• Title/Summary/Keyword: positive surface charge

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Behavior of Water Droplet on the Polymer Surface and Influence of the Charge

  • Zhu, Yong;Yamashita, Seiji;Anami, Naoya;Otsubo, Masahisa;Honda, Chikahisa;Takenouchi, Osamu;Hashimoto, Yousuke
    • KIEE International Transactions on Electrophysics and Applications
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    • v.3C no.3
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    • pp.81-85
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    • 2003
  • This paper describes the results of experiments made to examine the behavior of water droplet on the polymer surface and influence of the charge. In this experiment, water droplet was put on the polymer surface in an applied AC electric field and the investigations of its behavior were done with a high-speed video camera. It can be observed that the droplet elongates and vibrates with being pulled towards the positive electrode in a wave synchronism with the frequency of the power source. The volume and conductivity of water droplet are shown to have a marked effect on the mode of discharge development. These behaviors may be caused by the change of electric field of applied AC voltage and induced charges in/on the water droplet.

Removal of Dust in Positive and Negative Plates of Electrode Coated with Activated Carbon (활성탄으로 코팅된 전극에서 분진의 제거)

  • Kim, Kwang Soo;Park, Hyun Chul;Jun, Tae Hwan;Lee, Ju Haeng;Nam, Sang Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.830-837
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    • 2013
  • The purposes of this research are to know the dust removal efficiency according to the changes of gab between positive and negative plates in dust removal chamber. The experiments for dust removal efficiencies were conducted with changing the electrode-plate gab from 2 cm to 1 cm while the electric pressure, influent flow, and linear velocity were kept 5 kV, 80 L/min, and 6 cm/sec, respectively. From the experimental results of the electrode-plate gab of 2 cm, dust removal efficiencies were decreased to as low as about 50%. Attached dust on the surface of electrodes was released due to a reverse electric charge of dust. From the experimental results of the electrode-plate gab of 1 cm, dust removal efficiencies were increased to as high as about 80% due to the dust attachment velocity to the electrodes to be far more fast than influent linear velocity. Finally, to protect a attached dust from occurring a reverse electric charge it is needed to install the non-conductor between positive and negative electrodes and also to remove air humidity.

Properties of Poly(acrylic acid) Hydrogel by the Surface Charge of Magnetite Nanoparticles (나노 자철광의 표면전하에 따른 Poly(acrylic acid) 수화젤의 물성)

  • Seo Dong-Pil;Kang Hwi-Won;Jeong Chang-Nam
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.412-416
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    • 2006
  • The superparamagnetic nanoparticles were prepared by coprecipitation of $FeCl_3$ and $Na_2SO_3$ with $NH_4OH$ and the surface charge on hydroxyl group by chemisorption was changed depending on pH. We studied correlation between surface charge of magnetite and pH. Using this correlation the properties of poly (acrylic acid) (PAAc) hydrogel embedded with magnetite was studied. The magnetite was characterized by XRD, AFM. and FTIR. The zeta-potential of magnetite was influenced by pH: great positive charge was shown high under the pH 4 and isoelectric point was found at pH 7. The hydrogen bond formed by combining oi PAAc hydrogel and magnetic colloid under pH 4 caused tensile strength to increase, while swelling and elongation at break to decrease. The result confirmed that the magnetic moment was increased proportionally to the content of magnetite.

Polyelectrolyte Micropatterning Using Agarose Plane Stamp and a Substrate Having Microscale Features on Its Surface

  • Lee, Min-Jung;Lee, Nae-Yoon;Lee, Sang-Kil;Park, Sung-Su;Kim, Youn-Sang
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1539-1542
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    • 2005
  • We have introduced polyelectrolyte micro-patterning technique employing agarose plane stamp and a hard substrate having microscale features on its surface. With this method, chemically micropatterned surfaces with both positive and negative functionalities were successfully embedded in well-defined microstructures, and selective impartment of charge functionalities was confirmed by patterning bead bearing surface charge. Furthermore, this technique allows highly sensitive immobilization of protein onto targeted surface simply by endowing functionalities, which extends the potential of its use as a tool for high-throughput protein microarray and proteomics. Because plane agarose stamp is free of structures on its surface, there is no concern for pattern collapse, and the combination of agarose plane stamp with patterned substrate is more suited for selective protein patterning compared with adopting surface-patterned agarose stamp with flat substrate. Our technique using agarose plane stamp and a substrate having microscale features on its surface suggests a range of possible applications, including the micropatterning of biofunctionalized copolymer having polyelectrolyte block, immobilization of micro- and nanoparticle with biofunctionalities such as biotin and streptavidine, and establishing optoelectronic microstructures with micro-beads on various surfaces.

