• 제목/요약/키워드: precious metal

검색결과 201건 처리시간 0.033초

치아에 잔존하는 치과재료의 성분분석을 통한 개인식별에의 응용 (Analysis of Residual Dental Materials Existing on the Teeth and Its Application to Individual Identification)

  • 윤중교;최종훈;김종열
    • Journal of Oral Medicine and Pain
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    • 제23권2호
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    • pp.193-209
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    • 1998
  • In identifying bodies that are severely decayed or damaged, methods using fingerprints and various biochemical tests are known to have its limits. To overcome this, forensic odontological method which is based on the analysis of the cranium, tooth and dental restoration is used to enhance the accuracey of individual identification. For this reason, I have come to analysis of the dental materials that exists between the teeth that is perceived to have been previously restored and the one adjacent to it. By analyzing the constituents of gold crown-restored, non-precious metal-restored, gold inlay-restored and amalgam -restored teeth, and adjacent teeth using EDX(energy dispersive X-ray microanalysis) which was invented to analyze very small amount of elements, the nature of the restoration could be predicted and the results obtained were as follows. 1. Some of constitute of gold alloy was extracted from residual cement of gold crown restoration, but that was not extracted from the restored tooth and the one adjacent to it. 2. Some of constituents of non-precious metal alloy was extracted both in the residual cement on the tooth with no-precious metal restoration and in the tooth with the restoration itself. However, none of its constituents were found in the tooth adjacent to it. 3. Some of constituents of gold alloy were found in the residual cement of gold inlay, but they were not found in the restored tooth and the adjacent tooth. 4. Some of constituents of amalgam alloy were found both in tooth restored with amalgam and in the adjacent tooth. From the results obtained above, it is possible to utilize the data obtained from analyizing residual dental materials in a more effective way. This data compensates for the lost data due to any harm done to the restorations prior to individual identification and further enhances the accuracy. Therefore, it could be concluded that this process of analyzing residual dental materials could be beneficial to individual identification in the area of forensic odontoldogy.

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치과용 임플란트 적용 비귀금속 코어와 관련된 전조골세포의 변화 (Changes in pre-osteoblast cells associated with non-precious metal cores with dental implants: Pilot test)

  • 박정현;강신영;김종우;김장주;김웅철;김지환
    • 대한치과기공학회지
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    • 제40권2호
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    • pp.63-69
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    • 2018
  • Purpose: The purpose of this study is to investigate the non-precious metal core materials used in the dental laboratory to fabricate the implant superstructure by CAD / CAM method. And to observe and compare the morphology and distribution of the osteoblasts in relation to implant osseointegration. Methods: In this study, the mandibular right first molar tooth model was selected as an international standard to produce a single core. Using this model, the impression was made with the silicone rubber, the tooth model was scanned, and a single core was designed and 5-axis milling was performed. The materials used were Cobalt-Chromium and Nickel-Chromium, and the cores for dental implant top structures were fabricated according to the procedures of the dental labs. After the fabrication, the marginal area of the core was separated and cell culture experiment was performed. The osteoblast cells used MC3T3-E1, which is currently widely used. For morphological analysis of osteoblasts, cells were posttreated and observed using CLSM (Confocal Laser Scanning Microscope) and compared. Results: The cell adhesion behavior of the specimen surface measured by CLSM was uniformly distributed in specimen A (Cobalt-Chromium) than in specimen B (Nickel-Chromium). The distribution and changes of the cells were different in the two specimens. Conclusion : It is possible to confirm that specimen A (Cobalt-Chromium) is suitable for the living body through adhesion and proliferation of osteoblasts related to implant osseointegration in the non-precious metal superstructure used after implantation. It is considered that it is preferable to use Co-Cr when fabricating the superstructure.

Chemical Active Liquid Membranes in Inorganic Supports for Metal Ion Separations

  • Yi, Jongheop
    • 한국막학회:학술대회논문집
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    • 한국막학회 1994년도 추계 총회 및 학술발표회
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    • pp.8-11
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    • 1994
  • Disposal of hazardous ions in the aqueous streams is a significant industrial waste problem.. Waste streams from electronics, electroplating, and photographic industries contain metal ions such as copper, nickel, zinc, chromium(IV), cadmium, aluminum, silver, and gold, amongst others in various aqueous solutions such as sulfates, chlorides, fluorocarbons, and cyanides. Typical plating solutions having similar compositions are listed in Table 1. Spent process streams in catalyst manufacturing facilities also contain precious metals such as Ag, Pt, and Pd. Developing an effective recovery process of these metal ions for reuse is important.

