• Title/Summary/Keyword: produced water purification

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Optimization of POME treatment process using microalgae and ultrafiltration

  • Ibrahim, R.I.;Mohammad, A.W.;Wong, Z.H.
    • Membrane and Water Treatment
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    • v.6 no.4
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    • pp.293-308
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    • 2015
  • Palm oil mill effluent (POME) was produced in huge amounts in Malaysia, and if it discharged into the environment, it causes a serious problem regarding its high content of nutrients and high levels of COD and BOD concentrations. This study was devoted on POME treatment and purification using an integrated process consisting of microalgae treatment followed by membrane filtration. The main objective was to find the optimum conditions as retention time and pH in the biological treatment of POME. Since after the optimum conditions there is a diverse effect of time and the process become costly. According to our knowledge, there is no existing study optimized the retention time and percentage removal of nutrients for microalgae treatment of POME wastewater. In order to achieve with optimization, a second order polynomial model regression coefficients and goodness of fit results in removal percentages of ammonia nitrogen ($NH_3-N$), orthophosphorous ($PO_4{^{-3}}$), COD, TSS, and turbidity were estimated. WinQSB technique was used to optimize the objective function of the developed model, and the optimum conditions were found. Also, ultrafiltration membrane is useful for purification of POME samples as verified by experiments.

Development of a Novel Process to produce Biodiesel and its use as fuel in CI Engine performance study

  • Mishra, Prasheet;Lakshmi, D.V.N.;Sahu, D.K.;Das, Ratnakar
    • International journal of advanced smart convergence
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    • v.4 no.1
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    • pp.154-161
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    • 2015
  • A novel process has successfully been developed by overcoming major difficulties through the elimination of number of process steps involved in the Classical Transesterification reaction during the preparation of Fatty Acid Methyl/Ethyl Ester (FAME.FAEE) called biodiesel. The Classical process with cost intensive process steps such as the utilization of excess alcohol, needing downstream distillation for the recovery and reutilization of excess alcohol/cosolvent, unrecoverable homogenous catalyst which consumes vast quantity of fresh distilled water during the purification of the product and downstream waste water treatment before its safe disposal to the surface water body. The Novel Process FAME/FAEE is produced from any vegetable oil irrespective of edible or inedible variety using sonication energy. The novelty of the finding is the use of only theoretical quantity of alcohol along with a co-solvent and reduced quantity of homogeneous catalyst. Under this condition neither the homogeneous catalyst goes to the FAME layer nor is the distillation needed. The same ester also has been prepared in high pressure high temperature reactor without using catalyst at sub critical temperature. The quality of prepared biodiesel without involving any purification step meets the ASTM standards. Blended Biodiesel with Common Diesel Fuel (CDF) and FAME is prepared, characterized and used as fuel in the Kirloskar make CI Engines. The evaluation of the engine performance result of pure CDF, B05 biodiesel, B10 biodiesel of all types of biodiesel prepared by using the feedstock of Soybean (Glycine max) and Karanja (Pongamia pinnate) oil along with their mixed oil provides useful information such as brake power, brake thermal efficiency, brake specific fuel consumption, etc, and established it as ideal fuel for unmodified CI engine.

Purification of Materials Produced by Amylocolatosis sp. and Anticancer Effect in Oral Cancer Model (Amylocolatosis sp.가 생산하는 항암물질의 정제 및 구강암 모델에 미치는 항암 효과)

  • Kim, Jung;Park, Young-Min;Lim, Do-Seon
    • Journal of dental hygiene science
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    • v.3 no.1
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    • pp.11-14
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    • 2003
  • A methylotrophic Actinomycetes strain, which produce the anti-oral cancer activity compound, was isolated from soil and estimated as Amylocolatosis sp. based on taxonomic studies. A methanol didn't have influence on the production of the anticancer compounds. These compound were isolated by ethylacetate extract, silica gel column chromatography, sephadex LH-20 column and reverse phase HPLC. The compounds were very stable under heat ($121^{\circ}C$), acid(pH 2.0) and alkali(pH 11.0) treatment. The cytotoxic effect of isolated anticancer compounds on various cancer cell lines such as A549, SNU-1, KB, L1210, and Sarcoma 180 was investigated by MTT assay method. And these produced compounds also showed the broad antimicrobial spectrum to test strains such as bacteria and yeast.

