• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2642-2646
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• 2012

Pretreatment of spent FCC catalyst and its application in remove trace olefins in aromatics were investigated in this research. The most effective pretreatment route of spent FCC catalyst was calcining at $700^{\circ}C$ for 1 h, washing with 5% oxalic acid solution in ultrasonic reactor and dried. Treated spent FCC catalyst was modified with metal halides, then to prepare catalyst to remove trace olefins in aromatics. X-ray diffraction, Pyridine-FTIR, $N_2$ adsorption-desorption and inductively coupled plasma optical emission spectrometer (ICP-OES) were used to investigate the pretreatment process. The result showed that the performance of the treated spent FCC catalyst was much greater than that of the spent FCC catalyst, which indicted the possibility and improvement of this research.

• Journal of Fashion Business
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• v.9 no.3
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• pp.99-113
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• 2005

Recently, problems related to the natural dyeing have been addressed. Severer problems have been posed by the elution at metallic ions and dyestuff tram dyed fabrics. In order to prevent the elution tram the dyed fabrics, it is needed to improve the fastness. Especially, it is the most important measure to improve the fastness to perspiration in terms at human body safety. In this study, we employed chitosan pretreatment method bet ore the dyeing process, anticipating that the pretreatment might improve the fastness. We used Al, Sn, and Cu as mordants and investigated the fastness to light and perspiration of the chitosan treated and dyed fabric specimens. By the chitosan pretreatment, the fastness to perspiration improved, while the fastness to light did not.

• Environmental Engineering Research
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• v.14 no.1
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• pp.48-52
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• 2009

Solubilization of sewage sludge creates favorable conditions for anaerobic microorganisms to produce biogas. In this paper, we quantify the effect of heating pretreatment on the degree of solubilization of sewage sludge. The pretreatment process was carried out using a lab-scale industrial microwave unit (2450 MHz frequency). Response surface analysis was applied to determine the combination of temperature-increase rate (ramp rate) (2.9 to 17.1 ${^{\circ}C}$/min) and terminal temperature (52 to 108${^{\circ}C}$). Both ramp rate and temperature significantly affected the solubilization degree of sludge. Within the design boundaries, the conditions predicted to maximize the solubilization degree of 15.8% were determined to be 2.9 ${^{\circ}C}$/min and 104${^{\circ}C}$.

• The Korea Journal of Herbology
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• v.30 no.4
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• pp.71-79
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• 2015

Objectives : These present study was designed to investigate the relaxation effects of Alpiniae Oxyphyllae Fructus(AOF) on isolated corpus cavernosum smooth muscle.Methods : Rabbit corpus cavernous tissues were prepared in strip. Then relaxation responses of AOF at 0.01-3 ㎎/㎖ in contracted strips induced by phenylephrine(PE) were measured. To evaluate mechanisms, indomethacin(IM) tetraethylammonium chloride(TEA), Nω-nitro-L-arginine(_L-NNA), methylene blue(MB) were treated before AOF extract(0.1-3 ㎎/㎖) infused into precontracted strips induced by PE. And 1 mM Ca²⁺was infused into precontracted strips after pretreatment of AOF extract(3 ㎎/㎖) in Ca²⁺-free krebs-ringer solution. NO concentration was measured by Griess reagent system. Ratio of smooth muscles to collagen fibers and eNOS positive reaction were measured by histocheminal and immunohistochemical process.Results : The cavernous strips were significantly relaxed by AOF extract 0.1, 0.3, 1, 3 ㎎/㎖ and the pretreatment with IM 10 μM,_L-NNA 100 μM, MB 10 μM inhibited relaxation of AOF compared to non-pretreatment, but the pretreatment with TEA 100 μM didn't affect relaxation of AOF. In a Ca²⁺-free solution, pretreatment with AOF reduced increase on contraction of strips by Ca²⁺supply than non-pretreatment. On HUVEC, NO concentration was increased. On corpus cavernosum of penis in Spontaneous Hypertensive Rat, ratio of smooth muscles to collagen fibers and eNOS positive reaction in AOF group were increased compared to PE groupConclusions : Taken this results, we can suggest that AOF extract exerts a relaxation effects on rabbit corpus cavernosum smooth muscle in part by suppressing influx of extracellular Ca²⁺throughout prostacyclin, the NO-cGMP system.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.3
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• pp.286-297
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• 2010

This study deals with the effect of pretreatment on the $CO_2$ adsorption capacity of zeolitic adsorbents including a commercial A-type zeolite and cation exchanged adsorbents. The pre-heating could change the intrinsic properties such as specific surface area and adsorption capacity of the adsorbent. As a result of the experiment, the moisture previously filled inside might affect the potential adsorption capacity of the adsorbent, and could be disappeared throughout the heat treatment. An optimum pretreatment temperature for the test adsorbent was found to be $400^{\circ}C$, at which temperature enabled more than 90% refreshment. Precise examination through the TPD test showed that the TSA (Temperature Swing Adsorption) process would be desirable in dry adsorption of $CO_2$.

