• Environmental Engineering Research
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• v.25 no.3
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• pp.374-383
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• 2020

Landfill gas (LFG) emissions from a given amount of landfill waste depend on the carbon flows in the waste. The objective of this study was to more accurately estimate the first-order decay parameters through methane (CH₄) and carbon flow balances based on the analysis of a full-scale landfill with long-term data and detailed field records on LFG and leachate. The carbon storage factor for the case-study landfill was 0.055 g-degradable organic carbon (DOC) stored per g-wet waste and the amounts of DOC lost with the leachate were less than 1.3%. The appropriate CH₄ generation rate constant (k) for bulk waste was 0.24 y-1. The the CH₄ generation potential (L0) values ranged 33.7-46.7 m3-CH₄ Mg-1, based on the fraction of DOC that can decompose (DOCf) value of 0.40. Results show that CH4 and carbon flow balance methods can be used to estimate model parameters appropriately and to predict long-term carbon emissions from landfills.

• Nuclear Engineering and Technology
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• v.49 no.6
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• pp.1259-1268
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• 2017

The alpha eigenvalue problem in multigroup neutron diffusion is studied with particular attention to the theoretical analysis of the model. Contrary to previous literature results, the existence of eigenvalue and eigenflux clustering is investigated here without the simplification of a unique fissile isotope or a single emission spectrum. A discussion about the negative decay constants of the neutron precursors concentrations as potential eigenvalues is provided. An in-hour equation is derived by a perturbation approach recurring to the steady state adjoint and direct eigenvalue problems of the effective multiplication factor and is used to suggest proper detection criteria of flux clustering. In spite of the prior work, the in-hour equation results give a necessary and sufficient condition for the existence of the eigenvalue-eigenvector pair. A simplified asymptotic analysis is used to predict bands of accumulation of eigenvalues close to the negative decay constants of the precursors concentrations. The resolution of the problem in one-dimensional heterogeneous problems shows numerical evidence of the predicted clustering occurrences and also confirms previous theoretical analysis and numerical results.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.3
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• pp.397-410
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• 2023

This study examined the efficacy of various chlorinating agents in partitioning light water reactor spent fuel, with the aim of optimizing the chlorination process. Through thermodynamic equilibrium calculations, we assessed the outcomes of employing MgCl₂, NH₄Cl, and Cl₂ as chlorinating agents. A comparison was drawn between using a single agent and a sequential approach involving all three agents (MgCl₂, NH₄Cl, and Cl₂). Following heat treatment, the utilization of MgCl₂ as the sole chlorinating agent resulted in a moderate separation. Specifically, this method yielded a solid separation with 96.9% mass retention, 31.7% radioactivity, and 44.2% decay heat, relative to the initial spent fuel. In contrast, the sequential application of the chlorinating agents following heat treatment led to a final solid separation characterized by 93.1% mass retention, 5.1% radioactivity, and 15.4% decay heat, relative to the original spent fuel. The findings underscore the potential effectiveness of a sequential chlorination strategy for partitioning spent fuel. This approach holds promise as a standalone technique or as a complementary process alongside other partitioning processes such as pyroprocessing. Overall, our findings contribute to the advancement of spent fuel management strategies.

• Nuclear Engineering and Technology
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• v.55 no.11
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• pp.4173-4180
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• 2023

The stability of engineered barriers in high-level radioactive waste disposal systems can be influenced by the decay heat generated by the waste. This study focuses on the thermal analysis of various canister designs to effectively lower the maximum temperature of the engineered barrier. A numerical model was developed and employed to investigate the heat dissipation potential of copper rings placed across the buffer. Various canister designs incorporating copper rings were presented, and numerical analysis was performed to identify the design with the most significant temperature reduction effect. The results confirmed that the temperature of the buffer material was effectively lowered with an increase in the number of copper rings penetrating the buffer. Parametric studies were also conducted to analyze the impact of technical gaps, copper thickness, and collar height on the temperature reduction. The numerical model revealed that the presence of gaps between the components of the engineered barrier significantly increased the buffer temperature. Furthermore, the reduction in buffer temperature varied depending on the location of the gap and collar. The methods proposed in this study for reducing the buffer temperature hold promise for contributing to cost reduction in radioactive waste disposal.

• Journal of Ocean Engineering and Technology
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• v.34 no.2
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• pp.66-76
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• 2020

A light buoy is equipped with lighting functions and navigation signs. Its shape and colors indicate the route to vessels sailing nearby in the daytime, with its lights providing this information at night. It also plays a role in notifying the presence of obstacles such as reefs and shallows. When a light buoy operates in the ocean, the visibility and angle of light from the lantern installed on the buoy changes, which may cause them to function improperly. Therefore, it is necessary for the buoy to have stable and minimal motions under given environmental conditions, mainly waves. In this study, motion analyses for a newly developed lightweight light-buoy in waves were performed to predict the motion performance and determine the effect of the developed appendages for improving the motion performance. First, free decay tests, including benchmark cases, were performed using computational fluid dynamics (CFD) to estimate the viscous damping coefficients, which could not be obtained using potential-based simulations. A comparison was made of the results from potential-based simulations with and without considering viscous damping coefficients, which were estimated using CFD. It was confirmed that the pitch and heave motions of the buoy became smaller when the developed appendages were adopted.

