• 제목/요약/키워드: primary phase

검색결과 1,058건 처리시간 0.153초

페복제 적하법에 의한 나노 결정 TiO2 피복 석탄회의 제조와 광촉매 특성 (Preparation of Nanocrystalline TiO2 Coated Coal Fly Ash by Dropping Method of Coating Agent and Photocatalytic Characterization)

  • 유연태;최영윤;김병규
    • 한국재료학회지
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    • 제12권5호
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    • pp.334-340
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    • 2002
  • $TiO_2$-coated fly ash was synthesized by dropping method of coating agent in order to get $TiO_2$ coating layer with high photocatalytic activity on the surface of coal fly ash. The properties of the $TiO_2$ coating layer such as morphology, crystal structure, crystal size and photocatalytic activity were compared with those of the $TiO_2$-coated fly ash prepared by the traditional method of precipitation. $TiCl_4$ aqueous solution was used as a titanium stock solution and $NH_4HCO_3$ was used as a precipitant. The $TiO_2$ coating layer obtained by dropping method of coating agent was more uniform than that coated by precipitation. However, the crystal of $TiO_2$ coated by dropping method of coating agent was easy to grow by heat treatment because of the small primary particle size and bulky morphology, and its photocatalytic activity was consequently lower than that of the $TiO_2$ coated by precipitation. The $TiO_2$ coating layer obtained by both methods had a crystal structure of anatase, and the temperature of phase transformation into rutile was 90$0^{\circ}C$. The minimum crystal size of $TiO_2$ for the highest photocatalytic activity was found to be about 10nm.

안트라사이트를 활용한 산화마그네슘 보드의 실내 공기질 중 라돈가스 농도 저감 평가 (Evaluation of Decreasing Concentration of Radon Gas for Indoor Air Quality with Magnesium Oxide Board using Anthracite)

  • 편수정;임현웅;이상수
    • 한국건축시공학회지
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    • 제18권1호
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    • pp.9-15
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    • 2018
  • 지구상에 존재하는 라돈가스는 바위, 토양, 건축자재 등에서 방출되는 1급 발암물질로 유일한 기체상으로 존재하고 있다. 공기에 비해 무겁고 분자량이 커 하부에 가라앉아 있지만 이동성이 크다. 라돈가스는 특성상 실외에서 대기에 확산되지만 밀폐되고 환기가 어려운 실내공간의 농도는 수천 배까지 증가할 수 있다. 이러한 라돈가스의 위해성을 해결하기 위해 안트라사이트를 활용한 경화체의 라돈가스 저감 특성과 더불어 실내 마감재로 사용할 수 있는 기초 성능평가를 진행하였다. 기존 여과재로 사용된 안트라사이트를 사용하여 경화체를 제작하였으며, 기존 실내에서 사용된 건축자재 중 라돈을 방출하는 석고보드를 대체할 수 있는 시험을 진행하였다. 결합재로는 경소 마그네시아를 사용하였고, 경소마그네시아의 경화를 위해 염화마그네슘을 사용하였다. 흡착재로 사용된 안트라사이트의 치환율은 0, 10, 20, 30, 40, 50 (%)로 총 6수준으로 진행하였으며,W/B는 40%로 고정하였다. 시험항목은 휨파괴 하중, 열전도율, 라돈가스 농도를 진행하였으며, 양생조건은 항온항습 양생(습도 $80{\pm}5%$, 온도 $20{\pm}2^{\circ}C$)으로 진행하였다.

