• Journal of the Korea Institute of Military Science and Technology
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• v.7 no.2 s.17
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• pp.81-87
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• 2004

Semiconductor thick film gas sensors based on tin oxide are fabricated and their gas response characteristics are examined for four simulant gases of chemical warfare agent (CWA)s. The sensing materials are prepared in three different sets. 1) The Pt or Pd $(1,\;2,\;3\;wt.\%)$ as catalyst is impregnated in the base material of $SnO_2$ by impregnation method.2) $Al_2O_3\;(0,\;4,\;12,\;20\;wt.\%),\;In_2O_3\;(1,\;2,\;3\;wt.\%),\;WO_3\;(1,\;2,\;3\;wt.\%),\;TiO_2\;(3,\;5,\;10\;wt.\%)$ or $SiO_2\;(3,\;5,\;10\;wt.\%)$ is added to $SnO_2$ by physical ball milling process. 3) ZnO $(1,\;2,\;3,\;4,\;5\;wt.\%)$ or $ZrO_2\;(1,\;3,\;5\;wt.\%)$ is added to $SnO_2$ by co-precipitation method. Surface morphology, particle size, and specific surface area of fabricated sensing films are performed by the SEM, XRD and BET respectively. Response characteristics are examined for simulant gases with temperature in the range 200 to $400^{\circ}C$, with different gas concentrations. These sensors have high sensitivities more than $50\%$ at 500ppb concentration for test gases and also have shown good repetition tests. Four sensing materials are selected with good sensitivity and stability and are fabricated as a sensor array A sensor array Identities among the four simulant gases through the principal component analysis (PCA). High sensitivity is acquired by using the semiconductor thick film gas sensors and four CWA gases are classified by using a sensor array through PCA.

• Korean Journal of Agricultural and Forest Meteorology
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• v.15 no.4
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• pp.312-319
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• 2013

Our understanding of the sensitivities of crop responses to changes in carbon dioxide, temperature, and water is limited, which makes it difficult to fully utilize crop models in assessing the impact of climate change on future agricultural production. Genetic coefficients of CERES-Barley model for major domestic cultivars in South Korea (Olbori at Suwon, Albori at Milyang, Saessalbori at Iksan, and Samdobori at Jinju) were estimated from the observed data for daily weather and field trials for more than 10 years by using GenCalc in DSSAT. Data from 1997-2002 annual crop status report (Rural Development Administration, RDA) were used to validate the crop coefficients. The sitecalibrated CERES-Barley model was used to perform crop growth simulation with the 99 treatments of step change combinations in temperature, precipitation and carbon dioxide concentration with respect to the baseline climate (1981-2010) at four sites. The upper boundary corresponds to the 2071-2100 climate outlook from the RCP 8.5 scenario. The response surface of grain yield showed a distinct pattern of model behavior under the combined change in environmental variables. The simulated grain yield was most sensitive to $CO_2$ concentration, least sensitive to precipitation, and showing a variable response to temperature depending on cultivar. The emulated impacts of response surfaces are expected to facilitate assessment of projected climate impacts on a given cultivar in South Korea.

• Journal of Korea Water Resources Association
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• v.42 no.11
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• pp.921-931
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• 2009

For the assessment of climate change impacts for the Byeongseong stream, CGCM 3.1 T63 is selected as future climate information. The projections come from CGCM used to simulate the GHG emission scenario known as A2. Air temperature and precipitation information from the GCM simulations are converted to regional scale data using the statistical downscaling method known as MSPG. Downscaled climate data from GCM are then used as the input data for the SWAT model to generate regional runoff and water quality estimates in the Byeongseong stream. As a result of simple sensitivity analysis, the increase of CO2 concentration leads to increase water yield through reduction of evapotranspiration and increase of soil water. Hydrologic responses to climate change are in phase with precipitation change. Climate change is expected to reduce water yields in the period of 2021-2030. In the period of 2051-2060, stream flow is expected to be reduced in spring season and increased in summer season. While soil losses are also in phase with water yields, nutrient discharges (i.e., total nitrogen) are not always in phase with precipitation change. However, it should be noted that there are a lot of uncertainties in such multiple-step analysis used to convert climate information from GCM-based future climate projections into hydrologic information.

