quality of Minimally Processed Onions as Affected by Seal-Packaging Methods (포장방법에 따른 신선 편의가공 양파의 저장품질 변화)

  • Hong, Seok-In;Son, Seok-Min;Chung, Myong-Soo;Kim, Dong-Man
    • Korean Journal of Food Science and Technology
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    • v.35 no.6
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    • pp.1110-1116
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    • 2003
  • The effects of packaging methods on the storage quality of minimally processed (prepeeled) onions were investigated to determine the optimal packing design. Various packaging treatments used for modifying headspace atmospheres included two passive MAP using LDPE and PP films, two active MAP using a gas mixture of 20% $O_2/10%\;CO_2/balance\;N_2$ and an ethylene scavenging sachet, and moderate vacuum packaging (MVP). The quality attributes of onion samples were evaluated periodically in terms of flesh weight loss, color of cut surface, decay ratio, microbial counts, and sensory properties during storage at $10^{\circ}C$ for 28 days. Packaging methods did not significantly influence surface color, weight loss, and microbiological populations of mesophiles, psychrotrophs, and lactic acid bacteria. They did, however, affect sensory characteristics as well as decay occurrence. Results indicated that seal-packaging with a gas-permeable plastic film under a mild vacuum condition could retain better onion quality in terms of microbial decay and visual sensory aspects as compared with the other packages.

Catalytic Reactions of Ethanol and Acetaldehyde Over $TiO_2$-supported Gold Catalysts

  • Kim, Jeong-Jin;Kim, Yu-Gwon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.264-264
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    • 2012
  • As an environment-friendly alternative energy resource, ethanol may be used to obtain hydrogen, a clean energy source. Thus, studies on catalytic reactions involving ethanol have been studied to understand the underlying principles in the reaction mechanism using various oxide-supported catalysts. Among them, Au-based catalysts have shown a superior activity in producing hydrogen gas. In the present study, Au/$TiO_2$ catalysts were prepared by deposition-precipitation method to understand their catalytic activities toward ethanol and acetaldehyde with increasing gold loading, especially at the very low Au loading regime. A commercially available $TiO_2$ (Degussa P-25) was employed and the Au loading was varied to 0, 0.1, 0.5, and 1.0 wt% respectively. The catalysts showed characteristic x-ray diffraction (XRD) features at $2{\theta}=78.5^{\circ}$ that could be assigned to the presence of gold nanoparticles. Its reactivity measurements were performed under a constant flow of ethanol and acetaldehyde at a flow rate of ${\sim}0.6{\mu}mol/sec$ and the substrate temperature was slowly raised at a rate of 0.2 K/sec. We observed that the overall reactivity of the catalysts increased with increasing Au loading along with selectivity favoring dehydrogenation to product hydrogen gas. In addition, we disclosed various reaction channels involving competitive reaction paths such as dehydrogenation, dehydration, and condensation. In addition, subsequent reactions of acetaldehyde obtained from dehydrogenation of ethanol, were found to occur and produce butene, crotonaldehyde, furan, and benzene. Based on the results, we proposed overall reaction pathways of such reaction channels.

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A Study on the Desulfurization of Petroleum Cokes by Microwave Heating (마이크로웨이브 가열에 의한 석유 코크스의 탈황에 관한 연구)

  • Park, Min-Gyu;Kang, Tae-Won
    • Clean Technology
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    • v.8 no.1
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    • pp.11-17
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    • 2002
  • Petcokes is the final product obtained from a refinery process. This petcokes includes high percentage of inorganic and sulfur compounds. Currently, the petcokes produced from domestic refinery plants include more than 6% of sulfur. To use petcokes as valuable raw materials, the weight percentage of sulfur must be lower than 2% of sulfur. Solvent extraction, thermal desulfurization, and hydro-desulfurization have been used to remove the sulfur. In this study, we attempted new approach to remove the sulfur introducing microwave energy. Microwave increase the reaction rates by providing the fast heating and disconnecting the bonding structure of the molecules. The experiments of microwave thermal desulfurization and microwave plus hydrogen gas were carried out to remove the sulfur. We obtained 68.3% of sulfur removal rate with the 2 hours of reaction time and 1835 W of microwave powder. In the experiment of microwave with hydrogen gas, we obtained 86.4% of sulfur removal rate with the 1.5 hours of reaction time and 1835 W of microwave power. If we increase reaction time or decrease the particle size of petcokes, we expect more than 90% of sulfur removal.