• Korean Journal of Environmental Agriculture
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• v.14 no.1
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• pp.7-14
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• 1995

This research was conducted to apply the QUAL2E model to be adopted to the Nam river under current water quality conditions. The survey area of total 60 Km was divided into five reaches. Each reach was then subdivided into the uniform computational elements of 1.5 Km. Based on the stream characteristics, nine sampling stations consisting of six at main streams and three at tributaries were selected. The field data were obtained from the selected stations twice during October of 1991 and May of 1992, which represented the cold weather and low flow, also the warm weather and low flow conditions, respectively. As the results of sensitivity analysis of the model, the important parameters were the rates of BOD decay, Org-N oxidation, $NH_3-N$ oxidation, Org-P decay. The calibrated and verified results by QUAL2E model were correlation coefficient of $0.45{\sim}0.94$. The results displayed a good agreement between the variables of the field measurements and the model simulations, indicating a potential use of the QUAL2E model for the water quality assessment in the Nam River.

• Applied Chemistry for Engineering
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• v.7 no.3
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• pp.473-480
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• 1996

Synthesis of n-perfluorooctanesulfonyl fluoride(n-PFOSF), which is valuable precursor perfluoro-chemicals, was studied by electrochemical fluorination(ECF). Of prime concern was to investigate the cyclic voltamograms of Ni electrode in anhydrous hydrogen fluoride(AHF) with and without the reactants and to measure fluorine evolution potential. In a batch cell, chronoampherometric electrolysis and various chemical analysis such as GC, GC/MS and IR were used to understand the amphere change of electrode and the reaction paths. Fluorine equilibrium potential was found to be about 2.8V(vs. $Cu/CuF_2$) from the cyclic voltammograms and decay curves of anode potential in AHF. In batch processes, the ECF proceeded in two distinguished steps. The first step proceeded electrochemically and the second one chemically. Under 7V(vs. $Cu/CuF_2$), amount of crude products was proportional to the applied anode potential. Above 7V(vs. $Cu/CuF_2$), it had a hundred percentage with weight ratio of reactants and productivity of PFOSF was almost constant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.20 no.12
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• pp.820-824
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• 2008

Electret filter media are used in general ventilation filters, disposable respirators, vehicle cabin filters, vacuum cleaners and room air cleaners. There are basic mechanisms of interception, inertial impaction, diffusion, gravitational settling, electrostatic attraction by which an aerosol particle can be deposited onto a fiber in a filter. The ability of fine particle removal strongly depends on the electrostatic forces between particles and polarized fibers. Thus, the stability of the fiber polarization is a major factor in the reliability of electret filters. In this study, the electret filter is made by electrospinning process using Polystyrene which is dissolved by 5 : 5 of Tetrahydrofuran (THF) and Dimethylformamide (DMF). Also the electrical properties and the filtration performances of electrospun filter media are Quantitatively investigated. Electrical properties of electrospun filters have been studied on surface charge potential and surface charge density. Also the filtration performance of the electret filters are evaluated on collection efficiency. The surface charge potential and the surface charge density of electrospun PS filters are increased with increasing applied voltage and saturated at 30 kV of applied voltage. Also collection efficiency of electro spun filters is increased with increasing surface charge potential and surface charge density. But the surface charge potential is decreased by natural decay and it causes deterioration of particle collection efficiency.

• International conference on construction engineering and project management
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• 2009.05a
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• pp.856-863
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• 2009

The problem of urban decay in Hong Kong has drawn much attention of both practitioners and academics. Poorly managed buildings not just give a negative image to the Pearl of the Orient in the region, but also pose potential risk hazards to the health and safety of the general public. While it is necessary to devise a comprehensive plan on redevelopment and urban planning, preserving the existing buildings to maintain their conditions for habitation can be a short-term option to safeguard quality standard. With the increasing number of ageing buildings in Hong Kong, a lot of research efforts have been devoted to managing repair and maintenance projects properly (for example those initiated and funded by the Construction Industry Institute, Hong Kong; and the current study financially supported by The Hong Kong Polytechnic University). Given the short duration and more diversified nature of work, building repair and maintenance works are found to be more difficult to monitor and regulate when compared with new works. This paper aims to provide a comprehensive analysis on the problems of running building maintenance projects. An extensive review of contemporary literature was firstly conducted, which forms a solid basis for developing an empirical study on the problems and difficulties of running building maintenance projects from the viewpoints of industrial practitioners with a view to formulating effective strategies for managing maintenance projects successfully.

• Nuclear Engineering and Technology
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• v.24 no.1
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• pp.86-97
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• 1992

The purpose of this paper is to evaluate the direct vessel injection design from a pressurized thermal shock(PTS) viewpoint for the Combustion Engineering System 80+ A break of the main steam line from zero power and a 0.05 ft$^2$small break loss-of-coolant accident (LOCA) from full power were selected as the potential PTS events. In order to investigate the stratification effects in the reactor downcomer region, the fluid mixing analysis was performed using the COMMIX-IB code for steam line break and using the REMIX code for 0.05 ft$^2$small break LOCA. The stress distributions within the reactor vessel walls experiencing the pressure and the temperature transients were calculated using the OCA-P code for both events. The results of the analysis showed that a small break LOCA without decay heat presented the greatest challenge to the vessel, however, there is no crack initiation through end-of-life of the vessel with consideration of decay heat.