• Environmental Engineering Research
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• v.16 no.2
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• pp.103-109
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• 2011

This work experimentally determined the effect of thermal and microwave pretreatments on the anaerobic digestion of mixtures of municipal primary and secondary sludges in semi-continuous mesophilic digesters at hydraulic retention times (HRT) of 20, 15, 10, 7, and 5 days. The ratio of soluble chemical oxygen demand (COD) to total COD in thermally pretreated and microwaved sludges at $80^{\circ}C$ was 2.7 and 3.2 times higher than that of raw sludge, respectively. The volatile solids (VS) and COD removal efficiencies in all three digesters fed with raw (control), thermally pretreated (TM), and microwaved (MW) sludges decreased as the HRT was reduced. The highest relative improvement in VS removal compared to the control occurred at the HRT of 5 days in the TM and MW (29 and 41% higher than the control, respectively). At this HRT, improvement in the COD removal efficiencies in the TM and MW compared to the control was 28 and 53%, respectively. Improvements in biogas production compared with the control increased in both the TM and MW as the HRT was reduced to 5 days. The relative improvement in daily biogas production compared to the control from the TM and MW was 33 and 53% higher than the control at the HRT of 5 days, respectively. The results show that microwave pretreatment is more effective than thermal pretreatment in increasing the solubilization degree and mesophilic anaerobic biodegradability of sewage sludge.

• Journal of the Korean Vacuum Society
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• v.22 no.6
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• pp.277-284
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• 2013

Carbon coils could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition system. The Ni layer on the $SiO_2$ substrate was used as a catalyst for the formation of the carbon coils. The characteristics (formation densities, morphologies, and geometries) of the as-grown carbon coils on the substrate with or without the $H_2$ plasma pretreatment process were investigated. By the relatively short time (1 minute) $H_2$ plasma pretreatment on the Ni catalyst layered-substrate prior to the carbon coils synthesis reaction, the dominant formation of the carbon microcoils on the substrate could be achieved. After the relatively long time (30 minutes) $H_2$ plasma pretreatment process, on the other hand, we could obtain the noble-shaped geometrical nanostructures, namely the formation of the numerous carbon nanocoils along the growth of the carbon microcoils. This noble-shaped geometrical nanostructure seemed to play a promising role as the good catalyst support for holding the very tiny Ni catalyst grains.

• Journal of the Korean Wood Science and Technology
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• v.29 no.4
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• pp.103-110
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• 2001

Bio-kraft pulping of Populus alba${\times}$glandulosa pretreated with white-rot fungus, Phanerochaete chrysosporium KCCM 34740, was investigated The biopulping efficiency was evalued based on fungal pretreatment time and properties of bio-kraft pulp (pulp yield, freeness, WRY, kappa number and brightness) in comparison to the controls. Pretreatment of poplar wood chips with Phanerochaete chrysosporium KCCM 34740 for 10days resulted in a some increase in screened yield (by 2%). According to increase of fungal incubation time, decrease in freeness (CSF) and increase in WRY were observed And bio-kraft pulping also led to improvement of physical properties of handsheet. As a result of bio-beating effect, we expect the saving of chemicals in kraft cooking process and energy consumption in beating process.

• Korean Journal of Materials Research
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• v.26 no.3
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• pp.109-116
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• 2016

To achieve the fabrication of high-quality Ag-coated Cu particles through a wet chemical process, we reported herein pretreatment conditions using an ammonium-based mixed solvent for the removal of a $Cu_2O$ layer on Cu particles that were oxidized in air for 1 hr at $200^{\circ}C$ or for 3 days at room temperature. Furthermore, we discussed the results of post-Ag plating with respect to removal level of the oxide layer. X-ray diffraction results revealed that the removal rate of the oxide layer is directly proportional to the concentration of the pretreatment solvent. With the results of Auger electron spectroscopy using oxidized Cu plates, the concentrations required to completely remove 50-nm-thick and 2-nm-thick oxides within 5 min were determined to be X2.5 and X0.13. However, the optimal concentrations in an actual Ag plating process using Cu powder increased to X0.4 and X0.5, respectively, because the oxidation in powder may be accelerated and the complete removal of oxide should be tuned to the thickest oxide layer among all the particles. Back-scattered electron images showed the formation of pure fine Ag particles instead of a uniform and smooth Ag coating in the Ag plating performed after incomplete removal of the oxide layer, indicating that the remaining oxide layer obstructs heterogeneous nucleation and plating by reduced Ag atoms.

• Textile Coloration and Finishing
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• v.34 no.4
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• pp.224-233
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• 2022

Recently, consumer tastes of various classes at home and abroad prefer comfortable, unadorned, and simple clothing, and the athleisure trend, which can be used freely in daily life as well as exercise, has expanded to overall clothing products. Existing materials used for athleisure are composite knitted fabrics using polyester yarn and PU yarn, which has problems due to a chronic lack of color fastness and contamination by dyes even when PU laminating is applied, making it difficult to apply various colors. There is a quality problem in which deformation of the product occurs due to lack of durability. In this study, CDP yarn(75de/72f) and PU yarn(40de) were selected to commercialize the circular knitting for athleisure using CDP yarn in order to solve the problems that occur in the dyeing and laminating process when using polyester materials. CDP yarns were used to knit into single(CP75-S) and double(CP75-D) knit and single knit were found to be suitable as athleisure fabrics. After pretreatment and treatment under various conditions, the stainability of CDP circular knitting was examined. After pretreatment and dyeing process under various conditions, the property of scouring and dyeability of CP75-S were evaluated.