• Bulletin of the Korean Chemical Society
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• 제16권3호
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• pp.202-204
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• 1995

The ultraviolet photochemistry of N,N'-bis(salicylidene)ethylenediamine copper(II), Cu(sal)2en, was investigated with low pressure mercury lamp. Redution of Cu(Ⅱ) and formation of Cl- were shown on 254 nm irradiation both for aerated and deaerated chlorinated hydrocarbon solvent such as CH2Cl2, chloroform, and 1,2-dichloroethane. Relatively long lived $({\tau}=100{\mu}sec)$ intermediate was detected by flash photolysis. Overall photo-process can be described as the formation of Cl- and new copper complex, product(1) by chlorohydrocarbon mediation, photoinduced reduction by abstraction of halogen from solvent, followed by redox induced substitution of axial ligand with chlorine. Product(1) is possibly Cu(III) chlorosalicylaldeimido complex and cyclic -CH2CH2- moiety is absent in the structure. 247nm band of Cu(sal)2en should contain ligand to metal charge transfer character.

• 한국분말재료학회지
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• 제25권4호
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• pp.340-345
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• 2018

Additive manufacturing by electron beam melting is an affordable process for fabricating near net shaped parts of titanium and its alloys. 3D additive-manufactured parts have various kinds of voids, lack of fusion, etc., and they may affect crack initiation and propagation. Post process is necessary to eliminate or minimize these defects. Hot isostatic pressing (HIP) is the main method, which is expensive. The objective of this paper is to achieve an optimum and simple post heat treatment process without the HIP process. Various post heat treatments are conducted for the 3D-printed Ti-6Al-4V specimen below and above the beta transus temperature ($996^{\circ}C$). The as-fabricated EBM Ti-6Al-4V alloy has an ${\alpha}^{\prime}$-martensite structure and transforms into the ${\alpha}+{\beta}$ duplex phase during the post heat treatment. The fatigue strength of the as-fabricated specimen is 400 MPa. The post heat treatment at $1000^{\circ}C/30min/AC$ increases the fatigue strength to 420 MPa. By post heat treatment, the interior pore size and the pore volume fraction are reduced and this can increase the fatigue limit.

• 대한전자공학회논문지
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• 제13권5호
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• pp.17-23
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• 1976

고속열중성자로에서 정상 운전중인 원자로를 운전정지하였다가 재가동할 때 가장 문제가 되는 것은 핵분열 생성물인 Xe135의 독소작용이다. 이것은 Xe135가 원자로 출력에 영향을 주는 열중성자에 대한 흡수단면적이 크고 그의 반감기가 길기 때문이다. 그러므로 원자로의 일시적 운전정지가 요구될 때 이의 재가시에는 반듯이 이 독소를 능과할 수 있는 충분한 초과반응도를 가해 주던지, Xe135가 붕괴되어 그의 농도가 줄어든 이후에야 원자로의 재가동이 가능하게 된다. 위와 같은 문제는 사실상 원자로 운전시 안전성 뿐만 아니라 경제성에도 큰 영향을 주고 있다. 본 논문에서는 이 점을 고려하여 Pontoyagin의 최대원리를 이용하여 운전정지를 최적화시키므로서 언제든지 원자로를 전출력으로 재가동할 수 있도록 운전정지 방법을 개선하였다. 그러나 제어과정에서나 그 이후에도 X, 농도는 제어된 허용치를 넘지 않고 최소시간 이내에 모든 제어를 끝내도록 하였다. The buildup of fission product, i.e. Xe-135 poisoning, is a prime factor in restarting a nuclear reactor from the shutdown, which was under normal operation in the high flux thermal reactor, It is caused by the high absorption crosssection of Xe-135 to thermal neutrons and its long half life, from which the thermal power is affected. It is then possible to restart a nuclear reactor after the sufficient excess reactivity to override this poisoning must be inserted, or its concentration is decreased sufficiently when its temporary shutdown is required. As ratter of fact, these have an important influence not only on reactor safety but also on economic aspect in operation. Considering these points in this study, the shutdown process was cptimized using the Pontryagin's maximum principle so that the shutdown mirth[d was improved as to restart the reactor to its fulpower at any time, but the xenon concentration did not excess the constrained allowable value during and after shutdown, at the same time all the control actions were completed within minimum time from beginning of the shutdown.

