• Steel and Composite Structures
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• 제49권3호
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• pp.349-359
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• 2023

Dynamic response and economic of a laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the sinusoidal shear deformation theory (SSDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.

• Steel and Composite Structures
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• 제36권1호
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• pp.47-62
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• 2020

In this study, free vibration behavior of trapezoidal sandwich plates with porous core and two graphene platelets (GPLs) reinforced nanocomposite outer layers are presented. The distribution of pores and GPLs are supposed to be functionally graded (FG) along the thickness of core and nanocomposite layers, respectively. The effective Young's modulus of the GPL-reinforced (GPLR) nanocomposite layers is determined using the modified Halpin-Tsai micromechanics model, while the Poisson's ratio and density are computed by the rule of mixtures. The FSDT plate theory is utilized to establish governing partial differential equations and boundary conditions (B.C.s) for trapezoidal plate. The governing equations together with related B.C.s are discretized using a mapping- generalized differential quadrature (GDQ) method in the spatial domain. Then natural frequencies of the trapezoidal sandwich plates are obtained by GDQ method. Validity of current study is evaluated by comparing its numerical results with those available in the literature. A special attention is drawn to the role of GPLs weight fraction, GPLs patterns of two faces through the thickness, porosity coefficient and distribution of porosity on natural frequencies characteristics. New results show the importance of this permeates on vibrational characteristics of porous/GPLR nanocomposite plates. Finally, the influences of B.C.s and dimension as well as the plate geometry such as face to core thickness ratio on the vibration behaviors of the trapezoidal plates are discussed.

• Steel and Composite Structures
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• 제39권3호
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• pp.275-290
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• 2021

The main purpose of this research work is to investigate the critical buckling load of functionally graded (FG) porous plates with graphene platelets (GPLs) reinforcement using generalized differential quadrature (GDQ) method at thermal condition. It is supposed that the GPL nanofillers and the porosity coefficient vary continuously along the plate thickness direction. Generally, the thermal distribution is considered to be nonlinear and the temperature changing continuously through the thickness of the nanocomposite plates according to the power-law distribution. To model closed cell FG porous material reinforced with GPLs, Halpin-Tsai micromechanical modeling in conjunction with Gaussian-Random field scheme are used, through which mechanical properties of the structures can be extracted. Based on the third order shear deformation theory (TSDT) and the Hamilton's principle, the equations of motion are established and solved for various boundary conditions (B.Cs). The fast rate of convergence and accuracy of the method are investigated through the different solved examples and validity of the present study is evaluated by comparing its numerical results with those available in the literature. A special attention is drawn to the role of GPLs weight fraction, GPLs patterns through the thickness, porosity coefficient and distribution of porosity on critical buckling load. Results reveal that the importance of thermal condition on of the critical load of FGP-GPL reinforced nanocomposite plates.

• Advances in environmental research
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• 제4권2호
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• pp.69-81
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• 2015

A new magnetite-silica core/shell nanocomposite ($Fe_3O4@nSiO_2@mSiO_2$) was synthesized and functionalized with trimethylchlorosilane (TMCS). The prepared nanocomposite was used for the removal of diesel oil from aqueous media. The characterization of magnetite-silica nanocomposite was studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR), transmission electron microscopy (TEM), surface area measurement, and vibrating sample magnetization (VSM). Results have shown that the desired structure was obtained and surface modification was successfully carried out. FTIR analysis has confirmed the presence of TMCS on the surface of magnetite silica nanocomposites. The low- angle XRD pattern of nanocomposites indicated the mesoscopic structure of silica shell. Furthermore, TEM results have shown the core/shell structure with porous silica shell. Adsorption kinetic studies indicated that the nanocomposite was able to remove 80% of the oil contaminant during 2 h and fit well with the pseudo-second order model. Equilibrium studies at room temperature showed that the experimental data fitted well with Freundlich isotherm. The magnetic property of nanocomposite facilitated the separation of solid phase from aqueous solution.

• Steel and Composite Structures
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• 제45권3호
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• pp.409-423
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• 2022

Nowadays, there is a high demand for great structural implementation and multifunctionality with excellent mechanical properties. The porous structures reinforced by graphene platelets (GPLs) having valuable properties, such as heat resistance, lightweight, and excellent energy absorption, have been considerably used in different engineering implementations. However, stiffness of porous structures reduces significantly, due to the internal cavities, by adding GPLs into porous medium, effective mechanical properties of the porous structure considerably enhance. This paper is relating to vibration analysis of fluidconveying cantilever porous graphene platelet reinforced (GPLR) pipe with fractional viscoelastic model resting on foundations. A dynamical model of cantilever porous GPLR pipes conveying fluid and resting on a foundation is proposed, and the vibration, natural frequencies and primary resonant of such a system are explored. The pipe body is considered to be composed of GPLR viscoelastic polymeric pipe with porosity in which Halpin-Tsai scheme in conjunction with the fractional viscoelastic model is used to govern the construction relation of nanocomposite pipe. Three different porosity distributions through the pipe thickness are introduced. The harmonic concentrated force is also applied to the pipe and the excitation frequency is close to the first natural frequency. The governing equation for transverse motions of the pipe is derived by the Hamilton principle and then discretized by the Galerkin procedure. In order to obtain the frequency-response equation, the differential equation is solved with the assumption of small displacement, damping coefficient, and excitation amplitude by the multiple scale method. A parametric sensitivity analysis is carried out to reveal the influence of different parameters, such as nanocomposite pipe properties, fluid velocity and nonlinear viscoelastic foundation coefficients, on the primary resonance and linear natural frequency. Results indicate that the GPLs weight fraction porosity coefficient, fractional derivative order and the retardation time have substantial influences on the dynamic response of the system.

