• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.240-244
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• 1998

This study was carried out to investigate the efficiency of steel mill slag and sludge in removing heavy metals and cyanide in metal plating wastewater. Laboratory experiments were peformed with jar tester, The tests were peformed at ambient temperature. The results of tests showed that overall rates metals removed were greater than 90 %. Metals were removed from solution as the combined effects of adsorption and precipitation in alkaline condition. The removal efficiency of cyanide by steel mill wastes was above 90 % at optimum conditions. In view of the test results and other engineering characteristics of steel mill slag and sludge, these industrial by-products from steel industry have a high potential to be used in metal plating wastewater treament and were particularly beneficial.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.1
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• pp.102-108
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• 2002

The effects of ammonia on mesophilic anaerobic digestion were investigated by operating lab-scale two-stage ASBF reactors using swine wastewaters as influent without and with ammonia removal at HRT of 1-2 days and OLR of $2.2{\sim}9.6kg-COD/m^3{\cdot}d$ for 250 days. The COD removal efficiency and biogas generation of two-stage ASBF reactors was decreased by increasing influent ammonia concentrations to 1,580 mg(T-N)/L with increasing OLR to $6.3kg-COD/m^3{\cdot}d$, while those were increased by maintaining influent ammonia concentrations below 340 mg(T-N)/L by MAP precipitation with increasing OLR to $9.6kg-COD/m^3{\cdot}d$. Initial inhibirion of ammonia on anaerobic processes was observed at a concentration of 760 mg(T-N)/L and the COD removal efficiency and biogas generation dropped to 1/2 at ammonia concentration ranges of 1,540~1,870 mg(T-N)/L. It is essential to remove ammonia in swine wastewaters to an initial inhibition level before anaerobic processes for the effective removal of COD.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.140-144
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• 2000

In treatment of contaminated ground by electrokinetic remediation, pH control is the main prolllem for enhancinfi remediation efficiency. In this study, analysed pH variation characteristics according to contaminant(Pb$^{2+}$) concentration and estimated remediation efficiency with organic acid to prevent precipitation in cathode due to hydroxide ion occurrence. Because most of transported Pb$^{2+}$ is precipitatecl according as pH is increased at specimen adjacent to cathode reservoir, little magnitude of Pb$^{2+}$ is flowed out of specimen.cimen.

• Mass Spectrometry Letters
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• v.5 no.1
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• pp.30-33
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• 2014

A solid phase extraction (SPE) method was optimized for the quantitative analysis of perfluorooctanoic acid (PFOA) in serum using hydrophilic-lipophilic balance SPE and LC-MS/MS. Fetal bovine serums spiked with $^{13}C_8$-PFOA before or after SPE were used as test samples for evaluation of the SPE efficiency. Simultaneous evaluation of matrix effects and absolute SPE recovery for $^{13}C_8$-PFOA in serum using different sample pre-treatments and SPE conditions allowed optimization of SPE process efficiency with minimal matrix effect and decent SPE recovery. Introduction of protein precipitation as a sample pre-treatment procedure for serum samples before SPE generally decreased matrix effect in LC-MS/MS analysis and provided more stable recovery of PFOA.

• Journal of the Korean Society of Industry Convergence
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• v.7 no.1
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• pp.115-120
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• 2004

An indoor air cleaner consisting of a dielectric barrier discharge system and an electrostatic precipitator (ESP) was experimentally investigated. The function of the dielectric barrier discharge is to precharge particles by producing nonthermal plasma before indoor air enters ESP, leading to an enhancement in dust collection efficiency. The dependence of particle size distribution on the plasma discharge was examined to understand the mechanism of the particle precharging. The plasma discharge was found to increase the electrical force of the particles, rather than agglomerate them. Coarse particles in the range of 0.5 to $5.0{\mu}m$ were observed to be easily collected by this indoor air cleaner, and the present study laid emphasis on the removal of fine particles of $0.3{\mu}m$. The collection efficiency of the fine particles was largely enhanced by the plasma discharge.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.448-453
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• 2006

Electrical resistivity is an important property for the collection efficiency in the electrostatic precipitator. In this paper, electrical resistivities of tobacco dusts, yellow sand dusts and pine pollens are measured using a high voltage conductivity cell based on JIS B 9915. The resistivities of three kinds of indoor dusts are about $1{\times}10^7\;{\Omega}{\cdot}cm^2$ in the normal range and dust collection efficiency using an electrostatic precipitator at to face velocity of 1.0 m/s shows over 99% for the three kinds of indoor dusts.

