• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.472-477
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• 2001

Spent catalysts containing platinum were generated in petroleum refinery and other chemical industries. The reclamation of precious metals from such wastes has long been attempted in view of their rare, expensive and indispensable nature. In this study, the recovery of platinum from petroleum catalysts was attempted by a method consisting mainly of dissolving alumina substrate with sulfuric acid thereby concentrating insoluble platinum. Also, platinum dissolved partially in sulfuric acid was recovered by a cementation method using aluminum metal as a reductive agent. The effect of temperature, time, concentration of sulfuric acid. and pulp density on the dissolution of substrate was investigated. When the substrate of platinum catalyst was ${\gamma}$-AI$_2$O$_3$ about 95% alumina was dissolved in 6.0M sulfuric acid at 10$0^{\circ}C$ for 2 hours. When the substrate was the mixture of ${\gamma}$-A1$_2$O$_3$and $\alpha$-A1$_2$O$_3$about 92% was dissolved after 4 hours. As a result, more than 99% of platinum could be recovered by this method and aluminum sulfate was obtained as byproduct.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.579-587
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• 2003

A lot of VOCs that is noxious ate exhausted at drying process of enamel coating device. This VOC gas can be incinerated perfectly through catalytic combustion, and heat that is occurred in incineration process ran be again used in drying process. By using VU catalytic combustion technology, in this study, we developed a enamel coating machine that have an excellent environment improvement and energy saying effect. As basic research for this development characteristics ana performance of catalytic combustion for VOC gas was evaluated and numerical analysis for drying oven was calculated. According to the result, VOCs combustion characteristics of metal form catalysis was excellent in high temperature, and it was seen that enamel coating machine should be designed as a precious controllable structure of recirculating supply rate and suction rate.

• Journal of Power System Engineering
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• v.17 no.5
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• pp.13-22
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• 2013

This paper reports the investigation of the physical and chemical characteristics of the prepared 3Pt-2MgO-$3ZrO_2$-$2CeO_2/Al_2O_3$ DOC, based on its hydrothermal aging. As a result of impregnating and reducing the $H_2PtCl_6$ $6H_2O$ precursor on a ${\gamma}-Al_2O_3$ basis, it was well dispersed into small particles with the range 2-3nm. This was because the $Al_2O_3$ acted as a barrier to prevent movement of the catalyst particles. For a hydrothermally aged catalyst for 9h at $700^{\circ}C$, its performance when purifying harmful gases decreased compared to a fresh catalyst, but its specific surface area was at the same level. This was because the performance of the catalyst was reduced by the sintering of the precious metal Pt, rather than by washcoat sintering and pore clogging. For an excessively hydrothermally aged catalyst for 9h at $850^{\circ}C$, Pt grew into an approximately 50nm class, formed a cluster compared to a fresh catalyst. The $CeO_2$ promoters also formed clusters among components of the same type, reducing their specific surface area to $114m^2/g$, which was 14% less than a fresh catalyst.

• Journal of the Korean institute of surface engineering
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• v.41 no.3
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• pp.114-120
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• 2008

The pyrolysized carbon xerogel and aerogels were prepared from the sol-gel polymerization of resorcinol-formaldehyde(RF) followed by the dry process under ambient pressure and supercritical carbon dioxide condition respectively. The thermal behaviour of RF polymer xerogel was investigated with TGA analyzer to correspond with the pyrolysis process. The surface properties such as particle size, morphology and the point of zero charge of the pyrolysized porous carbon aerogels were studied for the precious metal catalyst supported media. It was found that the volume of the polymer aerogel decreased because of the significant linear shrinkage and weight loss of polymer gel during the carbonization. The point of zero charge of the carbon aerogel pyrolysized at $1050^{\circ}C$ under inert gas flow was about 10.

• Journal of the Korean institute of surface engineering
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• v.40 no.4
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• pp.197-202
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• 2007

Fit of the restoration and its cementation procedure is crucial to both its short and long term prognosis. Marginal fit is affected by many variables during the fabrication process. These variables, being intrinsic properties of the materials or the clinical technique used, can cause changes in the size and shape of the definitive restoration. Even if all variables are controlled carefully, the seating of a restoration can still be affected due to insufficient space for the luting agent. The use of die spacer can reduce the elevation of a cast restoration of a prepared tooth, decreased seating time, improve the outflow of excess cement, and lower the seating forces. The purpose of this study was to evaluate the marginal fidelity according to die spacer application times and measurement site. Casting alloys were prepared and fabricated using non-precious metal at $950^{\circ}C$. Specimens are divided into four groups: I(die spacer painted casting for wax pattern), II(die spacer non painted casting for wax pattern). The specimens were cut and polished for marginal gap observation. The marginal gap was observed using scanning electron microscopy (SEM).

• Korea Trade Review
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• v.47 no.3
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• pp.211-232
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• 2022

Due to the impact of the public health event COVID-19 epidemic, the Chinese futures market showed "Black Swan". This has brought the unpredictable into the economic environment with many commodities falling by the daily limit, while gold performed well and closed in the sunshine(Yan-Li and Rui Qian-Wang, 2020). Volatility is integral part of financial market. As an emerging market and a special precious metal, it is important to forecast return of gold futures price. This study selected data of the SHFE gold futures returns and conducted an empirical analysis based on the generalised autoregressive conditional heteroskedasticity (GARCH)-type model. Comparing the statistics of AIC, SC and H-QC, ARMA (12,9) model was selected as the best model. But serial correlation in the squared returns suggests conditional heteroskedasticity. Next part we established the autoregressive moving average ARMA-GARCH-type model to analysis whether Volatility Clustering and the leverage effect exist in the Chinese gold futures market. we consider three different distributions of innovation to explain fat-tailed features of financial returns. Additionally, the error degree and prediction results of different models were evaluated in terms of mean squared error (MSE), mean absolute error (MAE), Theil inequality coefficient(TIC) and root mean-squared error (RMSE). The results show that the ARMA(12,9)-TGARCH(2,2) model under Student's t-distribution outperforms other models when predicting the Chinese gold futures return series.

