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Elution Behavior of Pd(II) - Isonitrosoethylacetoacetate Imine Chelates by Reversed Phase High Performance liquid Chromatography (역상 액체 크로마토그래피에 의한 Pd(II) - Isonitrosoethylacetoacetate Imine 유도체 킬레이트들의 용리 거동)

  • Kim, In-Whan;Shin, Han-Chul;Lee, Man-Ho;Yoon, Tai-Kun;Kang, Chang-Hee;Lee, Won
    • Analytical Science and Technology
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    • v.5 no.4
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    • pp.389-399
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    • 1992
  • Liquid Chromatographic behavior of Pd(II) in Isonitrosoethylacetoacetate lmine, $Pd(IEAA-NR)_2$ (R=H, $CH_3$, $C_2H_5$, $n-C_3H_7$, $C_6H_5-CH_2$, $n-C_4H_9$) chelates were investigated by reversed-phase HPLC on Micropak MCH-5 column using methanol/water as mobile phase. The optimum conditions for the separation of $Pd(IEAA-NR)_2$ chelates were examined with respect to the effect of the flow rate, sample solvent, mobile phase strength and column temperature. It wass found that metal chelates were properly eluted in an acceptable range of capacity factor value($0{\leq}log\;k^{\prime}{\leq}1$). The dependence of the logarithm of capacity factor(k') on the volume fraction of water in the binary mobile phase was examined. Also, the dependence of k' on the liquid-liquid extration distribution ratio($D_c$) in methanol-water/n-alkane extration system was investigated. Both kinds of dependence are linear, which susggests that the retention of the electroneutral metal chelate is largely due to the solvophobic effect. Standard adsorption enthalpy changes (${\Delta}H^{\circ}$) and standard adsorption entropy changes (${\Delta}S^{\circ}$) of Pd(II) Isonitrosoethylacetoacetate imine chelates on Micropak MCH-5 column were calculated by measuring capacity factor with changing temperature of the column.

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ON π𝔉-EMBEDDED SUBGROUPS OF FINITE GROUPS

  • Guo, Wenbin;Yu, Haifeng;Zhang, Li
    • Bulletin of the Korean Mathematical Society
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    • v.53 no.1
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    • pp.91-102
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    • 2016
  • A chief factor H/K of G is called F-central in G provided $(H/K){\rtimes}(G/C_G(H/K)){\in}{\mathfrak{F}}$. A normal subgroup N of G is said to be ${\pi}{\mathfrak{F}}$-hypercentral in G if either N = 1 or $N{\neq}1$ and every chief factor of G below N of order divisible by at least one prime in ${\pi}$ is $\mathfrak{F}$-central in G. The symbol $Z_{{\pi}{\mathfrak{F}}}(G)$ denotes the ${\pi}{\mathfrak{F}}$-hypercentre of G, that is, the product of all the normal ${\pi}{\mathfrak{F}}$-hypercentral subgroups of G. We say that a subgroup H of G is ${\pi}{\mathfrak{F}}$-embedded in G if there exists a normal subgroup T of G such that HT is s-quasinormal in G and $(H{\cap}T)H_G/H_G{\leq}Z_{{\pi}{\mathfrak{F}}}(G/H_G)$, where $H_G$ is the maximal normal subgroup of G contained in H. In this paper, we use the ${\pi}{\mathfrak{F}}$-embedded subgroups to determine the structures of finite groups. In particular, we give some new characterizations of p-nilpotency and supersolvability of a group.

Croton hirtus L'Hér Extract Prevents Inflammation in RAW264.7 Macrophages Via Inhibition of NF-κB Signaling Pathway

  • Kim, Min Jeong;Kim, Ju Gyeong;Sydara, Kong Many;Lee, Sang Woo;Jung, Sung Keun
    • Journal of Microbiology and Biotechnology
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    • v.30 no.4
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    • pp.490-496
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    • 2020
  • Consumption of anti-inflammatory nutraceuticals may help treat or prevent inflammation-related illnesses such as diabetes, cardiovascular disease, and cancer. This study evaluated the effect of Croton hirtus L'Hér extract (CHE) on lipopolysaccharide (LPS)-induced nitric oxide (NO) production and nuclear factor kappa-B (NF-κB) signaling cascades. CHE significantly suppressed LPS-induced NO production and inducible nitric oxide synthase (iNOS) expression in RAW264.7 macrophages, although cyclooxygenase (COX)-2 expression was not affected. CHE also suppressed LPS-induced IκB kinase (IKK), IκB, and p65 phosphorylation in RAW264.7 cells. Western blot and immunofluorescence assays of cytosol and nuclear p65 and the catalytic subunit of NF-κB showed that CHE suppressed LPS-induced p65 translocation from the cytosol to the nucleus. CHE also suppressed LPS-induced Interleukin (IL)-6 and tumor necrosis factor (TNF)-α production in RAW264.7 cells. These results suggest that CHE prevents NO-mediated inflammation by suppressing NF-κB and inflammatory cytokines.