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Production of high dissolved O2/O3 with rotating wheel entraining gas method for environmental application

  • Li, Haitao;Xie, Bo;Hui, Mizhou
    • Advances in environmental research
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    • v.2 no.1
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    • pp.1-8
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    • 2013
  • There is a significant demand to make various dissolved gases in water. However, the conventional aeration method shows low gas mass transfer rate and gas utilization efficiency. In this study, a novel rotating wheel entraining gas method was developed for making high dissolved $O_2$ and $O_3$ in water. It produced higher concentration and higher transfer rate of dissolved $O_2$ and $O_3$ than conventional bubble aeration method, especially almost 100% of gas transfer efficiency was achieved for $O_3$ in enclosed reactor. For application of rotating wheel entraining gas method, aerobic bio-reactor and membrane bio-reactor (MBR) were successfully used for treatment of domestic and pharmaceutical wastewater, respectively; and vacuum ultraviolet $(VUV)/UV+O_3/O_2$ reactors were well used for sterilization in air/water, removal of dust particles and toxic gases in air, and degradation of pesticide residue and sterilization on fruits and vegetables.

CFD ANALYSIS ON THE CHARACTERISTICS FOR FLOCCULATORS OF VERTICAL PADDLE AND HYDRO-FOIL TYPE (수직 패들형 및 하이드로 포일형 응집기 특성의 전산유체역학 해석)

  • Shin, J.H.;Chang, S.M.;Cho, Y.
    • Journal of computational fluids engineering
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    • v.21 no.3
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    • pp.24-30
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    • 2016
  • In the water purification plant, the mixture of water and chemical from the mixing basin enters the flocculation basin. The rotating flocculators are generally used for the efficient flocculation of dregs. In this paper, the performance of flocculators of a vertical paddle type, widely used in the typical flocculation basins, and a hydro-foil type, recently disseminated in the field, are compared with each other by use of the numerical method. Also the characteristics and the efficiency are analyzed with CFD techniques. The strain rate and the eddy viscosity are compared for two types to predict the mixing efficiency, and the maximum speed and its location are pursued from the computed data. The hydrofoil type shows that the eddy viscosity is enhanced 1.66 to 3.03 times larger than that of vertical paddle type, and also produced 1.87 to 1.95 times larger flocs for each stage. However, the rapid rotation of hydrofoil may chop the floc to small size due to the higher turbulence intensity. From the result of computation, the strong and weak points of each type have been analyzed for the decision making.

Technical Feasibility for Hollow-Fiber Ultrafiltration Water Treatment System and its Economic Aspects (중공사형 한외여과막 수처리 공정의 기능성과 막을 사용한 수처리공정의 경제성에 관한 연구)

  • Wang, Jin-Soo;Kim, Byung-Jick;Choi, Soo Hyoung
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.12-18
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    • 1999
  • This research was undertaken to do the technical and economical feasibility study of membrane water treatment system. For the technical feasibility study, batch water treatment system using UF(ultrafiltration) was set up and several experiments were carried out. The performance of the UF membrane was tested in terms of turbidity. The experimental results showed that the UF membrane process produced less than 1 NTU water regardless of input water turbidity. For the economical feasibility study, the cost model was analyzed and programmed for simulation. Also costs of the membrane water treatment and the conventional treatment were evaluated. The simulation results showed that the unit production cost increased when design flow or permeate flow decreased. The production cost of membrane water treatment system was lower than that of the conventional system. Both technical and economical feasibility study showed that the UF membrane water purification system was a very competitive water purification process.

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Formation of Mixed Oxidants and Inactivation of E. coil by the Electrochemical Process using a Grid Shape Pt/Ti Electrode (Pt/Ti 격자형 평판 전극을 이용한 혼합 산화제 생성 및 E. coli 불활성화)

  • Jung, Yeon Jung;Oh, Byung Soo;Park, Sang Yeon;Baek, ko Woon;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.22 no.5
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    • pp.851-855
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    • 2006
  • The aim of this study was to investigate characteristics of formation of mixed oxidants and some aspects of the performance of electrochemical process as an alternative disinfection strategy for water purification. The study of electrochemical process has shown free chlorine to be produced, but smaller amounts of stronger oxidants, such as ozone, hydrogen peroxide and OH radicals, were also generated. The formation of ozone and hydrogen peroxide increased with increasing electric conductivity, but was limited at conductivities greater than 0.6 mS/cm. Also, formation of OH radical was enhanced as electric conductivity was increased to 0.9 mS/cm and The stead-state concentrations of OH radical were calculated at $1.1{\sim}6.4{\times}10^{-14}M$. Using E. coti, inactivation kinetic studies were performed. With the exception of free chlorine, the role of mixed oxidants, especially OH radical, was investigated for enhancement of the inactivation rate.