• Journal of the Korean Chemical Society
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• v.28 no.1
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• pp.41-46
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• 1984

To preconcentrate trace elements, microgram amounts of 5 heavy metals (Cu, Co, Ni, Zn and Cd) were precipitated with 8-hydroxyquinoline (oxine) and metal oxinates were extracted with stearic acid. And then each of the molten stearic acid extract with stearic acid. And then each of the molten stearic acid extract was poured into a glass ring and cooled for specimen preparation. The obtained specimens were analyzed by X-ray fluorescene spectrometry. And then conditions of precipitation formation and extraction, reproducibility, sensitivity and detection limit were observed. The relative standard deviation of specimen preparation was 1.0~5.7% and the detection limit was 5~$50{\mu}g$/100ml. The proposed preconcentration procedure exhibited a considerable inhancement and simplicity in preparing specimens.

• Atmosphere
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• v.23 no.2
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• pp.161-169
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• 2013

We examine the effects of the sea surface temperature (SST) distribution on heavy snowfall over the Yellow Sea using high-resolution SST products and WRF (Weather Research and Forecasting) model simulations in 30 December 2010. First, we evaluate the model by comparing the simulated and observed fresh snowfall over the Korean peninsula (Ho-Nam province). The comparison shows that the model reproduces the distributions and magnitudes of the observed snowfall. We then conduct sensitivity model simulations where SST perturbations by ${\pm}1.1^{\circ}C$ relative to baseline SST values (averaged SST for $5{\sim}15^{\circ}C$) are uniformly specified over the region of interest. Results show that ${\pm}1.1^{\circ}C$ SST perturbation simulations result in changes of air temperature by $+0.37/-0.38^{\circ}C$, and by ${\pm}0.31^{\circ}C$ hPa for sea level pressure, respectively, relative to the baseline simulation. Atmospheric responses to SST perturbations are found to be relatively linear. The changes in SST appear to perturb precipitation variability accounting for 10% of snow and graupel, and 18% of snowfall over the Yellow Sea and Ho- Nam province, respectively. We find that anomalies of air temperature, pressure, and hydrometeors due to SST perturbation propagate to the upper part of cloud top up to 500 hPa and show symmetric responses with respect to SST changes.

• BMB Reports
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• v.30 no.6
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• pp.403-409
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• 1997

Studies were undertaken to develop a competitive radioimmunoassay (RIA) and indirect antigen capture enzyme-linked immunosorbent assay (ELISA) for the determination of 5'-deoxy-5'-methylthioadenosine (MTA), which is formed from decarboxylated S-adenosylmethionine by spermidine and spermine synthase. Specific antiserum against MTA was raised in rabbits by immunization with MTA-BSA which was prepared by coupling BSA to oxidized MTA with periodate. Since MTA is oxidized easily to the sulfoxide, the sulfhydryl reagent, DTT. was added to the immunogen. For RIA, immunocomplexes were separated from free MTA by using ammonium sulfate precipitation. The antiserum showed almost no cross-reactivity with a variety of other nucleotides and riboses. But, the level of cross-reactivity of 5'-isobutylthioadenosine (SIBA) was high. These results showed the importance of hydrophobicity adjacent to the 5'-OH for determining antigenicity. The lower limit of detection by this assay was 100 fmol of MTA per tube. Using this assay. MTA levels were more easily and precisely determined in biological samples when compared with HPLC analysis. The RIA procedure is less time consuming. More than 24 analyses can be carried out in 2 h and required only a very small amount of sample ($20{\mu}l$ serum). In ELISA, biotin conjugated MTA-BSA was used as the labelled MTA. The sensitivity limit of this assay was lower than 100 pmol.