• Journal of the Korean institute of surface engineering
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• v.56 no.6
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• pp.427-436
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• 2023

In the industry, it is recognized that human activities significantly lead to a large amount of wastewater, mainly due to the increased use of water and energy. As a result, the growing field of wastewater resource technology is getting more attention. The common technology for hydrogen production, water electrolysis, requires purified water, leading to the need for desalination and reprocessing. However, producing hydrogen directly from wastewater could be a more cost-effective option compared to traditional methods. To achieve this, a series of first-principle computational simulations were conducted to assess how waste nutrient ions affect standard electrolysis catalysts. This study focused on understanding the adsorption mechanisms of byproducts related to the oxygen evolution reaction (OER) in anion exchange membrane (AEM) electrolysis, using Co₃O₄ as a typical non-precious metal catalyst. At the same time, efforts were made to develop a comprehensive free energy prediction model for more accurate predictions of OER results.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.7
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• pp.3261-3266
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• 2012

Sodium borohydride($NaBH_4$) known as the material of hydrogen generation and storage can produce the hydrogen via catalytic hydrolysis. This protide chemical could be used in the hydrogen supply system for residential and mobile fuel cells, and thus many researches and developments regarding to these chemicals and decomposition reactions have been implemented. We experimented the hydrolysis of $NaBH_4$ alkaline solution by metal oxide-supported PGM(platinum group metal) catalysts and measured the generation rate of hydrogen which is product of decomposition reaction. We compared oxides as catalyst supports, and the precious metals, Pt and Ru for the catalysts and studied the effects of amounts of catalyst added and $NaBH_4$ concentrations on the hydrogen generation rates and patterns.

• Journal of Technologic Dentistry
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• v.14 no.1
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• pp.55-65
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• 1992

The purpose of this study was to investigate the comparison of physical properties of nonprecious metal alloys colored goldish yellow. The experimental groups were copper based dental alloy and control group was Ni-Cr based dental alloy used crown and bridges frameworks. Hardness was tested by vickers hardness tester, tensile strength was tested by universal tension tester. After testing the tensile strength of castings, the microstrucure and the pattern of fracture were investigated by scanning electron microscope and metallurgical microscope. The results were as follows : Hardness of Ni based alloy was higher than Cu based alloys. Hardness number of A group was 200.41$\pm$16.10 Hv, B group was 194.33$\pm$1.69 Hv, C group was 139.29$\pm$2.19 Hv and D group was 293.81$\pm$27.17 Hv, respectively. Tensile strength of D group was 56.42$\pm$6.17 $kg/m^2$, A group was 50.39$\pm$5.68 $kg/m^2$, C group was 45.13$\pm$4.53 $kg/m^2$, B group was 45.25$\pm$9.25 $kg/m^2$, in order, and D group was maximum tensile strength. The fractured surfaces of tensile specimens in the all groups showed the tendency to form large voids in the center of specimens. Thus the ductile fracture was changed into the brittle fracture with the fine grain size.

• Journal of the Korean Home Economics Association
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• v.31 no.4
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• pp.215-229
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• 1993

As a result of making an inquiry into the ethnic look of each region appearing in present-day fashion by Asia. America and Oceania. Africa and Europe as mentioned above, its characteristics could be summarized as follows: Firstly the Asian ethnic look consists of Indian, Chinese and Japanese looks as mainstream. In terms of form, the draped form constituted its mainstream, and both the draped form and the tunic form are appearing Simultaneously in the Chinese look. And in respect to color the Indian look is using luxurious primary colors red, blue, yellow and green and other regions are making overall use of natural colors. With respect to ornament various kinds of ornaments is utilized in Indian's Sari and turban. Chines's Coolie hat, straw hat and embroidery, knotted button, and bead ornament, and Japan's Obi and Obijime, etc. Secondly in America and Oceania, costurme representing the Indian look in North America and the picture of Western pioneer, and the Peruvian, Mexican and chilean ethnic looks in South America were expressing much. Here, the form consistied a draped form as its main strem, such colors as yellow, purple, grey, etc were much utilized, and the material of costume comprised knits, cotton and the like. And the ornament consisted of hats, tassel ornaments, bead ornaments, metal chain belt, long braided hair, etc. Thirdly, the African ethnic look had an exposing form and a draped form, and such colors as black, white, yellow, brown, etc were used as the fashion color. Ornaments such as precious stone, bead ornaments, animal bones, straw metal ornament, etc were used as fashion decorations. Fourthly, Russia's Cossack look, Bulgaria's Bavshika look, spain's ethnic look cane to the fore as the European look Both the draped form and the tunic form were used simultaneously as fashion form. And grey, brown, purple, etc were much used as fashion color in the European look. Such ornaments as Cossack. Bavshka, boots, tassel ornaments were much used and paisley pattern also was used.