Identification of Discrimination Factors for a Pig Noncontact Weighing System Using Image Data (영상정보를 이용한 돼지의 비접촉 체중계측시스템 인자 구명)

  • 장동일;임영일;임정택;장요한;장홍희
    • Journal of Animal Environmental Science
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    • v.5 no.2
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    • pp.93-100
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    • 1999
  • Pig's original image data was transformed to a binary image, an image excluding head and tail portion from the whole binary image, and a projected image associated with pig's height. Then the length of body, width of shoulder, and area of pig were calculated and the relationships among the above characteristics and pig's weight were analyzed. The results obtained from this study were as follows: 1. Whole binary image data was considered to be improper to determine the pig's weight because the movement of pig's head and tail portion affected the image data. 2. Binary image data excluding head and tail portion from the whole binary image showed a better estimation of the pig's weight than the whole binary image. 3. Pig's should width was analyzed to be improper factor to determine the pig's weight. 4. The projected image associated with pig's height showed the highest correlation between the pig's area of the image and pig's weight(R2=0.9965). From this research the projected image associated with pig's height, which is excluding head and tail portion from the whole body of pig's image, was considered to be the prime factor to measure the pig's weight by the noncontact measurement.

Effect of Body Composition and Osteoporosis Self-efficacy on Bone Mineral Density of Female Nursing Students (간호대학생의 신체조성과 골다공증 자기효능감이 골밀도에 미치는 영향)

  • Lee, Kyu Eun;Kim, Nam Sun
    • Journal of Korean Academy of Fundamentals of Nursing
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    • v.20 no.3
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    • pp.230-238
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    • 2013
  • Purpose: This study was done to identify the relationship among bone mineral density (BMD), body composition and osteoporosis self-efficacy and to identify predictors of BMD in female nursing students. Method: Participants were 154 nursing students. Osteoporosis self-efficacy was determined by a self-report questionnaire. BMD was measured by ultrasound bone densitometry and body composition by a body composition analyzer. Data were collected between April 1 and 27, 2013 and analyzed using descriptive statistics, ANOVA, Scheff$\acute{e}$ test, Pearson correlation coefficient, and multiple regression with SPSS 18.0. Results: Mean BMD at the calcaneus site was $0.58{\pm}1.31$ (T-score). Incidence of osteopenia was 11.7%. Percentage of body fat (PBF)-defined obesity had higher prevalence than body mass index (BMI)-defined obesity. BMD had significant positive correlations with skeletal muscle mass (r=.226, p=.005) and fat free mass (r=.225, p=.005). The factor predicting BMD was skeletal muscle mass with 4.7% of explained variance. Conclusion: Study results indicate that of body composition components, skeletal muscle mass is the prime predicting factor for BMD. Thus to promote healthy bones, it is important to strengthen the muscles using a program, based on balanced development of all muscles.

SOME REDUCED FREE PRODUCTS OF ABELIAN C*

  • Heo, Jae-Seong;Kim, Jeong-Hee
    • Bulletin of the Korean Mathematical Society
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    • v.47 no.5
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    • pp.997-1000
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    • 2010
  • We prove that the reduced free product of $k\;{\times}\;k$ matrix algebras over abelian $C^*$-algebras is not the minimal tensor product of reduced free products of $k\;{\times}\;k$ matrix algebras over abelian $C^*$-algebras. It is shown that the reduced group $C^*$-algebra associated with a group having the property T of Kazhdan is not isomorphic to a reduced free product of abelian $C^*$-algebras or the minimal tensor product of such reduced free products. The infinite tensor product of reduced free products of abelian $C^*$-algebras is not isomorphic to the tensor product of a nuclear $C^*$-algebra and a reduced free product of abelian $C^*$-algebra. We discuss the freeness of free product $II_1$-factors and solidity of free product $II_1$-factors weaker than that of Ozawa. We show that the freeness in a free product is related to the existence of Cartan subalgebras in free product $II_1$-factors. Finally, we give a free product factor which is not solid in the weak sense.