• International Journal of Computer Science & Network Security
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• 제22권4호
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• pp.408-416
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• 2022

The new millennium is characterized by an unprecedented breakthrough in knowledge and information and communication technologies, and the challenges of the XXI century require modernized paradigms of interaction in all spheres of life. Education continues to play a key role in national and global growth. The key role of education and its leadership in developing creative potential, as the main paradigm of the countries' stability, have significantly influenced educational centers. The developers of educational programs use information technologies as an incentive to develop creative potential of educational process. Professional training of the educational candidate is enhanced by the use of information technologies, so the educational applicants should develop technological skills to be productive members of society. Using the latest achievements in the field of information technologies for the organization of the educational process helps to form the operational style of education applicants' thinking, which provides the ability to acquire skills of processing information, that is presented in the text, graphic, tabular form, and increase the level of general and informational culture necessary for better orientation in the modern information space. The purpose of the research is to determine the effectiveness of information technologies as an incentive to develop creative potential of educational process on the basis of the survey, to establish advantages and ability to provide high-quality education in the context of using information technologies. Methods of research: comparative analysis; systematization; generalization, survey. Results. Based on the survey conducted among students and teachers, it has been found out that the teachers use the following information technologies for the development of creative potential of the educational process: to provide video and audio communication process (100%), Moodle (95,6%), Duolingo (89,7%), LinguaLeo (89%), Google Forms (88%) and Adobe Captivate Prime (80,6%). It is determined that modular digital learning environments (97,9%), interactive exercises tools (96,3%), ICT for video and audio communication (96%) and interactive exercises tools (95,1%) are most conducive to the development of creative potential of the educational process. As a result of the research, it was revealed that implementation of information technologies for the development of creative potential of educational process in educational institutions is a complex process due to a large number of variables, which should be taken into account both on the educational course and on the individual level. It has been determined that the using the model of implementation information technologies for the development of creative potential in educational process, which is stimulated due to this model, benefits both students and teachers by establishing a reliable bilateral connection between teacher and education applicant.

• 대한산업공학회지
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• 제29권2호
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• pp.179-189
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• 2003

Gate poly-silicon critical dimension is a prime characteristic of a metal-oxide-semiconductor field effect transistor. It is important to achieve the uniformity of gate poly-silicon critical dimension in order that a semiconductor device has acceptable electrical test characteristics as well as a semiconductor wafer fabrication process has a competitive net-die-per-wafer yield. However, on gate poly-silicon critical dimension, the complexity associated with a semiconductor wafer fabrication process entails hierarchical variance components according to run-to-run, wafer-to-wafer and even die-to-die production unit changes. Specifically, estimates of the hierarchical variance components are required not only for disclosing dominant sources of the variation but also for testing the wafer-level uniformity. In this paper, two experimental designs, a two-stage nested design and a randomized complete block design are considered in order to estimate the hierarchical variance components. Since gate poly-silicon critical dimensions are collected from fixed die positions within wafers, a factor representing die positions can be regarded as fixed in linear statistical models for the designs. In this context, the two-stage nested design also checks the wafer-level uniformity taking all sampled runs into account. In more detail, using variance estimates derived from randomized complete block designs, Duncan's multiple range test examines the wafer-level uniformity for each run. Consequently, a framework presented in this study could provide guidelines to practitioners on estimating the hierarchical variance components and testing the wafer-level uniformity in parallel for any characteristics concerned in semiconductor wafer fabrication processes. Statistical analysis is illustrated for an experimental dataset from a real pilot semiconductor wafer fabrication process.

• 한국치위생학회지
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• 제6권1호
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• pp.25-35
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• 2006

The purpose of this study is to forecast patient satisfaction and service value through the staged regression analysis of the relation between each factor and its satisfaction and service value, following the measurement of the quality of dental care service that patients recognize. And a self-administered survey was used for this study. The subjects of this survey were 394 outpatients of dental clinics located in K city in the period from Dec. 5, 2004 to Feb. 19, 2005, the questionnaire was composed of a total of 31 questions to measure the quality of overall dental care service(22 questions), the patient satisfaction(6 questions) and the service value(3 questions). The 7 points Likert scale ranging from "very poor"(1-point) to "very high"(7-point) was used for these questions The results of study could be summarized as follows: 1. The most useful index to predict patient satisfaction turned out to be "internal environment", followed by "treatment process and waiting time", "dentist", "external environment", and "dental hygienist". 2. The service value had a significant effect on the "internal environment", "dentist", "treatment process and waiting time". 3. The most useful index to predict the service value turned out to be "treatment process and waiting time", followed by "internal environment" and "dentist". Today, the quality of dental care service is becoming a prime concern since it is directly connected to a matter of survival of medical service organizations. Dental clinics desperately need patient-oriented marketing strategies in order to actively cope with changing medical environment. They also need to thoroughly examine possible measures to maximize the service value by establishing a variety of service strategies which can promote service quality that patients recognize.