• Journal of Soil and Groundwater Environment
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• v.20 no.7
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• pp.103-111
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• 2015

Soil washing with ethylenediaminetetraacetic acid (EDTA) is highly effective in the remediation of soils contaminated with heavy metals. The EDTA recycling process is a requisite for reducing the operating cost. The applicability of Na₂S addition on the precipitation of heavy metals from the spent soil washing solution and thereby recycling of EDTA was investigated. Addition of Na₂S into the single metal-EDTA and the mixed metal-EDTA solutions ([Na₂S]/[metal-EDTA] ratio = 30, reaction time = 30 min and pH = 7~9) was highly effective in the separation of Cu and Pb from metal-EDTA complexes, but not for Ni. The Zn removal efficiency varied with pH and slightly increased upto 40% as the reaction time increased from 0 to 240 min which was longer than those for Cu and Pb. Ca(OH)₂ was subsequently added to induce further precipitation of Zn and Ni and to reduce the Na₂S dose. At the [Na₂S]/[metal-EDTA] ratio of 10, the removal efficiencies of all heavy metals excluding Ni were above 98% with the dose of Ca(OH)₂ at 0.002, 0.006 and 0.008 g into 100 mL of Cu-, Pb- and Zn-EDTA solutions, respectively. However, Ca(OH)₂ addition was not effective for Ni-EDTA solution. A further research is needed to improve metal removal efficiency and subsequent EDTA recycling for the real application in field-contaminated soils.

• Journal of the Korean Institute of Telematics and Electronics T
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• v.35T no.2
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• pp.66-71
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• 1998

A compact ESP of two-stage type is widely used with positive corona discharge in working environment where the production of ozone is extreamly prohibited. Since there are few scientific reports on a compact ESP, we have investigated the fundamental characteristics of a two-stage ESP. A model two-stage ESP is made with simple structure in order to simplify theoretical analysis and the relative position of the ionizer and collector section can be changed. The experimental investigation revealed many interesting facts.: The electric field in the collector electrodes affects the corona discharge of the ionizer. The concentration of particles after collector remarkably varied in the region between the high voltage and grounded electrodes. The collection efficiency right behind the high voltage electrode is much greater than that behind the grounded one. The total collection efficiency, calculated by integrating the particle concentration in whole measuring region, is greater when the high voltage electrode of the collector is located behind the discharge electrode of ionizer. Thus, the relative position of the ionizer and collector electrodes affects the precipitation characteristics.

• Journal of Soil and Groundwater Environment
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• v.27 no.1
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• pp.25-30
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• 2022

Mackinawite (FeS), as a ubiquitous reduced iron mineral, is known as a key controller of redox reactions in anaerobic subsurface environment. The reaction of FeS with redox-sensitive toxic element such as arsenic is substantially affected by pH conditions of the given environments. In this study, the interaction of As(V) with FeS was studied under strict anaerobic conditions with various pH conditions. The pH-dependent arsenic removal tests were conducted under wide ranges of pH conditions and X-ray absorption spectroscopy (XAS) was applied to investigate the reaction mechanisms under pH 5, 7, and 9. The removal efficiency of FeS for As(V) showed the higher removal of As(V) under low pH conditions and its removal efficiency decreased with increasing pH, and no As(V) reduction was observed in 1 g/L FeS solution. However, XAS analysis indicated the reduction of As(V) to As(III) occurred during reaction between FeS and As(V). The reduced form of As(III) was particularly identified as an arsenic sulfide mineral (As₂S₃) in all pH conditions (pH 5, 7, and 9). As₂S₃ precipitation was more pronounced in pH 5 where the solubility of FeS is higher than in other pH conditions. The linear combination fitting results of XAS demonstrated that As(V) removal mechanism is concerted processes of As₂S₃ precipitation and surface complexation of both arsenic species.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.466-470
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• 2022

The catalytic thermal oxidizer process has recently attracted considerable attention for the oxidation and decomposition of volatile organic compounds at low temperatures (< 450 ℃) with high efficiency (> 95%). Although many noble metal catalytic materials are well established, they are expensive and hazardous. Herein, highly active and low-cost Cu-Mn bimetallic catalysts were prepared using a simple and facile synthesis method involving the co-precipitation of Cu and Mn precursors. The synthesis of the catalyst was optimized by controlling the composition ratio of Cu and Mn. The optimized catalyst exhibited a large surface area of 230.8 m²/g with a mesoporous structure. To demonstrate the catalytic performance, the Cu-Mn catalyst was tested for the oxidation reaction of ethyl acetate, showing a high conversion efficiency of 100% at a low temperature of 250 ℃.