분산전원 연계선로에서 지락고장시 중성선의 과전류 해석 및 보호계전기의 새로운 알고리즘 (An Overcurrent Analysis in Neutral Line and Algorithm to Prevent Malfunction of Relay in Distributed Generations)

  • 신동열;김동명;차한주
    • 전기학회논문지
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    • 제58권10호
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    • pp.1916-1922
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    • 2009
  • Introducing distributed generators(DGs) to utility distribution system can cause malfunction of relay on the grid when ground faults or severe load unbalances are occurred on the system. Because DGs interconnected to the grid can contribute fault currents and make bidirectional power flows on the system, fault currents from DGs can cause an interference of relay operation. A directional over current relay(DOCR) can determine the direction of power flow whether a fault occurs at the source side or load side through detecting the phases of voltage and current simultaneously. However, it is identified in this paper that the contributed fault current(Ifdg) from the ground source when was occurred to contribute single-line-to-ground(SLG) fault current, has various phases according to the distances from the ground source. It means that the directionality of Ifdg may not be determined by simply detecting the phases of voltage and current in some fault conditions. The magnitude of Ifdg can be estimated approximately as high as 3 times of a phase current and its maximum is up to 2,000 A depending on the capacity of generation facilities. In order to prevent malfunction of relay and damage of DG facilities from the contribution of ground fault currents, Ifdg should be limited within a proper range. Installation of neutral ground reactor (NGR) at a primary neutral of interconnection transformer was suggested in the paper. Capacity of the proposed NGR can be adjusted easily by controlling taps of the NGR. An algorithm for unidirectional relay was also proposed to prevent the malfunction of relay due to the fault current, Ifdg. By the algorithm, it is possible to determine the directionality of fault from measuring only the magnitude of fault current. It also implies that the directionality of fault can be detected by unidirectional relay without replacement of relay with the bidirectional relay.

A Novel Hybrid Converter with Wide Range of Soft-Switching and No Circulating Current for On-Board Chargers of Electric Vehicles

  • Tran, Van-Long;Tran, Dai-Duong;Doan, Van-Tuan;Kim, Ki-Young;Choi, Woojin
    • Journal of Electrical Engineering and Technology
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    • 제13권1호
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    • pp.143-151
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    • 2018
  • In this paper, a novel hybrid configuration combining a phase-shift full-bridge (PSFB) and a half-bridge resonant LLC converter is proposed for the On-Board Charger of Electric Vehicles (EVs). In the proposed converter, the PSFB converter shares the lagging-leg switches with half-bridge resonant converter to achieve the wide ZVS range for the switches and to improve the efficiency. The output voltage is modulated by the effective-duty-cycle of the PSFB converter. The proposed converter employs an active reset circuit composed of an active switch and a diode for the transformer which makes it possible to achieve zero circulating current and the soft switching characteristic of the primary switches and rectifier diodes regardless of the load, thereby making the converter highly efficient and eliminating the reverse recovery problem of the diodes. In addition an optimal power sharing strategy is proposed to meet the specification of the charger and to optimize the efficiency of the converter. The operation principle the proposed converter and design considerations for high efficiency are presented. A 6.6 kW prototype converter is fabricated and tested to evaluate its performance at different conditions. The peak efficiency achieved with the proposed converter is 97.7%.

태양광 추진 항공기의 초기 사이징을 위한 에너지 균형 및 구속조건 연구 (Energy Balance and Constraints for the Initial Sizing of a Solar Powered Aircraft)

  • 황호연;남태우
    • 한국항공우주학회지
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    • 제40권6호
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    • pp.523-535
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    • 2012
  • 태양광 추진 항공기는 감시, 지구 모니터링, 통신 등에 대기 오염 없이 그리고 가까운 장래에 인공위성과의 가격 경쟁력까지 갖추게 될 수 있어 미래의 고고도 장기체공 임무수행을 위해 더욱더 그 중요성이 증대되고 있다. 그러나 전통적인 항공기 사이징 방법들은 태양광 추진 항공기에 바로 적용될 수 없다. 본 연구에서는 다양한 동력 시스템 구성품들이 태양광 추진 장기 체공 항공기의 사이징에 어떤 영향을 미치는지를 파악하기 위하여 에너지 균형 및 구속조건 연구를 수행하였다. 본 연구에서는 동력 생성과 연료전지의 재생 에너지 저장을 위한 광전지 모듈을 동력 시스템 구성품으로 고려하였다. 또한 본 연구 결과를 검증하기 위해 고고도 무인기에 이 새로운 사이징 기법을 적용하여 결과를 제시하였다.