• Steel and Composite Structures
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• 제46권5호
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• pp.611-619
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• 2023

In the present work, the flutter characteristics of porous nanocomposite cylindrical shells, reinforced with graphene platelets (GPLs) in supersonic airflow, have been investigated. Different distributions for GPLs and porosities have been considered which are named uniform and non-uniform distributions thorough the shell's thickness. The effective material properties have been determined via Halpin-Tsai micromechanical model. The cylindrical shell formulation considering supersonic airflow has been developed in the context of first-order shell and first-order piston theories. The governing equations have been solved using Galerkin's method to find the frequency-pressure plots. It will be seen that the flutter points of the shell are dependent on the both amount and distribution of porosities and GPLs and also shell geometrical parameters.

• Geomechanics and Engineering
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• 제36권4호
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• pp.407-416
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• 2024

Dynamic response of a rock tunnels by laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the exponential shear deformation theory (ESDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.

• 한국재료학회지
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• 제23권7호
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• pp.366-372
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• 2013

Flexible polyurethane/clay porous nanocomposite foams were synthesized using natural and organically modified montmorillonite clays such as bentonite, closite 10A and closite 30B. The content of nanoclays was varied from 1 to 5 wt% of polyol. Dispersion of clay in Polyurethane(PU) matrix was investigated by X-ray diffraction(Cu-$K{\alpha}$ rays of wavelength $1.54{\AA}$) using an X-ray diffractometer. Also, we determined that the thermal resistance of PU foam increased with added clay, compared to that of pure PU foam. The cell size and the fraction of open cells of the precursor foam were controlled by the addition of clay to the polyurethane foam. Modified clays were found to be more efficient cell openers than the unmodified clay. In addition, the tensile strength and elongation of the polyurethane/clay porous nanocomposites were examined. Increasing clay content increased the mechanical properties of the composites, such as tensile strength, and elongation at break. However, increasing the content over 5 wt% deteriorated the properties of the composites. We found that the nanofillers(bentonite, closite 10A and closite 30B) improved the thermal stability of the nanocomposite foam. The nanocomposite foam containing 3 wt% of closite 30B exhibited the best tensile strength and thermal stability.

• 전기화학회지
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• 제17권4호
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• pp.229-236
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• 2014

본 연구에서는 리튬이온 이차전지 양극 활물질로 사용되는 $LiFePO_4$ 활물질을 이용하여 전지를 제조한 후 그 특성들을 평가하였다. 공침법을 이용하여 $FePO_4$ 전구체를 합성한 후 생성된 전구체에 리튬을 합성시키며, 열처리를 통하여 활물질을 생성시킨다. 열처리 온도에 의한 결과 중 $750^{\circ}C$에서의 결과가 가장 우수함을 확인하였으며 전도성을 확보하기 위하여 카본을 코팅하는 방법을 물리적 코팅 방식과 화학적 코팅방법으로 나누어 실험하였으며 물리적 카본 코팅의 결과 6wt%를 코팅했을 때 125 mAh/g의 용량을 보였으며 화학적 코팅에서는 코팅하지 않은 기본 활물질 보다 약 40%의 성능향상을 보여 130~140 mAh/g 대의 활물질 용량을 보였다. 다공성 구조체를 형성하기 위하여 nanocomposite을 투입한 실험에서는 $Al_2O_3$를 첨가한 활물질이 porous 형태의 구조체를 형성하고 $SiO_2$을 첨가한 활물질 보다 132 mAh/g의 용량으로 우수함을 알 수 있었다.

• Steel and Composite Structures
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• 제43권1호
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• pp.129-137
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• 2022

Dynamic response of a laminated porous concrete beam reinforced by nanoparticles subjected to harmonic transverse dynamic load is investigated considering structural damping. The effective nanocomposite properties are evaluated on the basis of Mori-Tanaka model. The concrete beam is modeled by the sinusoidal shear deformation theory (SSDT). Utilizing nonlinear strains-deflection, energy relations and Hamilton's principal, the governing final equations of the concrete laminated beam are calculated. Utilizing differential quadrature method (DQM) as well as Newmark method, the dynamic displacement of the concrete laminated beam is discussed. The influences of porosity parameter, nanoparticles volume percent, agglomeration of nanoparticles, boundary condition, geometrical parameters of the concrete beam and harmonic transverse dynamic load are studied on the dynamic displacement of the laminated structure. Results indicated that enhancing the nanoparticles volume percent leads to decrease in the dynamic displacement about 63%. In addition, with considering porosity of the concrete, the dynamic displacement enhances about 2.8 time.