Analysis on the Improvement of Ski Resort Service Quality with the Performance Model (스키리조트 서비스품질 개선 우선순위 도출)

  • Yeo, Hwan-Leep;Kim, Pan-Soo
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.33 no.1
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    • pp.59-70
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    • 2010
  • This paper reorganized five service qualities dimensions of ski-resorts, then derived the improvement priority order of the service quality through a satisfaction measure considering the importance. There're more competitive situations to guarantee customers using the skies and snowboards is a major sports in winter season. In these competitive environments, this paper's going to propose a predominant-competitive strategies for improving the service quality of ski-resorts. This study measured the satisfaction considering the importance of service quality target on customers has an experience ski resort service quality to improve ski resort service quality. This study using Performance Model decide a priority order about a particular item improvement, then is going to present a guideline that can improve the service quality more exactly. As a result of the study the factors that is important to the customer were prime physical factor, access, assistance physical factor, staff service and assistant service, an improvement priority order were accommodation and eating-drinking facilities, waiting time of a slope and lift/gondola, entertainment/shopping facilities in the resorts, equipment rental and lift fare.

Performance Analysis and Improvement of Dedicated Short Range Communication System (DSRC 시스템의 성능해석 및 개선)

  • Park, Ju-Nam;Cho, Sung-Joon
    • Journal of Advanced Navigation Technology
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    • v.5 no.1
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    • pp.62-73
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    • 2001
  • In this paper, performance of DSRC systems is analyzed with considering the real roads and height of vehicles. The channels are modeled as 2-Ray and 4-Ray with a direct wave and reflected waves by a road and buildings in a physical layer because DSRC keeps LOS propagation characteristics, and the pass loss for each model is calculated respectively. Rician factor is obtained through the calculated path loss on two models for DSRC, and the performance of the systems is analyzed in AWGN and Rician fading channels, Impulsive noise and Rician fading channels respectively. As a result, in Rician fading channels with impulsive noise(A=0.2, ${\Gamma}^{\prime}=0.22$), BER is below $10^{-6}$ when the distance is farther than 80[m] and 40[m] in 2-Ray model and 4-Ray model respectively. For performance improvement, BCH coding scheme and MRC diversity scheme are adopted.

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The new Weakness of RSA and The Algorithm to Solve this Problem

  • Somsuk, Kritsanapong
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.9
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    • pp.3841-3857
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    • 2020
  • RSA is one of the best well-known public key cryptosystems. This methodology is widely used at present because there is not any algorithm which can break this system that has all strong parameters within polynomial time. However, it may be easily broken when at least one parameter is weak. In fact, many weak parameters are already found and are solved by some algorithms. Some examples of weak parameters consist of a small private key, a large private key, a small prime factor and a small result of the difference between two prime factors. In this paper, the new weakness of RSA is proposed. Assuming Euler's totient value, Φ (n), can be rewritten as Φ (n) = ad + b, where d is the private key and a, b ∈ ℤ, if a divides both of Φ (n) and b and the new exponent for the decryption equation is a small integer, this condition is assigned as the new weakness for breaking RSA. Firstly, the specific algorithm which is created for this weakness directly is proposed. Secondly, two equations are presented to find a, b and d. In fact, one of two equations must be implemented to find a and b at first. After that, the other equation is chosen to find d. The experimental results show that if this weakness has happened and the new exponent is small, original plaintext, m, will be recovered very fast. Furthermore, number of steps to recover d are very small when a is large. However, if a is too large, d may not be recovered because m which must be always written as m = ha is higher than modulus.

A Study on the Elution Behavior of some Metal-N-Alkylisonitrosoacetylacetone imine Chelates by Reversed Phase High Performance Liquid Chromatography (역상 액체 크로마토그래피에 의한 몇 가지 금속-N-Alkylisonitrosoacetylacetone imine 킬레이트의 용리거동에 관한 연구)

  • Kim, Yong Jun;Kewon, Ji Hae;Lee, Won
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.63-71
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    • 1992
  • Liquid chromatographic behavior of Pd(II), Ni(II) and Co(III) in N-Alkylisonitrosoacetylacetone imine(HIAA-NR) chelates was investigated by reversed phase high perfomance liquid chromatography. The optimum conditions for the separation of IAA-NR-metal chelates were examined respect to the flow rate and mobile phase strength. The metal-N-Alkylisonitrosoacetylacetone imine chelates in solution were successfully separated on Novapak $C_{18}$ column using acetonitrile/water mixture as mobile phase. The elution order of chelates is methyl>ethyl>propyl>butyl as N-alkyl group for ligand is varied. It was found that all IAA-NR-metal chelates were eluted in an acceptable range of capacity factor value($0{\leq}log\;k^{\prime}{\leq}1$). The dependence of log k' on the volume fraction of water in the binary mobile phase was examined. Also, the dependence of k' on the liquid-liquid extraction distribution ratio(Dc) in acetonitrile-water-alkane extraction system was investigated for IAA-NR-metal chelate. Both kinds of dependence are linear, which suggests that the retention of the electroneutral metal chelates on Novapak $C_{18}$ column is largely due to the hydrophobic effect.

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