• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.297-302
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• 2005

The determination of total phenols was accomplished by capillary-high performance liquid chromatography (capillary-HPLC) after nitrosation of the U.S.E.P.A. classified 11 priority pollutant phenols, using the nitrosated parent phenol (POHNO) as a reference for calibration. The optimum mobile phase composition for this analysis was found by examining the effect of changing the percentage of acetonitrile (MeCN) in the mobile phase on retention factors (k values) and peak intensities. As MeCN percentage was increased, k values were reduced and peak intensities were generally increased. From the results obtained, it was found that the optimum mobile phase was 90%(v/v) MeCN solution at pH 8.0, the detection wavelength of 400 nm, and a detection limit (D.L., concentration at signal to noise ratio (S/N) of 3.0) of 4.5 ${\times}$ $10^{-7}$ M. In addition, 10 of the 11 phenols present in mineral or waste water were separated after the nitrosation by capillary-HPLC. The optimum mobile phase for separation was a 40%(v/v) MeCN solution at pH 5.0.

• 한국농공학회논문집
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• 제60권5호
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• pp.17-27
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• 2018

The objective of this study is to identify the priority area where the nonpoint source pollution (NPS) management is required and to set up the load reduction goals for the identified priority area. In this study, the load duration curve (LDC) was first developed using the flow and water quality data observed at 286 monitoring stations. Based on the developed LDC, the priority area for the NPS pollution management was determined using a three-step method. The 24 watersheds were finally identified as the priority areas for the NPS pollution management. The water quality parameters of concern in the priority areas were the total phosphorus or chemical oxygen demand. The load reduction goals, which were calculated as the percent reduction from current loading levels needed to meet target water quality, ranged from 67.9% to 97.2% during high flows and from 40.3% to 69.5% during moist conditions, respectively. The results from this study will help to identify critical watersheds for NPS program planning purposes. In addition, the process used in this study can be effectively applied to identify the pollutant of concern as well as the load reduction target.

• 한국환경과학회지
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• 제26권8호
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• pp.881-891
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• 2017

In this study, the discharge loads of non-point pollution sources were analyzed using a Hydrologic Simulation Program-Fortran (HSPF) model for 46 sub-watersheds in order to guide the management plan for water and streams passing through the city. The results using HSPF showed good applicability in comparison to point measurements, which were based on BOD, TP, and TN. The mean value of the BOD loads was $4.08kg/km^2$ per day, and the highest level of BOD was $17.75kg/km^2$ per day at Namri. Three potential areas of high priority for the installment of constructed wetlands were selected in order to reduce non-point pollution sources based on BOD loads and on environmental and economic conditions. The results for these scenarios indicated a maximum rate of reduction in BOD of 39.12% within the proposed constructed wetlands.

• 한국물환경학회지
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• 제23권4호
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• pp.440-447
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• 2007

This paper is dealing with recent hot issues related with copper toxicity and its criteria, which was caused by a new government policy relocating some industries discharging priority-water quality pollutants from the watershed of Han River to other regions. Author is not interested in arguments between two sides of anti- and pro-policy but would like to go over status of copper pollution and its management and regulatory policy in Korea. From the data of published Research Journals and Reports, it can be concluded that copper is very common metal not only in the effluent from publically owned wastewater treatment plants, but also as a non-point source pollutant in the rainfall runoff. In addition, there have been very few studies personal interests, not by National Fund Basis. In order to enforce a new regulation, national-wide macro and micro-mass balance work of heavy metals should be performed in advance. In particular, background concentration and measurement errors have to be clearly defined before a new standard or criteria is established. The new standard has to be acceptable in terms of the best available technology and cost.

• 한국환경복원기술학회지
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• 제17권1호
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• pp.173-184
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• 2014

Riparian areas are significant functional grounds for inhabiting ecological system on the river such as the self-regulation of the water quality and the foundation of important corridors. For such functional device to operate, consecutive land purchase scheme that prioritizes targeted areas with high pollutant load rate imposes sustainable development of the ecological riparian belt. The purpose of this study is focused on measuring the methodology for selecting land purchse order before establishing riparian belt in accordance with pollution loading estimation and the basin approach. The Yeongsan and Seomjin river which includes targeted areas of the land purchase have been classified into the large-medium-small(standard basin) influence areas based on their catchment rage, which than sub-divided the research area of Juam lake by 38 small basins and 223 units. Small basins with the high pollution load rates have been assessed as the first prioritized targets. For the second priority, the condition of the point pollutant sources, original area of the targets, original restored area were concerned. The final decision of the land purchase order targeted only those within 50 meter range from the basin. To validate the accumulated data, the on-site investigation went along the targeted zones, which the result shows that all prioritized areas included both point and non-point pollutant sources, and had not a small originally restored areas.

• Environmental Analysis Health and Toxicology
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• 제5권3_4호
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• pp.1-17
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• 1990

In order to decide the priority of prevention activities in environmental pollution, a study must be carried out in the wide spectrum of causes and effects of pollution particularly effects on humanbeing in the concept of environmental engineering and toxicology Therefore, a study must be covered various segments of environment such as air, water/sea water, wastes and soil in other words sources of pollution should be analysed in the view point of intergrated efforts of engineering and toxicology to locate high priority of prevention activities which given the high value of human health.