STUDY OF CORRELATION BETWEEN WETTED FUEL FOOTPRINTS ON COMBUSTION CHAMBER WALLS AND UBHC IN ENGINE START PROCESSES

  • KIM H.;YOON S.;LAI M.-C.
    • International Journal of Automotive Technology
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    • 제6권5호
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    • pp.437-444
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    • 2005
  • Unburned hydrocarbon (UBHC) emissions from gasoline engines remain a primary engineering research and development concern due to stricter emission regulations. Gasoline engines produce more UBHC emissions during cold start and warm-up than during any other stage of operation, because of insufficient fuel-air mixing, particularly in view of the additional fuel enrichment used for early starting. Impingement of fuel droplets on the cylinder wall is a major source of UBHC and a concern for oil dilution. This paper describes an experimental study that was carried out to investigate the distribution and 'footprint' of fuel droplets impinging on the cylinder wall during the intake stroke under engine starting conditions. Injectors having different targeting and atomization characteristics were used in a 4-Valve engine with optical access to the intake port and combustion chamber. The spray and targeting performance were characterized using high-speed visualization and Phase Doppler Interferometry techniques. The fuel droplets impinging on the port, cylinder wall and piston top were characterized using a color imaging technique during simulated engine start-up from room temperature. Highly absorbent filter paper was placed around the circumference of the cylinder liner and on the piston top to collect fuel droplets during the intake strokes. A small amount of colored dye, which dissolves completely in gasoline, was used as the tracer. Color density on the paper, which is correlated with the amount of fuel deposited and its distribution on the cylinder wall, was measured using image analysis. The results show that by comparing the locations of the wetted footprints and their color intensities, the influence of fuel injection and engine conditions can be qualitatively and quantitatively examined. Fast FID measurements of UBHC were also performed on the engine for correlation to the mixture formation results.

붕장어 (Conger myriaster)의 뇌로부터 Vasopressin-related Peptide, [Arg8]-vasotocin의 정제 (Purification of Vasopressin-related Peptide, [Arg8]-vasotocin, from the Brain of Conger Eel (Conger myriaster))

  • 고혜진;김찬희;김은정;김인혜;박희연;윤호동;홍용기;박남규
    • 한국수산과학회지
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    • 제38권1호
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    • pp.6-11
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    • 2005
  • Vasopressin (VP)-related peptide was purified from the brain extract of conger eel (Conger myriaster) by reverse-phase, ion-exchange high performance liquid chromatography (HPLC). This peptide with a molecular weight of 1,051.2 Da was determined as $H-Cys-Tyr-Ile-Gln-Asn-Cys-Pro-Arg-Gly-NH_2$, whose Cys residues made an intramolecular disulfide bridge by the automated amino acid sequence analysis, MALDI- TOF mass spectrometry. It's sequence was confirmed by identity of the elution position with the synthetic peptide in HPLC system. As a result of homology investigation, the primary structure of this peptide was the same as that of VP-superfamily member, $[Arg^8]-vasotocin$. The synthetic peptide showed a contractile activity at a minimal effective concentration of $10^{-10}\;M$ on the intestinal smooth muscle of goldfish.

1리터급 엔진을 이용한 암모니아-가솔린 혼소 성능 특성 (Combustion Characteristics of Ammonia-Gasoline Dual-Fuel System in a One liter Engine)