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Role of Chemical Fertilizer and Change of Agriculture in Korea (우리나라 농업의 변천과 비료의 역할)

  • Chung, Doug-Y.;Lee, Kyo-S.
    • Korean Journal of Agricultural Science
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    • v.35 no.1
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    • pp.69-83
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    • 2008
  • The self-supply rate of Korea in 2006 was approximately 27.3 % by importing 13.99Mt for 19.79Mt of demanded amount. Among the imported crops, wheat, corn, and soybean consumed 95 % for the total imported amount, and wheat, corn, and soybean were 3.5Mt(Table use : 0.22Mt; Feed stuff : 0.13Mt), 8.7Mt(Table use : 0.19Mt; Feed stuff : 0.68Mt), and 1.2Mt (Table use : 0.03Mt; Feed stuff : 0.09Mt), respectively. On the other hand, our government has prepared the strategies for a great fear of food according to sharp price rise of the international crops by maintaining the self-supply rate of 5 % excluding 5.23Mt of rice in Korea. Also concern for recycled energy known as future energy for era of high oil price and global warming due to green house gas is rapidly growing. Therefore, our country which has relied on import of the whole oil needed in Korea and has to keep Kyoto Agent to request reduction of green house gas fully support research and practical use for agricultural products as resource of alternate energy. At first, we have to develop the mass production technology in order to secure a program of self-supply of food for bioenergy production utilizing agricultural product in Korea. But we assume that this matter is difficult to achieve under the current agriculture system that more emphasizes the environment conservation such as environmentally-friendly agriculture than production of food.

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Micro Gas Turbine Performance using Catalytic Cracked Ethanol as Fuel (촉매 분해 에탄올을 연료로 사용하는 마이크로 가스터빈의 성능)

  • Choi, Songyi;Koo, Jaye;Yoon, Youngbin
    • Journal of Aerospace System Engineering
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    • v.11 no.2
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    • pp.9-15
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    • 2017
  • In order to verify the possiblity of improving the combustion performance of ethanol using zeolite catalyst and the characteristics of nitrogen oxides and carbon monoxide emission, micro gas turbine experiments were performed using catalytic reaction products, ethanol and kerosene as fuels and the results were compared. The thrust of the catalytic reaction product was lower than that of kerosene, but it was improved by 5% on average compared with the use of ethanol. Nitrogen oxides and carbon monoxide emissions of the catalytic reaction products were measured to be very low overall compared to kerosene. As a result, when the ethanol was reformed using the zeolite catalyst, the engine performance could be improved while maintaining the environment friendliness of the ethanol.

Status and Response Strategies of Carbon Labeling in Landscape Architecture (조경분야 탄소성적표지제도 적용실태 및 대응전략)

  • Kim, Jeong-Ho;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.24 no.6
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    • pp.709-720
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    • 2015
  • After analyzing the actual acquisition status of carbon labeling by year and by product for the past four years, as well as its certification in the construction-related sectors of greenhouse gas emission, this study attempted to present the problems and coping strategies upon issuing the carbon labeling certification in the landscape architecture. During the period of this analysis, the carbon labelings were acquired by 134 enterprises, 267 workplaces, and 735 products, while the percentage of acquisition was highest in the regular non-durable goods(49%), followed by energy-consuming durable goods(26%), regular production goods (19%), regular durable goods(3%), and service(3%). Furthermore, the acquisition certifications in construction sectors, were highest in the various pipes/panel(8 cases), followed by concrete(6 cases), gypsum board(4 cases), and landscape architecture materials(2 cases). The landscape architecture only had two cases in the acquisition certification for the first time in 2012, which accounted for 0.27% of the entire certification products, due to the uncertainty in the process, the lack of professionalism, and the lack of comprehension. However, the study conducted on the coping strategies for carbon labeling in the landscape architecture revealed the following: (1) regular reporting system management through the division of labor in the head office and factories, (2) the building of objective DB through the adoption of data management programs such as SAP, (3) continuous promotion and vitalization of the incentive system, (4) the adoption of mandatory or preferential application system in landscaping projects, management, and bidding, (5) enhancement of elasticity in deliberation of certification by recruiting experts in the landscape architecture sectors, and (6) provision of incentives for the cooperative firms acquiring the certification and support for their participation.

Facile Synthesis of M-MOF-74 (M=Co, Ni, Zn) and its Application as an ElectroCatalyst for Electrochemical CO2 Conversion and H2 Production

  • Choi, Insoo;Jung, Yoo Eil;Yoo, Sung Jong;Kim, Jin Young;Kim, Hyoung-Juhn;Lee, Chang Yeon;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.1
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    • pp.61-68
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    • 2017
  • Electrochemical conversion of $CO_2$ and production of $H_2$ were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of $CO_2$. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert $CO_2$ into useful chemicals.

Coal gasification with High Temperature Steam (고온(高溫) 수증기(水蒸氣)를 이용한 석탄(石炭) 가스화)

  • Yun, Jin-Han;Kim, Woo-Hyun;Keel, Sang-In;Min, Tai-Jin;Roh, Seon-Ah
    • Resources Recycling
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    • v.16 no.6
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    • pp.28-33
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    • 2007
  • Coal is the most abundant energy source and deposited in every area of world. Combustion process with lower efficiency has been mainly used. Therefore, implementation of more efficient technologies, involving gasification, combined cycles and fuel cells, would be a key issue in the plans for more efficient power generation. In these technologies, gasification has been studied for decades. However, coal gasification to high value combustible gas such as hydrogen and carbon monoxide is focused again due to high oil price. The gaseous product, called syngas, can be effectively utilized in a variety of ways ranging from electricity production to chemical industry (as feedstock). In this study, coal gasification with ultra high temperature steam has been performed. The effect of steam/carbon ratio on the produced gas concentrations, gasification rate and additional products like tar, ammonia and cyan compounds has been determined.