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The genetic implication of gold-silver mineralization in the Suryun mine, Korea

  • Pak, Sang-Joon;Park, Seon-Gyu;Song, Yun-Sub;Park, Sang-Hoon
    • Proceedings of the KSEEG Conference
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    • 2003.04a
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    • pp.186-188
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    • 2003
  • The Suryun gold-silver mine is one of precious metal occurrences discovered in the Hapcheon mineralized district on which lies the western margin of the Cretaceous Gyeongsang Basin, Korea. The district hosts deposits that include the early to late Cretaceous (108 ~ 88 Ma) Au-Ag-bearing vein systems (So et al. 1989; Shelton et al. 1990). (omitted)

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Fabrication of Metal Discs Using Molten Tin and Brass Droplets (주석과 황동 용탕 드롭렛을 이용한 디스크형 응고체 제조)

  • Song, Jeongho;Lee, Tae-Kyeong;Rhee, Gwang-Hoon;Song, Ohsung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.714-721
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    • 2016
  • This paper proposes a simple process to fabricate tin and brass metal discs with a large surface area from molten droplets for the wet-refining process of nonferrous metals by assuming they have precious metal elements. To optimize the droplet condition in a graphite crucible, the appropriate nozzle size was determined using a simulation program (STAR-CCM+) by varying the diameters (0.5, 1.0, and 2.0 mm). The simulation results showed that both tin and brass do not fall out with a 0.5 mm diameter nozzle but they do fall out in continuous ribbon mode with a 2.0 mm nozzle. Only the 1.0mm nozzle was expected to fabricate droplets. Finally, solidified metal discs were fabricated successfully with the 1.0 mm nozzle within 10 minutes by impacting the droplets with a cooling water flowing over a Ti plate placed at the $40^{\circ}$ falling direction. The weight, average thickness, and surface area of the tin discs were 0.15 g, $107.8{\mu}m$, and $3.71cm^2$, respectively. The brass discs were 1.16 g, $129.15{\mu}m$, and $23.98cm^2$, respectively. The surface area of the tin and brass disc were 8.2 and 17.6 times the size of the tin and brass droplets, respectively. This process for precious metal extraction is expected to save cost and time.

Electro-refining Characteristics of PCB-based Copper Anode for the Enrichment of Precious Metals (귀금속 농축을 위한 PCB 기반 양극동의 전해정련 특성)

  • Ahn, Nak-Kyoon;Shim, Hyun-Woo;Park, Kyung-Soo;Park, Jeung-Jin
    • Resources Recycling
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    • v.27 no.5
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    • pp.14-22
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    • 2018
  • In this study, scarp of PCB containing copper and precious metals was manufactured as an anode, and electrorefining experiments were conducted on change of $H_2SO_4$ concentration and current density. Through electrolytic refining experiments, the concentration of Cu and slime recovered from each electrode was analyzed, element behavior was confirmed, and current efficiency was also calculated. As the $H_2SO_4$ concentration was increased, the current efficiency and the purity of Cu decreased, but the precious metals in the anode slime were maximally concentrated with 2.0 M $H_2SO_4$. In addition, as the current density was increased, the current efficiency decreased and the purity of Cu showed a tendency to increase, and the precious metals in the anode slime were maximally concentrated with $300A/m^2$. As a result of the pilot scale experiments, the Au content was 8,705 mg/kg, the Ag content was 35,092 mg/kg in the anode slime. As compared with the initial content, Au was concentrated 16 times and Ag concentrated 14 times.

COMPARATIVE STUDY ON THE FRACTURE STRENGTH OF METAL-CERAMIC VERSUS COMPOSITE RESIN-VENEERED METAL CROWNS IN CEMENT-RETAINED IMPLANT-SUPPORTED CROWNS UNDER VERTICAL COMPRESSIVE LOAD

  • Pae, Ahran;Jeon, Kyung-A;Kim, Myung-Rae;Kim, Sung-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.3
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    • pp.295-302
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    • 2007
  • Statement of problem. Fracture of the tooth-colored superstructure material is one of the main prosthetic complications in implant-supported prostheses. Purpose. The purpose of this in vitro study was to compare the fracture strength between the cement-retained implant-supported metal-ceramic crowns and the indirect composite resinveneered metal crowns under the vertical compressive load. Material and methods. Standard implants of external type (AVANA IFR 415 Pre-mount; Osstem Co., Busan, Korea) were embedded in stainless steel blocks perpendicular to their long axis. Customized abutments were fabricated using plastic UCLA abutments (Esthetic plastic cylinder; Osstem Co., Busan, Korea). Thirty standardized copings were cast with non-precious metal (Rexillium III, Pentron, Walling ford, Conn., USA). Copings were divided into two groups of 15 specimens each (n = 15). For Group I specimens, metal-ceramic crowns were fabricated. For Group II specimens, composite resin-veneered (Sinfony, 3M-ESPE, St. Paul, MN, USA) metal crowns (Sinfony-veneered crowns) were fabricated according to manufacturer's instructions. All crowns were temporary cemented and vertically loaded with an Instron universal testing machine (Instron 3366, Instron Corp., Norwood, MA, USA). The maximum load value (N) at the moment of complete failure was recorded and all data were statistically analyzed by independent sample t-test at the significance level of 0.05. The modes of failure were also investigated with visual analysis. Results. The fracture strength of Sinfony-veneered crowns ($2292.7{\pm}576.0N$) was significantly greater than that of metal-ceramic crowns ($1150.6{\pm}268.2N$) (P < 0.05). With regard to the failure mode, Sinfony-veneered crowns exhibited adhesive failure, while metal-ceramic crowns tended to fracture in a manner that resulted in combined failure. Conclusion. Sinfony-veneered crowns demonstrated a significantly higher fracture strength than that of metal-ceramic crowns in cement-retained implant-supported prostheses.

