• Korean Journal of Materials Research
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• v.22 no.6
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• pp.298-302
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• 2012

Fe/$SiO_2$ core-shell type composite nanoparticles have been synthesized using a reverse micelle process combined with metal alkoxide hydrolysis and condensation. Nano-sized $SiO_2$ composite particles with a core-shell structure were prepared by arrested precipitation of Fe clusters in reverse micelles, followed by hydrolysis and condensation of organometallic precursors in micro-emulsion matrices. Microstructural and chemical analyses of Fe/$SiO_2$ core-shell type composite nanoparticles were carried out by TEM and EDS. The size of the particles and the thickness of the coating could be controlled by manipulating the relative rates of the hydrolysis and condensation reaction of TEOS within the micro-emulsion. The water/surfactant molar ratio influenced the Fe particle distribution of the core-shell composite particles, and the distribution of Fe particles was broadened as R increased. The particle size of Fe increased linearly with increasing $FeNO_3$ solution concentration. The average size of the cluster was found to depend on the micelle size, the nature of the solvent, and the concentration of the reagent. The average size of synthesized Fe/$SiO_2$ core-shell type composite nanoparticles was in a range of 10-30 nm and Fe particles were 1.5-7 nm in size. The effects of synthesis parameters, such as the molar ratio of water to TEOS and the molar ratio of water to surfactant, are discussed.

• Atmosphere
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• v.27 no.2
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• pp.163-175
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• 2017

The global terrestrial ecosystems have shown a large spatial variability in recent decades and represented a carbon sink pattern at mid-to-high latitude in Northern Hemisphere. However, there are many uncertainties in magnitude and spatial distribution of terrestrial carbon fluxes due to the effect of climate factors. So, it needs to accurately understand the spatio-temporal variations on carbon exchange flux with climate. This study focused on the effects of climate factors, .i.e. temperature, precipitation, and solar radiation, to terrestrial biosphere carbon flux. We used the terrestrial carbon flux that is simulated by a CarbonTracker, which performs data assimilation of global atmospheric $CO_2$ mole fraction measurements. We demonstrated significant interactions between Net Ecosystem Production (NEP) and climate factors by using the partial correlation analysis. NEP showed positive correlation with temperature at mid-to-high latitude in Northern Hemisphere but showed negative correlation pattern at $0-30^{\circ}N$. Also, NEP represented mostly negative correlation with precipitation at $60^{\circ}S-30^{\circ}N$. Solar radiation affected NEP positively at all latitudes and percentage of positive correlation at tropical regions was relatively lower than other latitudes. Spring and summer warming had potentially positive effect on NEP in Northern Hemisphere. On the other hand as increasing the temperature in autumn, NEP was largely reduced in most northern terrestrial ecosystems. The NEP variability that depends on climate factors also differently represented with the type of vegetation. Especially in crop regions, land carbon sinks had positive correlation with temperature but showed negative correlation with precipitation.

• Magazine of the Korean Society of Agricultural Engineers
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• v.32 no.1
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• pp.103-109
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• 1990

The application of the Log-Pearson Type m distribution recommended by Water Resources Council, U. S. A. for flood frequency analysis requires the estimation of the regionalized skew coefficient. In this study, regionalized skew coefficients are estimated using a weighted regression model which relates at-site skews based on logarithms of observed annual flood peak series to both basin characteristics and precipitation data in the Han river and the Nakdong river basin. The model is developed with weighted least squares method in which the weights are determined by separating residual variance into that due to model error and due to sampling error. As the result of analysis, regionalized skews are estimated as - 0.732 and - 0.575 in the Han river and the Nakdong river basin, respectively.

