• Title/Summary/Keyword: porous polymer

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Study of Optimal Process Conditions of 3D Porous Polymer Printing for Personal Safety Products (개인안전 제품을 위한 3 차원 다공성 폴리머 프린팅의 최적화 공정조건에 대한 연구)

  • Yoo, Chan-Ju;Kim, Hyesu;Park, Jun-Han;Yun, Dan-Hee;Shin, Jong-Kuk;Shin, Bo-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.5
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    • pp.333-339
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    • 2016
  • In this paper, a fundamental experiment regarding the formation of porous 3D structures for personal safety products using 3D PPP (Porous Polymer Printing) was introduced for the first time. The filament was manufactured by mixing PP (Polypropylene) and CBA (Chemical Blowing Agent) with polymer extruder, and the diameter of the filament was approximately 1.75mm. The proposed 3D PPP method, combined with the conventional FDM (Fused Deposition Modeling) procedure, was influenced by process parameters, such as the nozzle temperature, printing speed and CBA density. In order to verify the best processing conditions, the depositing parameters were experimentally investigated for the porous polymer structure. These results provide parameters under which to form a multiple of 3D porous polymer structures, as well as various other 3D structures, and help to improve the mechanical shock absorption for personal safety products.

Studies on the Durable Properties of Porous Concrete for Permeable Pavement using Polymer (폴리머를 혼입한 투수성 포장용 콘크리트의 내구성능에 관한 실험적 연구)

  • Park Seong Bum;Seo Dae Seuk;Lee Byung Jae;Song Jae Lib;Son Sung Woo;Cho Kwang Yeon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.703-706
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    • 2005
  • This study is analyzed mechanical properties and durability of pavement of a road permeability porous concrete to mix polymer for the enhance of porous concrete of performance and durability. As a result, void ratio showed the tendency which the mixing rate of polymer is decreased a little as increased. And, the influence of void ratio according to the kind of polymer has the difference, but void ratio showed the tendency which the mixing rate of polymer is decreased a little as increased. Compressive strength showed the tendency which the mixing rate of polymer is increased a little as increased. but, it showed the tendency to be reduced rather when above $20\%$ it mixed polymer mixing rate $10\%$ at apex.

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An Optimization of the Porous Asphalt Pavement Permeability Function Focusing on the Surface Free Energy of Polymer Fog-Coat Methods

  • Ohmichi Massaru;Yamanokuchi Hiroshi;Maruyama Teruhiko
    • International Journal of Highway Engineering
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    • v.8 no.2 s.28
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    • pp.13-22
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    • 2006
  • Surface fog coating methods to porous pavements with a polymer, that contains MMA as a main ingredient, are being widely used in Japan and called 'Top-Coat Processes'. They have lots of effects such as to prevention of the pavement void choking, improvement of the water permeability of the pavements and so on. The purpose of this research is to show the characterization of the polymer to optimize the functions of the polymer fog-coat methods. This study focused on the difference of 'wetting' by water among polymers used for the fog coatings, and calculation the surface free energy from the water contact angle on each material. At the end, the water permeability test were conducted using porous asphalt mixtures that were coated with several kinds of polymers. The permeability was also measured on the specimens that were forcibly choked by muddy water and the resistance to choking was compared. It is concluded that the reduction of the surface free energy between water and a polymer improves the life of the permeability functions of porous pavements. Improvement of water permeation capacity and void-blocking controlling effects can be quantitatively evaluated using the interfacial tension ($\gamma$sl) with water for the coating material (high-viscosity asphalt and hardening resin binder). Consequently, the smaller the $\gamma$sl of the coating material the higher the water permeation capacity and void-blocking controlling effects of the porous asphalt pavements.

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Fabrication of Nitrogen Self-Doped Porous Carbons from Melamine Foam for Supercapacitors (슈퍼커패시터용 멜라민 폼으로부터 질소가 자가 도핑된 다공성 탄소 재료의 제조)

  • Lee, Byoung-Min;Chang, Hyeong-Seok;Choi, Jae-Hak;Hong, Sung-Kwon
    • Korean Journal of Materials Research
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    • v.31 no.5
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    • pp.264-271
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    • 2021
  • Porous carbons have been widely used as electrode material for supercapacitors. However, commercial porous carbons, such as activated carbons, have low electrochemical performance. Nitrogen-doping is one of the most promising strategies to improve electrochemical performance of porous carbons. In this study, nitrogen self-doped porous carbon (NPC) is prepared from melamine foam by carbonization to improve the supercapacitive performance. The prepared NPC is characterized in terms of the chemical structures and elements, morphology, pore structures, and electrochemical performance. The results of the N2 physisorption measurement, X-ray diffraction, and Raman analyses reveal that the prepared NPC has bimodal pore structures and pseudo-graphite structures with nitrogen functionality. The NPC-based electrode exhibits a gravimetric capacitance of 153 F g-1 at 1 A g-1, a rate capability of 73.2 % at 10 A g-1, and an outstanding cycling ability of 97.85 % after 10,000 cycles at 10 A g-1. Thus, the NPC prepared in this study can be applied as electrode material for high-performance supercapacitors.