Total value recovery in the copper smelting and refining operations

  • Kim Joe. Y.;Kong Bong S.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.590-597
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    • 2003
  • Processing and smelting of copper containing sulphide concentrates result in the accumulation of impurities into various process streams. All primary copper smelters and refineries around the world produce significant amounts of slag, dust, sludge, residues and others, which contain copper and precious metals. The recovery of these valuable metals is essential to the overall economics of the smelting process. Physical, chemical and mineralogical characterization of particular slag and Cottrell dusts from primary smelters and $Dor\'{e}$ furnace (TBRC) slag and Pressure Leached Anode slimes from a copper refinery have been carried out to understand the basic behind the recovery processes. Various process options have been evaluated and adapted for the treatment of slag from different smelting furnaces and Cottrell dusts as well as the intermediate products from copper refineries. Besides the hydro- or pyro-metallurgical treatments, the above mentioned physical separation options such as magnetic, gravity separation, flotation and precipitation flotation processes have been successfully identified and adapted as the possible process options to produce a Cu-rich or precious metal-rich concentrates for in-house recycling and other valued by-product for further treatment. The results of laboratory, pilot plant and production operations are presented, and incorporation of several alternative flowsheet is discussed in this paper.

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Continuous electricity generation in microbial fuel cells with non-precious metal catalysts (비귀금속촉매 미생물연료전지의 연속운전을 통한 전기 생산)

  • Moon, Chungman;Kim, Dong-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.1
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    • pp.45-51
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    • 2015
  • In this study, continuous microbial fuel cells (MFCs) were operated using non-precious metal catalysts such as iron(II) phthalocyanine (FePc) and cobalt tetramethoxyphenylporphyrin (CoTMPP)) as alternative cathode catalysts for platinum. To evaluate MFCs performance, operational conditions of organic loading rate (OLR) (0.5~3 g COD/L/d) and hydraulic retention rate (HRT) (0.25~1 day) were changed. Power density of MFCs were determined by cathode electrode performance. The maximum power density was $3.3W/m^3$ with platinum at OLR 3 g COD/L/d. Given each HRTs at 1 g COD/L/d, FePc showed to be a better alternative for platinum than CoTMPP because the power density of MFC with FePc was similar to that of MFC with platinum. CoTMPP catalyst, however, showed the lowest power density due to increase of internal resistance during continuous operation.

A Study on the Leaching of Gold and Silver from Concentrate by Acidothiouration (산성치오요소법에 의한 금정광으로부터 금, 은의 침출에 관한 연구)

  • 김성규;이화영;오종기
    • Resources Recycling
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    • v.3 no.2
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    • pp.17-23
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    • 1994
  • The dissolution of gold and silver from concentrate was studied with acidic thiourea solution. The results showed that the gold and silver extraction was severely affected by concentration of thiourea and oxidant, pulp density, etc. Especially, oxidant such as ferric ions enhanced the leching rate of gold and silver. High concentration of ferric ions, however, dissolved the sulfide ore to form electrochemically passive layer on the surface of ore particles, which caused the precious metal not to be leached out from the ore. The use of $SO_2$could not effectively enhance the recovery of precious metal but reduce to some extent the consumption of thiourea. The leaching of gold and silver was achieved with recovery more than 90% and 80%, respectively, under the following conditions; Thiourea conc. :0.4M Oxidant : None $H_2SO_4$ conc. : 0.5M Pulp density : <10% Leaching time :4 Hrs Potential :250mV The Thiourea was consumed about 10% in comparison with its initial concentration.