  • 장진영;우영민;윤형철;김종남;이영재;김정환
    • 한국가스학회지
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    • 제19권6호
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    • pp.1-7
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    • 2015
  • 지구온난화와 화석연료 고갈 문제의 해결을 위하여 대체 연료 개발에 많은 노력을 하고 있다. 암모니아(NH3)는 수소와 마찬가지로 탄소를 포함하고 있지 않으면서 대표적인 수소 캐리어이다. 또한, 상온에서 0.6 MPa 정도의 압력을 가하면 액상을 유지할 수 있어 LPG 충전인프라를 그대로 사용가능한 장점이 있다. 본 연구는 암모니아를 가솔린과 함께 혼소시켰으며, 혼소 비율에 따른 엔진 성능을 비교하였다. 암모니아와 가솔린의 혼소를 위하여 가솔린 인젝터와 암모니아용 인젝터를 각각 사용하였으며, 암모니아는 액상으로 분사시켰다. 암모니아-가솔린 혼소 엔진의 최대 장점은 가솔린 대체량에 비례하여 이산화탄소 배출량을 크 게 감소시킬 수 있다는 것이다. 하지만 암모니아-가솔린 혼소율에 따라 연소가 불안정한 구간이 있었으며, 암모니아 혼소 비율 0.7 이상에서는 연소 불안정성 증가로 인해 토크와 NOx 배출량이 감소하고, THC 배출량이 급증하였다.

Optical emission analysis of hybrid air-water discharges

  • Pavel, Kostyuk;Park, J.Y.;Han, S.B.;Koh, H.S.;Gou, B.K.;Lee, H.W.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.521-522
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    • 2006
  • In this paper, hybrid air-water discharges were used to develop an optimal condition for providing a high level of water decomposition for hydrogen yield. Electrical and optical phenomena accompanying the discharges were investigated along with feeding gases, flow rates, and point-to-plane electrode gap distance. The primary focus of this experiment was put on the optical emission of the near UV range, with the energy threshold sufficient for water dissociation and excitation. The $OH(A^{2+},'=0\;X^2,"=0$) band's optical emission intensity indicated the presence of plasma chemical reactions involving hydrogen formation. In the gaseous atmosphere saturated with water vapor the OH(A-X) band intensity was relatively high compared to the liquid and transient phases although the optical emission strongly depended on the flow rate and type of feeding gas. In the gaseous phase discharge phenomenon for Ar carrier gas transformed into a gliding arc via the flow rate growth. OH(A-X) band's intensity increased according to the flow rate or residence time of He feeding gas. Reciprocal tendency was acquired for $N_2$ and Ar carrier gases. The peak value of OH(A-X) intensity was observed in the proximity of the water surface, however in the cases of Ar and $N_2$ with 0.5 SLM flow rate peaks shifted to the region below the water surface. Rotational temperature ($T_{rot}$) was estimated to be in the range of 900-3600 K, according to the carrier gas and flow rate, which corresponds to the arc-like-streamer discharge.

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20대 남성의 낮은 조도의 평지 보행 시 보행 패턴 변화 (Changes of Walking Pattern for Young Adults dur ing Level Walking under Low Illumination)

  • 최진승;강동원;방윤환;탁계래
    • 한국운동역학회지
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    • 제20권4호
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    • pp.381-386
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    • 2010
  • This study examined the changes in the walking pattern during level walking under low illumination conditions. Fourteen male subjects ($22.1{\pm}2.21$ years, $174{\pm}3.74\;cm$, $68.86{\pm}10.81\;kg$) with normal vision and no disabilities were enrolled in this study. All experiments were performed on a level walkway with three conditions: normal walking (preferred & low speed) and walking with low illumination. 3D motion capturing system was used for acquisition and analysis of the walking motion data with a sampling frequency of 120Hz. The walking speed, normalized jerk(NJ) at the center of mass(COM), wrist and heel, knee and elbow joint angle, ratio of the knee joint angle to elbow joint angle and the toe clearance on stance phase were used to compare the differences in walking pattern between the two illumination conditions, The results showed that the walking speed and joint angles decreased in low illumination, whereas the NJ and toe minimum clearance increased. In low illumination, most variables were similar to effects of low speed walking, but toe clearance was different from the effects of low speed. These results can be used as primary data for examining the changes in the level walking pattern of young adults under low illumination. Further study will be needed to compare these results in young adults with those in the elderly.