• 인지과학
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• 제15권2호
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• pp.43-53
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• 2004

영어를 제2언어로 사용하는 한국인을 대상으로 이중언어의 어휘접근이 음운 정보와 관련하여 어떻게 일어나는지를 알아보았다. 이중언어를 처리할 매에 양 언어의 음운적 지식이 동시에 활성화된다는 비선택적 가설과 한 언어의 음운적 지식만이 활성화된다는 선택적 가설을 검증하고자하는 목적으로 2개의 실험을 실시하였다. 실험결과 한글 표적자극의 수행이(실험2) 점화자극으로 제시된 영어 단어의 음운적 조작에 따라 유의미한 영향을 받았고, 영어 표적자극을 처리할 때에는 (실험1) 점화자극으로 제시된 한글 단어의 음운적 조작에 따라 영향을 받는 경향을 발견하였다. 이는 이중언어 중 한 언어를 처리할 때에 다른 언어의 음운적 지식이 자동적으로 활성화됨을 의미하며 한국인에게 있어서 제2언어인 영어의 처리에서 음운정보가 중요한 역할을 함을 의미한다.

• Composites Research
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• 제17권3호
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• pp.1-7
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• 2004

최근 대형 복합재료 구조물 성형에 적합한 공정으로 주목받는 vacuum assisted RTM (VARTM) 공정에 있어, 보강섬유의 조직 내부에 잔류하는 공기를 제거하여 기공함유율을 낮추는 기술의 중요성이 인식되고 있다. 거대기공 혹은 불완전 함침영역은 부적절한 주입구 및 공기배출구의 위치, 혹은 금형의 형상에 의해 발생한다. 미세기공은 불균일한 수지 유동선단의 속도로 인해 유동선단 부분에서 집중적으로 형성되며, 금형충전 공정 도중 수지와 함께 이동한다. 성형이 완료된 제품내의 잔류 기공들은 완성품의 물리적 성질을 저하 및 제품의 파손을 초래할 수 있다. 본 연구에서는 VARTM 공정에서의 기공의 형성 및 이동을 해석할 수 있는 통합된 거시적/미시적 해석 방법을 개발하였다. 수치해석 프로그램을 개발하여 VARTM 공정에서의 3차원 수지 유동을 해석하였으며, 그에 따른 거대기공 및 미세기공의 분포를 예측하였다.

• Journal of Biosystems Engineering
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• 제19권2호
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• pp.124-137
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• 1994

Visual features of a mushroom(Lentinus Edodes, L.) are critical in grading and sorting as most agricultural products are. Because of its complex and various visual features, grading and sorting of mushrooms have been done manually by the human expert. To realize the automatic handling and grading of mushrooms in real time, the computer vision system should be utilized and the efficient and robust processing of the camera captured visual information be provided. Since visual features of a mushroom are distributed over the front and back sides, recognizing sides and states of the stalk including the stalk orientation from the captured image is a prime process in the automatic task processing. In this paper, the efficient and robust recognition process identifying the front and back side and the state of the stalk was developed and its performance was compared with other recognition trials. First, recognition was tried based on the rule set up with some experimental heuristics using the quantitative features such as geometry and texture extracted from the segmented mushroom image. And the neural net based learning recognition was done without extracting quantitative features. For network inputs the segmented binary image obtained from the combined type automatic thresholding was tested first. And then the gray valued raw camera image was directly utilized. The state of the stalk seriously affects the measured size of the mushroom cap. When its effect is serious, the stalk should be excluded in mushroom cap sizing. In this paper, the stalk removal process followed by the boundary regeneration of the cap image was also presented. The neural net based gray valued raw image processing showed the successful results for our recognition task. The developed technology through this research may open the new way of the quality inspection and sorting especially for the agricultural products whose visual features are fuzzy and not uniquely defined.

• 통합자연과학논문집
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• 제6권1호
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• pp.34-38
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• 2013

Tributyltin hydride ($n-Bu_3SnH$), an endocrine disruptor, was slowly polymerized by the group 4 ${Cp^{\prime}}_2TiCl_2/N$-selectride (Cp' = $C_5H_5$, Cp; $Me-C_5H_4$, Me-Cp; $Me_5C_5$, $Cp^*$) catalyst combination to give two phases of products: one is an insoluble cross-linked solid, polystannane in 3-25% yield as minor product via disproportionation/dehydrocoupling combination process, and the other is an oil, hexabutyldistannane in 65-90% yield as major product via simple dehydrocoupling process. Disproportionation/dehydrocoupling process first produced a low-molecular-weight oligostannane possessing partial backbone Sn-H bonds which then underwent an extensive cross-linking reaction of backbone Sn-H bonds, resulting in the formation of an insoluble polystannane. The disproportionation/dehydrocoupling of a tertiary hydrostannane mediated by early transition metallocene/inorganic hydride is quite unusual and applicable.