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A Study on the Castability of Non-precious Porcelain Metal According to Investing Method (매몰방법에 따른 도재용 비금속의 주조성에 관한 연구)

  • Lee, In-Kyu;Kim, Yong-Won
    • Journal of Technologic Dentistry
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    • v.19 no.1
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    • pp.5-12
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    • 1997
  • To examine the difference of castability of non -precious porcelain metal according to 2 type of investing method, experiments were carried out using the method of both existing investing method and the investment with spaces to the upper & lower parts of the ring. The following conclusion were obtained from the result. 1. Seperataly using the existing investment and with spaces to the upper & lower parts of the ring, 44 samples resulted in success with the former method and 52 with the latter out of 84 samples. 2. Under the existing investing method, 44 samples out of 56 total resulted in success when the temperature of the ring was $870^{\circ}C$, and all samples failed when the temperature was $800^{\circ}C$. 3. Under the investment that gives space to the ring, when casted with the temperature of the ring fixed at $870^{\circ}C$, 40 samples out of 56 and 17 samples with the temperature fixed at $800^{\circ}C$ resulted in success. 4. Under the existing investing method with the temperaure of the ring fixed at $870^{\circ}C$ and heat soaking time given an hour, 26 out of 28 samples resulted in success and 18 resulted the same with half an hour heat soaking time. 5. Using the investment that gives space to the ring, at ring temperature $870^{\circ}C$ with heat soaking time 1 hour, all of total 28 rusulted insuccess however only 12 smaples succeeded with 30 minutes heat soaking time. 6. Under the existing investing method, samples with heat soaking time 1 hour equally given at ring temperature $870^{\circ}C$, 26 samples out of 28 succeed however at $800^{\circ}C$ all samples failed. 7. In the case of ring's upper and lower parts opened ring temperature is $870^{\circ}C$ and $800^{\circ}C$ and the heat soaking time was fixed at 1 hour, all 28 samples resulted in success and at $800^{\circ}C$ 17 succeed.

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A Study on grand Preference and the Actual Condition by Wedding Fashion Masterpiece Consumer's Lifestyle Group (라이프스타일 집단별 혼례용 패션명품 소비자의 브랜드 선호도 및 구매행동 연구)

  • Park, Ok-Lyun;Ryu, Mi-Ae
    • Journal of Fashion Business
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    • v.12 no.5
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    • pp.67-76
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    • 2008
  • The study surveyed preference and Actual Condition of wedding fashion masterpiece brand by consumer's lifestyle group. First, it was found that the brand preference by wedding fashion masterpiece consumer was Bulgari in precious metal, Burberry in scarf, Louisvuitton in bag and Chanel in cosmetics. Second, as a study result of purchase status, wedding fashion masterpiece brand consumers, who enjoy shopping about 1 time a month, usually purchased the masterpiece in masterpiece hall of department store. Their total purchase amount for wedding was less than 5 million in most cases. Third, regarding purchase-experience brand by consumer's lifestyle group, in clothes, there was significant difference between 4 groups such as shopping unconcerned type, reasonable economic type, self-focused brand-oriented type and social achievement type. In bag, slight difference appeared in 4 groups. Fourth, as a study result of the brand preference by consumer's lifestyle group, there was somewhat significant difference between precious metal, clothes, scarf, bag and cosmetic variables. Fifth, as a study result of the difference of information source use by consumer's lifestyle group, it was found that social achievement type used most various sources such as commerce, store and personnel information. Sixth, as a study result of shopping trend by consumer's lifestyle group, social achievement group searched for pleasure, unique personality and ostentation. Shopping unconcerned type searched for necessary shopping with comfortable style without sparing time in shopping.

Effect of Iron Species in Mesoporous Fe-N/C Catalysts with Different Shapes on Activity Towards Oxygen Reduction Reaction

  • Kang, Taehong;Lee, Jiyeon;Kim, Jong Gyeong;Pak, Chanho
    • Journal of Electrochemical Science and Technology
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    • v.12 no.1
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    • pp.137-145
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    • 2021
  • Among the non-precious metal catalysts, iron-nitrogen doped carbon (Fe-N/C) catalysts have been recognized as the most promising candidates for an alternative to Pt-based catalysts for the oxygen reduction reaction (ORR) under alkaline and acidic conditions. In this study, the nano replication method using mesoporous silica, which features tunable primary particle sizes and shape, is employed to prepare the mesoporous Fe-N/C catalysts with different shapes. Platelet SBA-15, irregular KIT-6, and spherical silica particle (SSP) were selected as a template to generate three different kinds of shapes of the mesoporous Fe-N/C catalyst. Physicochemical properties of mesoporous Fe-N/C catalysts are characterized by using small-angle X-ray diffraction, nitrogen adsorption-desorption isotherms, and scanning electron microscopy images. According to the electrochemical evaluation, there is no morphological preference of mesoporous Fe-N/C catalysts toward the ORR activity with half-cell configuration under alkaline electrolyte. By implementing X-ray photoelectron spectroscopy analysis of Fe and N atoms in the mesoporous Fe-N/C catalysts, it is possible to verify that the activity towards ORR highly depends on the portions of "Fe-N" species in the catalysts regardless of the shape of catalysts. It was suggested that active site distribution in the Fe-N/C is one important factor towards ORR activity.