Development and Performance Evaluation of Positively Charged Porous Filter media for Water Purification System (정수 설비를 위한 양전하가 부가된 다공성 수처리 필터 개발과 성능평가)

  • Lee, Chang-Gun;Joo, Ho-Young;Lee, Jae-Keun;Ahn, Young-Chull;Park, Seong-En
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.95-98
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    • 2006
  • Filtration by fibrous filter is one of the Principle methods used for removing pollutant particles in the liquid. Because of the increasing need to protect both human health and valuable devices from exposure to fine particles, filtration has become more important. Filters have been developed with modified surface charge characteristics to capture and adsorb particles by electrokinetic interaction between the filter surface and particles contained in water. The main purposes of this study are to develop and evaluate the performance evaluation of the apparatus for making a positively charged porous filter media and to analyze the surface characteristics of the filter media for capturing negavitely charged contaminants mainly bacteria and virus from water. The experimental apparatus consists of a mixing tank, a vacuum pumping system, a injection nozzle, a roller press and a controller. The filter media is composed of glass fiber(50-750 nm), cellulose($10-20{\mu}m$) and colloidal charge modifier. The characteristics of filter media is analyzed by SEM(Scanning Electron Microscopy), AFM(Atomic Force Microscopy) and quantified by measuring the zeta potential values.

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A New Type of Nonthermal Plasma Reactor

  • Geum, Sang-Taek;Moon, Jae-Duk;Jun, Sun-Gon
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.245-249
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    • 1999
  • A new type of nonthermal plasma reactor utilizing ferroelectric pellets is proposed to generate nonthermal plasma efficiently, which is used for simultaneous control of various pollutant gases. Electric charges stored on ferroelctric pellets by corona discharge between a corona tip and a mesh electrode provide partial electrical discharges among ferroelectric pellets. These partial electrical discharges can enhance partial discharges around the surface of ferroelectric pellets. This method utilizes wide reacting area of ferroelectric pellets and partial discharge. Positive and negative dc voltage are applied to the corona tip to generate partial discharges, and corona currents are estimated to investigate charge storage on ferroelectric pellets as function of time and charge relaxation time constants of ferroelectric pellects. As a result, charge relaxationtime, dielectric constants of ferroelectric pellets, polarity of applied voltage and applied time influence partial discharges among ferroelectric pellect.

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Multilocus sequence type-dependent activity of human and animal cathelicidins against community-, hospital-, and livestock-associated methicillin-resistant Staphylococcus aureus isolates

  • Sun Do, Kim;Geun-Bae, Kim;Gi Yong, Lee;Soo-Jin, Yang
    • Journal of Animal Science and Technology
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    • v.64 no.3
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    • pp.515-530
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    • 2022
  • Sequence type (ST) 5 methicillin-resistant Staphylococcus aureus (MRSA) with staphylococcal cassette chromosome mec (SCCmec) type II (ST5-MRSA-II) and ST72-MRSA-IV represent the most significant genotypes for healthcare- (HA) and community-associated (CA) MRSA in Korea, respectively. In addition to the human-type MRSA strains, the prevalence of livestock-associated (LA) MRSA clonal lineages, such as ST541 and ST398 LA-MRSA-V in pigs and ST692 LA-MRSA-V and ST188 LA-MRSA-IV in chickens, has recently been found. In this study, clonotype-specific resistance profiles to cathelicidins derived from humans (LL-37), pigs (PMAP-36), and chickens (CATH-2) were examined using six different ST groups of MRSA strains: ST5 HA-MRSA-II, ST72 CA-MRSA-IV, ST398 LA-MRSA-V, ST541 LA-MRSA-V, ST188 LA-MRSA-IV, and ST692 LA-MRSA-V. Phenotypic characteristics often involved in cathelicidin resistance, such as net surface positive charge, carotenoid production, and hydrogen peroxide susceptibility were also determined in the MRSA strains. Human- and animal-type MRSA strains exhibited clonotype-specific resistance profiles to LL-37, PMAP-36, or CATH-2, indicating the potential role of cathelicidin resistance in the adaptation and colonization of human and animal hosts. The ST5 HA-MRSA isolates showed enhanced resistance to all three cathelicidins and hydrogen peroxide than ST72 CA-MRSA isolates by implementing increased surface positive charge and carotenoid production. In contrast, LA-MRSA strains employed mechanisms independent of surface charge regulation and carotenoid production for cathelicidin resistance. These results suggest that human- and livestock-derived MRSA strains use different strategies to counteract the bactericidal action of cathelicidins during the colonization of their respective host species.