• Journal of the Korean Society for Heat Treatment
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• v.2 no.4
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• pp.19-26
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• 1989

Fundmental fatigue crack propagation tests with C-T type specimens were conducted at various load ratios (R) such as 0.1, 0.3 and 0.5 in T6 and Thermomechanically treated (TMT) conditions of 7039 Al alloy. Better mechanical properties from monotonic test as well as fatigue crack propagation were obtained by TMT process owing to uniform distribution of fine microstructures and non-existence of precipitation free zone (PFZ). Through the measurement of Kop and ${\Delta}K$ at various R the concept of effective stress intensity factor range ratio, U was reviewed to asses the load ratio effect on fatigue crack propagation. A relationship between U and variables such as ${\Delta}K$ and R was obtained empirically. This may enable us to predict ${\Delta}K_{eff}$ that is of critical importance for prediction of fatigue crack propagation rate.

• Journal of the Korean earth science society
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• v.42 no.5
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• pp.556-570
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• 2021

This study presents the data analysis results of groundwater chemistry and the occurrence of fluoride in groundwater obtained from the groundwater quality monitoring network of Korea. The groundwater data were collected from the National Groundwater Information Center and censored for erratic values and charge balance (±10%). From the geochemical graphs and various ionic ratios, it was observed that the Ca-HCO₃ type was predominant in Korean groundwater. In addition, water-rock interaction was identified as a key chemical process controlling groundwater chemistry, while precipitation and evaporation were found to be less important. According to a non-parametric trend test, at p=0.05, the concentration of fluoride in groundwater did not increase significantly and only 4.3% of the total groundwater exceeded the Korean drinking water standard of 1.5 mg/L. However, student t-tests revealed that the fluoride concentrations were closely associated with the lithologies of tuff, granite porphyry, and metamorphic rocks showing distinctively high levels. This study enhances our understanding of groundwater chemical composition and major controlling factors of fluoride occurrence and distribution in Korean groundwater.

• Water Engineering Research
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• v.6 no.2
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• pp.73-89
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• 2005

Two kinds of high resolution GCMs with the same spatial resolutions but with different schemes run by domestic and foreign agencies are used to clarify the usefulness and sensitivity of GCM for water resources applications for Korea. One is AMIP-II (Atmospheric Model Intercomparison Project-II) type GCM simulation results done by ECMWF (European Centre for Medium-Range Weather Forecasts) and the other one is AMIP-I type GCM simulation results done by METRI (Korean Meteorological Research Institute). Observed mean areal precipitation, temperature, and discharge values on 7 major river basins were used for target variables. Monte Carlo simulation was used to establish the significance of the estimator values. Sensitivity analyses were done in accordance with the proposed ways. Through the various tests, discrimination condition is sensitive for the distribution of the data. Window size is sensitive for the data variation and the area of the basins. Discrimination abilities of each nodal value affects on the correct association. In addition to theses sensitivity analyses results, we also noticed some characteristics of each GCM. For Korean water resources, monthly and small window setting analyses are recommended using GCMs.

• Journal of Korea Water Resources Association
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• v.40 no.9
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• pp.697-707
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• 2007

In this study, we estimated the PMP(Probable Maximum Precipitation) and its transition in case of the typhoon Rusa which happened the biggest damage of all typhoons in the Korea. Specially, we analysed the moisture maximizing rate under the consideration of meteorological condition based on the orographic property when it hits in Gangneung region. The PMP is calculated by the rate of the maximum persisting 12 hours 1000 hPa dew points and representative persisting 12 hours 1000 hPa dew point. The former is influenced by the moisture inflow regions. These regions are determined by the surface wind direction, 850 hPa moisture flux and streamline, which are the critically different aspects compared to that of previous study. The latter is calculated using statistics program (FARD2002) provided by NIDP(National Institute for Disaster Prevention). In this program, the dew point is calculated by reappearance period 50-year frequency analysis from 5% of the level of significant when probability distribution type is applied extreme type I (Gumbel distribution) and parameter estimation method is used the Moment method. So this study indicated for small basin$(3.76km^2)$ the difference the PMP through new method and through existing result of established storm transposition and DAD(Depth-Area-Duration). Consequently, the moisture maximizing rate is calculated in the moisture inflow regions determined by meteorological fields is higher $0.20{\sim}0.40$ range than that of previous study. And the precipitation is increased $16{\sim}31%$ when this rate is applied for calculation.

