• Journal of the Korean Applied Science and Technology
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• v.37 no.4
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• pp.778-785
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• 2020

The purpose of this study was to investigate in vitro antibacterial activities of pozzolan against super bacteria and intestinal bacteria. There were four treatment groups: 1) CON, pozzolan free control group; 2) DP0.3, microbial culture medium prepared by mixing distilled water and 0.3% of pozzolan powder; 3) DP0.5, microbial culture medium prepared by mixing distilled water and 0.5% of pozzolan powder; and 4) PE, microbial culture medium prepared with pozzolan powder extracts without adding distilled water. The count of Lacctobacillus casei was significantly higher in the DP0.3 group compared to CON (P<0.05). However, it showed no significant difference compared to other treatment groups. Numbers of Clostridium butyricum, Escherichia coli, and Salmonella typhimurium were significantly lower in pozzolanic treatment groups compared to CON (P<0.05). Clostridium butyricum and Salmonella typhimurium counts were significantly different among DP0.3, DP0.5, and PE groups (P<0.05). Counts of E. coli were also significantly between DP0.5 and PE groups (P<0.05). Counts of MRSA and VRE were significantly lower in pozzolanic treatment groups compared to CON (P<0.05). MRSA counts were significantly different among DP0.5, DP0.3 and PE groups. VRE counts were significantly higher in the order of PE > DP0.3> DP0.5> CON (P<0.05). These results suggest that pozzolan could be used as a dietary silicate supplement and a natural antibacterial agent for livestock if its antimicrobial activity against super bacteria and harmful bacteria in the intestine is confirmed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.43-44
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• 2016

Large amount of dredged sea soil is produced in southeast seashore region in during harbor maintenance. Disposal of dredged sea soil has become difficult due to the environmental regulation. Therefore, disposal of dredged sea soil method is to landfill. But, the capacity of the landfill limit state and if the size of the dredged sea soil is in the range of silt or clay, it cannot be used as reclamation material because ground subsidence occur. In this study, analyzed the pozzolanic activity of dredged sea soil. Analysis of the results showed a pozzolanic activity of dredged sea soil. In addition, incorporation of heat treated dredged sea soil increase both 28 and 56 day compressive strength of mortar specimen.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.335-336
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• 2010

This paper presents experimentally investigated the effects of pozzolan made from various by-Product materials on mechanical properties of mortar. Fly ash(FA), slag (BFS), and palm oil fuel ash (POFA) were partially used to replace Portland cement. The results suggest that mortars containing FA, BFS, and POFA can be used as pozzolanic materials in making concrete with 28day compressive strength. After curing, the mortar containing 10-30% FA or POFA, and 30% BFS exhibited compressive strengths that of the original Portland cement (OPC). The use of FA, POFA, and BFS to partially replace Portland cement has evaluation method of the Assessed Pozzolan-activity index.(API)

• International Journal of Concrete Structures and Materials
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• v.8 no.3
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• pp.259-268
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• 2014

This paper presents results of an experimental study which investigates the effect of industrial pozzolan made from calcined silt of dam at $750^{\circ}C$ for 5 h, on mechanical properties and durability of ordinary mortar, compared to the silica fume. Mortar specimens prepared with 5, 10 and 15 % of calcined silt to substitute cement were evaluated for their compressive and flexural strength, sulfate, acid and penetration of chloride ions resistance. The results were compared with ordinary mortar (without addition) and mortar containing 10 % of silica fume. The results obtained showed that the calcined silt of dam has a high potential to be used as a pozzolanic material, it improves the strength and the durability of mortar and compete the silica fume.

• Advances in concrete construction
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• v.3 no.1
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• pp.71-90
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• 2015

In order to investigate the feasibility and advantage of tuff used as pozzolan in cement-based composite, the representative specimens of tuff were collected, and their chemical compositions, proportion of vitreous phase, mineral species, and rock structure were measured by chemical composition analysis, petrographic analysis, and XRD. Pozzolanic activity strength index of tuff was tested by the ratio of the compression strength of the tuff/cement mortar to that of a control cement mortar. Pozzolanic reaction degree, and the contents of CH and bond water in the tuff/cement paste were determined by selective hydrochloric acid dissolution, and DSC-TG, respectively. The tuffs were demonstrated to be qualified supplementary binding material in cement-based composite according to relevant standards. The tuffs possessed abundant $SiO_2+Al_2O_3$ on chemical composition and plentiful content of amorphous phase on rock texture. The pozzolanic reaction degrees of the tuffs in the tuff/cement pastes were gradually increased with prolongation of curing time. The consistency of CH consumption and pozzolanic reaction degree was revealed. Variation of the pozzolanic reaction degree was enhanced with the bond water content and relationship between them appeared to satisfy an approximating linear law. The fitting linear regression equation can be applied to mutual conversion between pozzolanic reaction degree and bond water content.