The Preparation of Quaternary Ammonium Polysulfone and its Permeation Behavior (II) - The Permeation Characteristics of Quaternary Ammonium Polysulfone Membranes - (Quaternary Ammonium Polysulfone막의 제조 및 투과 특성(II) - Quaternary Ammonium Polysulfone막의 투과특성 -)

  • 현진호;전종영;탁태문
    • Membrane Journal
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    • v.6 no.2
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    • pp.79-85
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    • 1996
  • This study is undertaken to investigate the effect of positive charge on the premeation characteristics of quaternary ammonium polysulfone (AMPS) membrane. AMPS membrane having a hydrophilic property was less fouled than PSf membrane. AMPS membrane had a positive charge and was thought to be able to expel charged solutes, such as basic dyes, proteins and amino acids, having same sign as the membrane surface.

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Selective removal of cationic dye pollutants using coal ash-derived zeolite/zinc adsorbents

  • Chatchai Rodwihok;Mayulee Suwannakaew;Sang Woo Han;Siyu Chen;Duangmanee Wongratanaphisan;Han S. Kim
    • Membrane and Water Treatment
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    • v.14 no.3
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    • pp.121-128
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    • 2023
  • This study introduces a NaOH/Zn-assisted hydrothermal method for the synthesis of zeolites derived from coal ash (CA). A zeolite/Zn adsorbent is successfully prepared by the activation of CA with NaOH and Zn; it is characterized by a high surface area and a negative surface charge.Methylene blue (MB) and methyl orange (MO) are selected as dye pollutants, and their adsorption onto the zeolite/Zn adsorbent is investigated. Results show the high adsorption capacities of MB and MO and that the negative surface charge facilitates electrostatic interactions between the adsorbates and adsorbents. The zeolite/Zn adsorbents shows the selective adsorption of positively charged dye MB via electrostatic interactions between the =NH+ group (positive dipole) and the oxygen functional group of the adsorbents (negative dipole). The selectivity for the positively charged dye is sufficiently high, with the removal efficiency reaching 99.41% within 10 min. By contrast, the negatively charged dye MO exhibits negligible absorption. These findings confirm the role of electrostatic interactions in the adsorption of MB, in addition to the effect of a large surface area. The results of this study are expected to facilitate the development of simple, eco-friendly, and cost-effective zeolite-based adsorptive composites from CA residuals for the selective removal of dye pollutants from CA waste.

Newly Synthesized Silicon Quantum Dot-Polystyrene Nanocomposite Having Thermally Robust Positive Charge Trapping

  • Dung, Mai Xuan;Choi, Jin-Kyu;Jeong, Hyun-Dam
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.221-221
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    • 2013
  • Striving to replace the well known silicon nanocrystals embedded in oxides with solution-processable charge-trapping materials has been debated because of large scale and cost effective demands. Herein, a silicon quantum dot-polystyrene nanocomposite (SiQD-PS NC) was synthesized by postfunctionalization of hydrogen-terminated silicon quantum dots (H-SiQDs) with styrene using a thermally induced surface-initiated polymerization approach. The NC contains two miscible components: PS and SiQD@PS, which respectively are polystyrene and polystyrene chains-capped SiQDs. Spin-coated films of the nanocomposite on various substrate were thermally annealed at different temperatures and subsequently used to construct metal-insulator-semiconductor (MIS) devices and thin film field effect transistors (TFTs) having a structure p-$S^{++}$/$SiO_2$/NC/pentacene/Au source-drain. C-V curves obtained from the MIS devices exhibit a well-defined counterclockwise hysteresis with negative fat band shifts, which was stable over a wide range of curing temperature ($50{\sim}250^{\circ}C$. The positive charge trapping capability of the NC originates from the spherical potential well structure of the SiQD@PS component while the strong chemical bonding between SiQDs and polystyrene chains accounts for the thermal stability of the charge trapping property. The transfer curve of the transistor was controllably shifted to the negative direction by chaining applied gate voltage. Thereby, this newly synthesized and solution processable SiQD-PS nanocomposite is applicable as charge trapping materials for TFT based memory devices.

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