A Convenient Manufacturing Method for Mass Production of EGCG Rich Green Tea Extract (Epigallocatechin Gallate 고함유 녹차추출물의 제조공정 개선)

  • Seo, Eun Hye;Kim, Eun Jeong;Cheon, Seong Bong;Yoon, Min Ji;Choi, Sang Un;Ryu, Geon-Seek;Ryu, Shi Yong
    • Korean Journal of Pharmacognosy
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    • v.50 no.3
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    • pp.198-204
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    • 2019
  • A facile and convenient method was developed for the mass production of epigallocatechin gallate (EGCG) rich green tea extract (Er-GTE). The Er-GTE was successfully obtained from the crude water extract of green tea by the combination of two step purification, i.e., a simple adsorption process on the cation exchange resins (Trilite SCR-B) followed by the chromatography with Diaion HP-20 resins. The green tea extract produced by water extraction under $45^{\circ}C$ was subjected to adsorb on the strongly acidic cation exchange resin, Trilite SCR-B. The eluate passed through the resin was reabsorbed on Diaion HP-20 resin, which was subjected to elute with a mixture of water and alcohol by conventional chromatographical manner. The EGCG content in Er-GTE was estimated above 97% by HP-LC analysis and the newly developed method was regarded as the most suitable and appropriate process for the mass production of epigallocatechin gallate rich green tea extract (Er-GTE).

Catalytic Membrane Reactor for Dehydrogenation of Water Via gas-Shift: A Review of the Activities for the Fusion Reactor Fuel Cycle

  • Tosti, Silvano;Rizzello, Claudio;Castelli, Stefano;Violante, Vittorio
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.1-7
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    • 1999
  • Pd-ceramic composite membranes and catalytic membrane reactors(CMR) have been studied for hydrogen and its isotopes (deuterium and tritium) purification and recovery in the fusion reactor fuel cycle. Particularly a closed-loop process has been studied for recovering tritium from tritiated water by means of a CMR in which the water gas shift reaction takes place. The development of the techniques for coating micro-porous ceramic tubes with Pd and Pd/Ag thin layers is described : P composite membranes have been produced by electroless deposition (Pd/Ag film of 10-20 $\mu$m) and rolling of thin metal sheets (Pd and Pd/Ag membranes of 50-70 $\mu$m). Experimental results of the electroless membranes have shown a not complete hydrogen selectivity because of the presence of some defects(micro-holes) in the metallic thin layer. Conversely the rolled thin Pd and Pd/ag membranes have separated hydrogen from the other gases with a complete selectivity giving rise to a slightly larger (about a factor 1.7) mass transfer resistance with respect to the electroless membranes. Experimental tests have confirmed the good performances of the rolled membranes in terms of chemical stability over several weeks of operation. Therefore these rolled membranes and CMR are adequate for applications in the fusion reactor fuel cycle as well as in the industrial processes where high pure hydrogen is required (i.e. hydrocarbon reforming for fuel cell)

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Production of Chemistry Laboratory Class for Senior High School Freshmen

  • Yasuzawa, Mikito;Minagawa, Keiji;Kamitani, Sachiyo;Arai, Yuka;Konishi, Yuki;Nakanishi, Shinsuke;Oshima, Takuya;Yamaguchi, Junko;Ishii, Arisa
    • Journal of Engineering Education Research
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    • v.13 no.5
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    • pp.55-60
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    • 2010
  • Chemistry laboratory class was produced for senior high school freshmen with the cooperation of university staffs, high school teachers and the university students. Although the students who will take the lab class are senior high school freshmen, we decided to prepare four experiments that are simple and have highly visible reactions or transformation. That is, 1) Water purification, 2) Surface modification, 3) Briggs-Rauscher reaction, and 4) Polymer synthesis and characterization. After the safety guideline and experiment instructions by the faculty staffs, two teaching assistants (TAs) supervised each experiment. Since taking a direct part in it will provide stronger impact than only being one who is just watching the experiment, all experiments contained some process that the high school students must handle the reagents, tools or the equipment, by themselves. Although, the operation performed by the students was limited to a series of simple actions, the various unique phenomena presented by the experiments impressed the students. The lab class was fruitful not only for high school students, but also good for university students. The lab class provided good opportunity for them to improve the abilities to teach and guide someone.

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