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귀금속촉매하에서 암모니아의 전환반응 (Ammonia Conversion in the Presence of Precious Metal Catalysts)

  • 장현태;박윤국;고용식
    • Korean Chemical Engineering Research
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    • 제46권4호
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    • pp.806-812
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    • 2008
  • 귀금속촉매 존재하에서 암모니아 전환반응은 배가스내의 암모니아를 처리하는데 중요한 기술이다. 과잉용액 함침법을 이용하여 $Pt-Rh/Al_2O_3$, $Pt-Rh/TiO_2$, $Pt-Rh/ZrO_2$, $Pt-Pd/Al_2O_3$, $Pd-Rh/Al_2O_3$, $Pd-Rh/TiO_2$, $Pd-Rh/ZrO_2$, $Pt-Pd-Rh/Al_2O_3$, $Pd/Ga-Al_2O_3$, $Rh/Ga-Al_2O_3$, 그리고 $Ru/Ga-Al_2O_3$의 촉매를 제조하였다. 제조된 촉매는 1/4"의 반응기에 $10,000{\sim}50,000hr^{-1}$의 공간속도 조건하에서 촉매활성능 실험을 수행하였다. 암모니아의 초기농도는 2,000 ppm (나머지는 공기)으로 유지하였다. $T_{50}$는 암모니아 전환율이 50%일 때를 나타내는 온도를, $T_{90}$은 90%의 전환율일 때의 온도를 나타낸다. 알루미나를 담지체로 사용했을때의 $T_{50}$$T_{90}$은 다른 담체를 사용했을때의 $T_{50}$$T_{90}$보다 훨씬 낮았다. Pd-Rh촉매의 경우 $Al_2O_3$를 담체로 사용하였을 때 $ZrO_2$$TiO_2$보다 저온 활성이 우수하게 나타났다. 황산화물의 피독실험 결과 본 연구에서는 최종적으로 $Pt-Rh/Al_2O_3$ 촉매가 다른 촉매에 비하여 우수함을 보였다. 실험결과 Pt-Rh가 암모니아 전환공정에서 유용한 촉매라는 사실을 알 수 있다.

Optimal Metal Dose of Alternative Cathode Catalyst Considering Organic Substances in Single Chamber Microbial Fuel Cells

  • Nam, Joo-Youn;Moon, Chungman;Jeong, Emma;Lee, Won-Tae;Shin, Hang-Sik;Kim, Hyun-Woo
    • Environmental Engineering Research
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    • 제18권3호
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    • pp.145-150
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    • 2013
  • Optimal preparation guidelines of a cathode catalyst layer by non-precious metal catalysts were evaluated based on electrochemical performance in single-chamber microbial fuel cells (MFCs). Experiments for catalyst loading rate revealed that iron(II) phthalocyanine (FePc) can be a promising alternative, comparable to platinum (Pt) and cobalt tetramethoxyphenylporphyrin (CoTMPP), including effects of substrate concentration. Results showed that using an optimal FePc loading of $1mg/cm^2$ was equivalent to a Pt loading of $0.35mg/cm^2$ on the basis of maximum power density. Given higher loading rates or substrate concentrations, FePc proved to be a better alternative for Pt than CoTMPP. Under the optimal loading rate, it was further revealed that 40 wt% of FePc to carbon support allowed for the best power generation. These results suggest that proper control of the non-precious metal catalyst layer and substrate concentration are highly interrelated, and reveal how those combinations promote the economic power generation of single-chamber MFCs.

현대 패션디자인의 금속소재 연구 -모드사적 분석과 조형성를 중심으로- (Study on Metal material in Contemporary Fashion -Focus on analysis of mode history and the normativeness-)

  • 이영재
    • 한국의류학회지
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    • 제26권5호
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    • pp.582-593
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    • 2002
  • Metal materials have been used in the clothing design on the spirit of ingenious experiment by fashion designers, and they have been put to practical use by several designers who work out a scheme of popular fashion merchandise. This current starting from the 1960s was weakened in the 1980s, but it was appeared with various shapes of metal materials in the 1990s due to a popularity of techno/cyber fashion. Recently, textile engineering technology causes to develop new-materials which are practical and sanitary. The development of fashionable metal materials brings about the popularization of fashion with metal materials, and it induces that mainstream of modem fashion has been changed into designers of pursuing the spirit of ingenious experiment. This study examines the formative characteristics of metal materials that are based on the spirit of ingenious experiment. As a result, it is evaluated that the formative of metal materials shown in modern fashion is futurism, visual concentration, avast-garde, resistance, precious.