• Korean Chemical Engineering Research
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• v.51 no.2
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• pp.195-202
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• 2013

$TiO_2$ powders were prepared from titanium (IV) sulfate ($Ti(SO_4)_2$) solution using ammonia solution at low reaction temperature ($80{\sim}100^{\circ}C$) and atmospheric pressure by hydrothermal precipitation method without calcination. The effect of reaction conditions, such as reaction temperature, initial concentration of titanium (IV) sulfate ($Ti(SO_4)_2$) solution, pH of mixture solution and the physical properties of the prepared $TiO_2$, such as crystallite structure, crystallite size were investigated. The photocatalytic activity of prepared $TiO_2$ was tested by the photolysis of brilliant blue FCF (BB-FCF) under the UV and the analysis of UV-VIS diffuse reflectance spectroscopy (DRS). The physical properties of prepared $TiO_2$ were examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectrometer (PL), particle size distribution measurements. The crystallite size and crystallinity of prepared $TiO_2$ increased with increasing titanium (IV) sulfate ($Ti(SO_4)_2$) concentration, but photocatalytic activity decreased. The crystallite size decreased with increasing pH of mixture solution, but photocatalytic activity increased. The crystallinity and photocatalytic activity increased with increasing reaction temperature. The results showed that anatase type $TiO_2$ could be prepared by hydrothermal precipitation method using titanium (IV) sulfate ($Ti(SO_4)_2$) solution and ammonia solution at low reaction temperature and atmospheric pressure without calcination.

• Korean Journal of Agricultural and Forest Meteorology
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• v.16 no.4
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• pp.359-367
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• 2014

Drought index can be used to implement an early warning system for drought and to operate a drought monitoring service. In this study, an approach was examined to determine agricultural drought index (ADI) at high spatial resolution, e.g., 270 m. The value of ADI was calculated based on soil water balance between supply and demand of water. Water supply is calculated by the cumulative effective precipitation with the application of the weight to the precipitation from two months ago. Water demand is derived from the actual evapotranspiration, which was calculated applying a crop coefficient to the reference evapotranspiration. The amount of surface runoff on a given soil type was also used to calculate soil residual moisture. Presence of drought was determined based on the probability distribution in the given area. In order to assess the reliability of this index, the amount of residual moisture, which represents severity of drought, was compared with measurements of soil moisture at three experimental between July 2012 and December 2013. As a result, the ADI had greater correlation with measured soil moisture compared with the standardized precipitation index, which suggested that the ADI would be useful for drought warning services.

• Journal of the Korean Electrochemical Society
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• v.10 no.1
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• pp.48-51
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• 2007

In order to investigate the effects of particle size and specific surface area(BET area) of spinel powder, $LiMn_2O_4$ were synthesized using metal oxide precursor by co-precipitation method(CoP) and solid state reaction (SSR) .X-ray diffraction(XRD) patterns revealed that the both prepared powder has a well developed spinel structure with Fd3m space group. The $LiMn_2O_4$ prepared by co-precipitation showed spherical morphology with narrow size distribution. However, the $LiMn_2O_4$ prepared by solid state reaction showed relatively smaller particles with irregular shape. The measured BET areas of the powers are $0.8m^2g^{-1}$ (CoP) and $3.6m^2g^{-1}$(SSR). The electrochemical performance of the Prepared $LiMn_2O_4$ powders was evaluated using coin type cells(CR2032) at elevated temperature ($55^{\circ}C$). The $LiMn_2O_4$ prepared by co-precipitation showed the better cycling performance(82.3%capacity retention at $50^{th}$ cycle) than that of the $LiMn_2O_4$(68.3%) prepared by solid state reaction at elevated temperature.