• The Plant Pathology Journal
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• v.36 no.5
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• pp.406-417
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• 2020

Early warning services for crop diseases are valuable when they provide timely forecasts that farmers can utilize to inform their disease management decisions. In South Korea, collaborative disease controls that utilize unmanned aerial vehicles are commonly performed for most rice paddies. However, such controls could benefit from seasonal disease early warnings with a lead time of a few months. As a first step to establish a seasonal disease early warning service using seasonal climate forecasts, we developed the EPIRICE Daily Risk Model for rice blast by extracting and modifying the core infection algorithms of the EPIRICE model. The daily risk scores generated by the EPIRICE Daily Risk Model were successfully converted into a realistic and measurable disease value through statistical analyses with 13 rice blast incidence datasets, and subsequently validated using the data from another rice blast experiment conducted in Icheon, South Korea, from 1974 to 2000. The sensitivity of the model to air temperature, relative humidity, and precipitation input variables was examined, and the relative humidity resulted in the most sensitive response from the model. Overall, our results indicate that the EPIRICE Daily Risk Model can be used to produce potential disease risk predictions for the seasonal disease early warning service.

• Journal of Korean Society on Water Environment
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• v.25 no.1
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• pp.26-36
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• 2009

Combined sewer system (CSS) has been built in the most urban areas across the nation. During dry weather conditions, CSS works fine. But during heavy rain storms, combined sewage frequently overflows into the stream. This study simulated the hydrologic cycle and pollutant loads (BOD, SS, TN and TP) in the Mokgamcheon watershed considering combined sewer overflows (CSOs). PC storm water management model (PCSWMM) was used for continuous simulation and CSOs are considered using the flow divider. Sensitivity analysis, calibration and verification for water quantity and quality are carried out. To verify CSOs, field measurements of CSOs are compared with simulated results. As a result, 41.3% of precipitation flows into the stream directly and 1.1% of water supply flows into stream as CSOs. 6.5% of BOD total loads, 12.0% of SS, 13.6% of TP, and 29.2% of TN are from CSOs. This result will be effective to the integrated watershed management for sustainability.

• Proceedings of the Korea Water Resources Association Conference
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• 2005.09b
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• pp.1179-1180
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• 2005

To immobilize the pollutants from wastewater in situ, two phosphatic clays collected from different areas in Egypt (eastern and western Sebaia, Aswan-Isna, Upper Egypt) used to remove contaminant ions from industrial wastewater. Obtained results confirmed the strong relationship between phosphatic clay and Pb elimination from wastewater. The sensitivity classification of phosphatic clay toward ions retained as described in three categories: highly sensitive to retain Pb , Al and Cr ; moderately sensitive for Mn; and weakly sensitive for Band Zn. Data suggested that large fraction of Pb removed by phosphatic clays stayed intact under a wide variation in extracting solution pH (3-11). In situ immobilization is considered a promising technique that has the potential to remove contaminant ions from wastewater. Two important factors need to be considered when applying this technique: The first, is the clay must be effective and selective under different composition of wastewater. The second, is the immobilized ions should be stable and non-leacheable under varying water conditions. Phosphatic clays with $Pb^{2+}$ were suitable to achieve these two factors. Possible mechanism for removal $Pb^{2+}$ by phosphatic clays is the formation of fluoropyromorphite through the dissolution of fluoro and hydroxyl apatite by its precipitation from solution, beside, Pb complexation at phosphatic clay surface at P-OH sites.

• Korean Chemical Engineering Research
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• v.55 no.3
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• pp.287-295
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• 2017

Using nanotechnology, magnetic nanoparticles of iron oxide were produced via co-precipitation method and followed modification with organic compounds. In the next step, functionalized monomer was provided via coupling ${\beta}$-cyclodextrine and allylamine onto modified magnetic nanoparticles. These nanoparticles were used to establish the adsorption rate of celecoxib. Magnetic nanoparticles are modified by (3-mercaptopropyl)trimethoxysilane. Nano-adsorbent was characterized by analytical and spectroscopic methods, such as Fourier transform infrared spectroscopy, elemental analysis, thermo-gravimetric analysis, and transmission electron microscopy (TEM). Laboratory parameters, such as the kinetics of adsorption isotherms, pH, reaction temperature and capacity were optimized. Finally, by using this nano-adsorbent in the optimized condition, extraction of celecoxib from biological samples as urine, drug matrix and blood plasma was carried out by high performance liquid chromatography with sensitivity and high accuracy.