• Journal of the Korean Ceramic Society
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• v.53 no.1
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• pp.116-121
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• 2016

The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.75-80
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• 2015

The carbon dioxide($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical method to reducing $CO_2$ for building materials is the addition of slag and fly ash, like pozzolan material, while another method is reducing $CO_2$ production by carbon negative cement development. The MgO-based cement was from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements could improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as main starting materials, as well as silica fume, fly ash and blast furnace slag for the mineral admixture, were carried out for industrial waste material recycling. In order to increase the hydration activity, $MgCl_2$ was also added. To improve hydration activity, $MgCO_3$ and serpentinite were fired at $700^{\circ}C$ and autoclave treatment was conducted. In the case of $MgCO_3$ as starting material, hydration activity was the highest at firing temperature of $700^{\circ}C$. This $MgCO_3$ was completely transferred to MgO after firing. This occurred after the hydration reaction with water MgO was transferred completely to $Mg(OH)_2$ as a hydration product. In the case of using only $MgCO_3$, the compressive strength was 3.5MPa at 28 days. The addition of silica fume enhanced compressive strength to 5.5 MPa. In the composition of $MgCO_3$-serpentine, the addition of pozzolanic materials such as silica fume increased the compression strength. In particular, the addition of $MgCl_2$ compressive strength was increased to 80 MPa.

• Computers and Concrete
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• v.31 no.2
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• pp.85-95
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• 2023

Natural pozzolans are used as additives in cement to develop more durable and high-performance concrete. Pozzolanic activity index (PAI) is important for assessing the performance of a pozzolan as a binding material and has an important effect on the compressive strength, permeability, and chemical durability of concrete mixtures. However, the determining of the 28 days (short term) and 90 days (long term) PAI of concrete mixtures is a time-consuming process. In this study, to reduce extensive experimental work, it is aimed to predict the short term and long term PAIs as a function of the chemical compositions of various natural pozzolans. For this purpose, the chemical compositions of various natural pozzolans from Central Anatolia were determined with X-ray fluorescence spectroscopy. The mortar samples were prepared with the natural pozzolans and then, the short term and the long term PAIs were calculated based on compressive strength method. The effect of the natural pozzolans' chemical compositions on the short term and the long term PAIs were evaluated and the PAIs were predicted by using multiple linear regression (MLR) and adaptive neuro-fuzzy inference system (ANFIS) model. The prediction model results show that both reactive SiO₂ and SiO₂+Al₂O₃+Fe₂O₃ contents are the most effective parameters on PAI. According to the performance of prediction models determined with metrics such as root mean squared error (RMSE) and coefficient of correlation (R²), ANFIS models are more feasible than the multiple regression model in predicting the 28 days and 90 days pozzolanic activity. Estimation of PAIs based on the chemical component of natural pozzolana with high-performance prediction models is going to make an important contribution to material engineering applications in terms of selection of favorable natural pozzolana and saving time from tedious test processes.

• Korean Journal of Materials Research
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• v.22 no.11
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• pp.598-603
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• 2012

MgO based cement for the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. Furthermore, adding reactive MgO to Portland-pozzolan cement can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, the basic research for magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as starting materials was carried out. In order to increase the hydration activity, $MgCO_3$ and serpentinite were fired at a temperature higher than $600^{\circ}C$. In the case of $MgCO_3$ as starting material, hydration activity was highest at $700^{\circ}C$ firing temperature; this $MgCO_3$ was completely transformed to MgO after firing. After the hydration reaction with water, MgO was totally transformed to $Mg(OH)_2$ as hydration product. In the case of using only $MgCO_3$, compressive strength was 35 $kgf/cm^2$ after 28 days. The addition of silica fume and $Mg(OH)_2$ led to an enhancements of the compressive strength to 55 $kgf/cm^2$ and 50 $kgf/cm^2$, respectively. Serpentine led to an up to 20% increase in the compressive strength; however, addition of this material beyond 20% led to a decrease of the compressive strength. When we added $MgCl_2$, the compressive strength tends to increase.

• Journal of the Korea Institute of Building Construction
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• v.11 no.4
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• pp.363-370
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• 2011

This study considerated reject ash, wastes of coal-fired power plants, to use mineral admixtures for cement. The pozzolan activity selected the fineness of the efficient reject ash through comparison and it compared to the fly ash that are widely used for concrete mixed material. Cement composites was prepared replacing of slag cement by fineness reject ash and fly ash, and properties of cement composites was tested by paste(setting time, fluidity, instrumental analysis) and mortar(compressive strength). Instrumental analysis results showed hydration reaction of fineness reject ash was not different from fly ash, but had more dense micro structures. Results of physical properties showed fineness reject ash shorten setting time, increased compressive strength compared by fly ash. Therefore using fineness reject ash with $6,000cm^2$/g to concrete mineral admixtures or cement composites was might be possible and could contribute to improve properties of concrete.