• 분석과학
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• 제9권3호
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• pp.320-324
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• 1996

The dynamic range of mass selected detector, which is very popular recently because of the simplicity and cheap price, was determined by using priority pollutants. The applied priority pollutants were four pesticides, 4,4'-DDE and 4,4'-DDD, which show the sharp peaks, and ${\alpha}$-endosulfan and ${\beta}$-endosulfan, which show the broad peaks in SIM Chromatogram. The dynamic range of the 4,4'-DDE and the 4,4'-DDD was $0.1{\sim}3000{\mu}g/ml$. The broad peaks of the ${\alpha}$-endosulfan and ${\beta}$-endosulfan resulted in $0.25{\sim}3000{\mu}g/ml$ of dynamic range.

• Journal of Preventive Medicine and Public Health
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• 제19권1호
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• pp.65-75
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• 1986

In order to assess the general health effect due to air pollution and to determine the critical pollutant which is meant by the worst effect to health among various pollutants in Seoul, air quality measurements at 10 sites during $1983{\sim}1984$ were analyzed using Pollutant Standards Index(PSI) : This index has been ultimately proposed to describe the comprehensive degree of the air pollution by U.S. Environmental Protection Agency(EPA) since 1976. Total average of PSI in Seoul during the two years was 139 that is described in 'unhealthful' The highest PSI appeared in Winter 183 through the 2 years, the lowest in Summer 99, and Spring 129 and Fall 150 respectively, PSI in Deungchon dong and Seongsu dong which are industrial areas were very high in terms of 'very unhealthful', while shinlim dong was shown in low in terms of 'good'. TSP was a priority pollutant in Seoul as the most frequently occuring critical pollutant. Its frequency was 76.4% in Spring, 86.0% in Summer, 78.0% in Fall and 44.2% in Winter during the 2 years. In Winter, $TSP{\times}SO_2$ was an important term as the critical pollutant in Seoul. Oxidant was the most frequently occuring critical pollutant in Kwangwhamoon through the whole seasons. It was recommended that the PSI could be used to assess the air pollution administratively and legally in context with publich health.

• 분석과학
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• 제11권4호
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• pp.297-304
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• 1998

무기 priority pollutants의 분석에 미치는 매질의 영향을 살펴보기 위하여 도금, 피혁, 제지, 전기, 염색 sludge에 7종의 무기 priority pollutants(Ni, Cr, Cu, Zn, Pb, Cd, Hg)를 첨가하고 EPA 3050방법, 환경처의 폐기물공정시험방법 및 폐기물공정시험방법을 수정한 본 연구실 방법으로 비교 연구하였다. EPA 3050법에 따라 추출한 경우 Hg를 제외하고 평균회수율은 95.5%, 폐기물공정시험방법의 용출시험 방법에 따라 추출한 경우는 11.1%, 그리고 본 연구실에서 폐기물공정시험방법을 수정한 추출법의 경우는 27.7%의 평균 회수율이 나타났다. 매질에 따른 digestion에 대한 영향을 살펴보기 위하여 추출법에 의해 추출된 용액을 MDS(microwave digestion system)와 $HNO_3+HClO_4$ digestion 방법으로 회수율을 비교하였다. 유기 및 무기 매질에 대한 영향을 살펴보기 위하여 유기 매질인 경우는 triethanol amine, 무기 매질인 경우는 $FeCl_3{\cdot}6H_2O$와 $AlCl_3{\cdot}6H_2O$를 첨가하여 분석용 시료를 조제하고 AAS 및 HG-AAS로 회수율을 구하였다. 유기 및 무기 매질을 첨가한 시료가 첨가 하지 않은 시료 보다 회수율이 낮게 나타남에 따라 매질에 의한 영향을 받는 것으로 조사되었다. Hg는 MDS로 digestion하는 것이 회수율이 높게 나타났으며, Hg를 제외한 다른 원소는 $HNO_3+HClO_4$로 digestion 하는 것이 회수율 증가를 나타냈다.

• 한국해양공학회지
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• 제17권5호
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• pp.32-38
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• 2003

This study investigates the distribution characteristics and relationship of water quality, and analyzes the spatial and temporal variation and distribution of the pollutant loads at Yeong-il Bay. The results of these analysis, the concentrations of nutrient loads (T-N and T-P), both appeared to be at the maximum value in November, while most small values were taken in May for the T-N, and in August for the T-P. For COD, the maximum concentration was in August, which has much precipitation during the same season, T-N was at the mean, and T-P was at the minimum value. Using the cluster analysis to develop the division of the sea basin by the dendrogram, before and after construction of Pohang New-port, the variation characteristics of water quality of Yeong-il Bay were discussed. The in flowing pollutant loads were transported to the landward by the high-density salinity water volume of the bottom layer therefore, it formed nutrient trap or coastal trapping areas of the pollutant load. By this mechanism, it is clear that the water volume with high-density nutrient exists on both sides of the Pohang New-port. Thus, the sea basins increasing concentration of the pollutant load at Yeong-il Bay are most prevalent at Hyeong-san estuary, the Pohang Old, and New-port. To improve water quality of this sea basin, the reduction of these nutrients loads should be the highest priority.