상이(霜異)한 Ceramometal System에 있어서 Nickel-Chromium합금과 도재(陶材)와의 결합강도(結合强度)에 관(關)한 비교실험연구(比較實驗硏究) (A Study of Bond Strength of Nickel-Chromium Alloys with Porcelain in Ceramometal System)

  • 김치영
    • 대한치과기공학회지
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    • 제7권1호
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    • pp.19-25
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    • 1985
  • In oder to compare and measure bond strength of ceramometal system with use of ceramco porcelain powder including SnO2 and uni metal, Rexillium III, Vera Bond as non precious alloys manufactured for porecelain-metal restorations. Total 24 test sample were constructed. All Test sample were measured with a Mitutoyo micrometer graduated to 0.01mm. It is as follows measured of thickness 3.3mm(metal : 1.1mm, porcelain: 2.2mm), width 12mm, length 30mm(porcelain 12mm x 12mm), Compared maximum bending stress test. The results obtained were as follows: 1. Bond strength of each metal with ceramco porcelain powder showed statistical significance.(P<0.05) 2. Vera Bond and uni metal, uni metal and Rexillium III revealed no statistical Significance.(P>0.05) Vera Bond and Rexillium III showed statistical significance.(P<0.05) 3. The order of maximum bending stress was Rexillium III, uni metal, vera Bond. The order of bond strength ratio making bending stress was Vera bond, uni metal, Rexillium III.

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비귀금속 합금에 적용한 Au Based Bonding Agent가 금속-도재 결합에 미치는 영향 (The Effect of a Au Based Bonding Agent Coating on Non-Precious Metals-Ceramic Bond Strength)

  • 이정환;안재석
    • 치위생과학회지
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    • 제9권4호
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    • pp.405-412
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    • 2009
  • 본 연구는 도재소부용 비귀금속에 Au 코팅 층을 형성하고, Au 코팅 층이 금속-도재의 결합력에 미치는 영향을 알아보고자 2출 굴곡 시험 후에 SEM/EDS 방법으로 조사하여 비교하였다. 1. Ni-Cr ally 군과 Co-Cr alloy 군, 그리고 Ti 군의 절단면 시편의 전자현미경 사진에서 Au 코팅 층은 산화층의 확산을 제어하는 것으로 관찰되었다. 2. 2축 굴곡 시험 후에 EDS 분석 결과 Ni-Cr alloy 군과 Co-Cr alloy 군에서 Si 함량은 Au 코팅 층을 형성한 시편에서 약간 감소하였고, 결합실패의 형태는 cohesive failure와 adhesive failure가 혼재된 양상으로 관찰되었다. 3. Ni-Cr alloy 군과 Co-Cr alloy 군에서 Au 코팅 층은 도재-금속 결합력에 미치는 영향은 미미하였다. 4. Ti 군의 결합실패 형태는 Ni-Cr alloy 군과 Co-Cr alloy 군에 비해서 adhesive failure 양상이 두드러지게 관찰되었고, Au 코팅 층은 도재-금속 결합력에 영향을 미치지 않았다. 이상의 결과 비귀금속에 적용한 Au 코팅은 산화층의 확산을 제어 하는 것으로 관찰 되었으나, 금속-도재 간의 결합력 증징에 미치는 효과는 미미하였다. Au 코팅을 이용하여 금속-도재 간의 결합력 증진을 위해서는 많은 연구가 지속되어야 할 것으로 사료된다.

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캄보디아 빠일링지역의 보석광상의 성인에 대한 예비연구 (The Preliminary Study for Genetic Environment of the Gem fields in the Pailling Area, Cambodia)

  • 김인준
    • 자원환경지질
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    • 제36권4호
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    • pp.269-274
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    • 2003
  • 금번 연구는 환태평양 귀금속 광화대 중 국내기업이 이미 진출한 나라를 대상으로 하였고, 캄보디아 빠일링 지역에 분포하는 보석광상에 대하여 조사를 수행하였다. 빠일링 보석광상은 현무암이 풍화된 라테라이트에 형성되어 있으며 표토 가까운 곳(깊이 1m 정도)에서는 주로 저품위의 강옥이, 이보다 깊은 곳에서는 고품위의 강옥이 산출된다. 또한, 풍화토의 색깔이 적색인 경우에는 루비, 청색의 경우에는 사파이어가 많이 산출되며, 일반적으로 적색토가 청색토의 상위에 놓인다. 보석류의 산출 및 성인은 풍화토와는 관계가 없으며, 적어도 화산암 상부에 원래 만들어져 있던 이들 보석류가 암석이 풍화를 받으면서 다량으로 산출되는 것이다. 이들 보석류는 화산암의 분출 시 또는 분출 후에 층의 상부 내지는 다른 화산암의 분출로 인해 두 층간 사이에서, 고온의 상태 하에서 보석이 만들어진다고 사료되며, 보석을 함유하는 화산암은 보석을 함유하지 않는 화산암과는 분출시 조금 달랐을 것으로 사료되나, 암석의 화학성분은 다른 지역에서 산출되는 화산암과 별다른 차이가 없다.