Preparation of porous polymers by environmentally friend process in supercritical carbon dioxide (초임계 이산화탄소를 이용하는 친환경 공정에 의한 다공성 고분자의 제조)

  • 강세란;홍성수;이민규;이석희;천재기;주창식
    • Journal of Environmental Science International
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    • v.13 no.3
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    • pp.319-325
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    • 2004
  • An experimental study on the preparation of monolithic porous polymers by environmentally friend process in supercritical carbon dioxide has been carried out. Polymerization mixture composed of a cross-linking monomer, initiator and functional co-polymer was charged in the reactor with sapphire window. After the system was purged with a flow of $CO_2$ for 15 min, the reactor was pressurized with liquid $CO_2$ up to 100 bars. The reactor was isolated from and placed back to the system via quick connector for shaking until the mixture had become fully homogeneous. The reactor was then heated and pressurized to the required reaction conditions and left overnight. After cooling and $CO_2$ evacuation, the polymer was removed from the reactor as dry, white, continuous monoliths. The effect of experimental conditions on the physical properties of porous polymer was systematically examined, and it was found that monomer content had a major effect on the physical properties of the polymers.

Mold technology with 3D printing for manufacturing of porous implant (다공성 임플란트 제조를 위한 3D 프린팅 응용 금형기술)

  • Lee, Sung-Hee;Kim, Mi-Ae;Yun, Eon-Gyeong;Lee, Won-Sik
    • Design & Manufacturing
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    • v.11 no.1
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    • pp.30-33
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    • 2017
  • In this study, the mold technology for manufacturing of porous implant was investigated. Firstly, we considered the concept of insert molding technology with 3D printing of porous inert part. The part on implant was designed in the end region of the implant. And then main implant bodies were manufactured using conventional machining method. The other porous parts were designed and optimized with molding simulation. As the feature size of porous implant was so small that perfect feature of it using 3D printing technology could not be obtained. So, we proposed another scheme for manufacturing of the porous implant in the replace of the former approach. Polymer mold cores with 3D printing technology were considered. The effects of addictive manufacturing process parameters on the properties of mechanical and dimensional accuracy were investigated. Direct 3D printed polymer mold cores were designed and manufactured under the simulation of thermal and molding analysis. It was shown that 3D printed mold core with polymer could be adapted to the injection molding for porous implant.

In-Situ Formation of Porous HAp Using Polymer Foam Process (폴리머 발포법을 이용한 다공성 HAp 지지체의 제조 및 특성 평가)

  • Kim, Zin-Kook;Ji, Sang-Yong;Ji, Hyung-Bin;Park, Hong-Chae;Yoon, Seog-Young
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.289-293
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    • 2008
  • Porous HAp with three-dimensional network channels was prepared in a polymer foam process using a in-situ formation. HAp/polyol with various HAp solid contents was formed with an addition of isocyanate. Under all conditions, the obtained porous HAp had pore sizes ranging $50\;{\mu}m$ to $250\;{\mu}m$. The influence of the HAp content on the physical and mechanical properties of porous HAp scaffolds was investigated. As the solid content increased, the porosity of the porous HAp decreased from 79.3% to 77.9%. On the other hand, the compressive strength of the porous HAp increased from 0.7 MPa to 3.7 MPa. With a HAp solid content of 15 g, the obtained porous HAp had physical properties that were more suitable for scaffolds compared to other conditions.

Fundamental Study on the Development of Porous Concrete Using Super Absorbent Polymer (고흡수성 수지를 활용한 다공질 구조 콘크리트 개발을 위한 기초적 연구)

  • Jo, Jae-Hyun;Baek, Sung-Jin;Lim, Gun-Su;Han, Jun-Hiu;Kim, Jong;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.217-218
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    • 2023
  • This study is to develop porous concrete using super absorbent polymer, which possesses insolubility and high absorption capacity, as a substitute material for lightweight soil. Various mixtures were prepared using aggregates, cement, mixing water, and super absorbent polymer, and the absorption ratio and compressive strength were examined for each mixture. As the amount of super absorbent polymer added increased, the absorption ratio also increased, reaching up to 35-105%. However, the compressive strength decreased by 49.5% to 65.3%. This is believed to be due to the inherent properties of super absorbent polymer, which led to an increase in the absorption ratio but, in turn, reduced the binding strength of cement paste particles, resulting in a decrease in compressive strength.

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An Experimental Study on the Physical Properties of Porous Cement Concrete Using Polymer as an Admixture (폴리머를 혼화재로 혼입한 투수콘크리트의 물리적 특성에 관한 실험적 연구)

  • 채창우;민병렬;심종우
    • Journal of the Korea Concrete Institute
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    • v.12 no.5
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    • pp.131-139
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    • 2000
  • Porous Concrete usually contains large amount of voids(about 10∼20%) after compaction so that it has relatively high permeability. It has been introduced in domestic since early 1980's but it has problems such as lack of optimized mixture, low strength and durability, and other defects, etc. The purpose of this study is to manufacture high-performance porous concrete using polymer to enhance the mechanical properties. The results of this study are as follows; the compressive strength range 12 92∼207kgf/㎠, the tensile strength range is 14∼28kgf/㎠, the bending stength range is 42∼73kgf/㎠, and the coefficient permeability range is 5.77×10-2∼6.79×10-1cm/sec. To develope high-performance porous concrete. further studies are needed on optimum mixture of fineness modulus and admixture.