• 제목/요약/키워드: porous metal

검색결과 460건 처리시간 0.024초

다공성 수침-평판전극간의 수적 방출 특성 (Water Droplet Ejection Characteristics of a Wet Porous Point-Plate Airgap)

  • 정재승;이우석;문재덕
    • 전기학회논문지
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    • 제58권10호
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    • pp.2005-2010
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    • 2009
  • Water droplet ejection characteristics of a point-to-plate airgap, with a wet porous point as a corona electrode, has been investigated. And the water droplet traces, charge, mass and number were measured experimentally. More particles are observed with wet porous point than metal point because the corona-discharging wet porous point can eject a number of water droplets. The water droplets ejected from the positive-corona-discharging wet porous point showed very fine traces as compared with those from the negative-corona-discharging wet porous point. Moreover, the water droplets ejected from the AC-corona-discharging wet porous point showed granular-like larger traces. It was shown that the weak corona discharge can eject smaller water droplets with larger ratio of mass-to-charge than the intense corona discharge.

Bone ingrowth 향상을 위해 플라즈마 용사된 초내식성 오스테나이트 스테인리스강의 다공성 코팅층에 대한 연구 (A Study on Plasma Sprayed Porous Super Austenitic Stainless Steel Coating for Improvement of Bone Ingrowth)

  • 오근택;박용수
    • 한국표면공학회지
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    • 제29권2호
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    • pp.81-92
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    • 1996
  • The cementless fixation of bone ingrowth by porous coatings on artificial hip joint prostheses are replacing polymethylmethacrylate(PMMA) bone cement fixations. However, the major interests in the field of porous metal coating are environmental corrosivity accelerated by metal ion release, deterioration in the mechanical property of the coating, and the mechanical failure of the coatings as well as the substrate. Therefore, the selection of right materials for coatings and the development of porous coating techniques must be accomplished. Because of the existing problems in Ti and Ti alloys which are used extensively, this study is focused on the plasma spraying technique for coating on super stainless steel substrate. In order to determine the optimum conditions which satisfy the requirement for the porous coatings, under the plasma spraying, we selected the experimental parameters which extensively influenced on the characteristics of the coating through the pre-examination. Spray distance has been selected among 120, 160, and 200mm and primary gas flow rate among 70, 100, and 130 SCFH. Current and secondary gas($H_2$) flow rate was fixed at 400A, and 15 SCFH respectively. To understand the characteristics of the coatings, surface morphology, cross-sectional micro-structure, surface roughness, residual stress, and corrosion resistance were elucidated and the best conditions for the bone ingrowth improvement on artificial hip joint prostheses were found.

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윤활액이 담지된 나노다공성 표면의 최신 응용분야 (Recent applications of lubricant-impregnated nanoporous surface : A Review)

  • 한경완;배기창;이정훈
    • 한국표면공학회지
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    • 제56권1호
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    • pp.1-11
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    • 2023
  • Lubricant-impregnated nanoporous surfaces (LIS), which is created by impregnating water-immiscible oil into nanoporous surface structure, have been explored considering wide range of application fields. Due to the lubricant impregnated in nanoporous structure, the surface shows extreme de-wetting with a high mobility of water droplets, so that various functionalities can be realized. The lubricant layer inhibits the contact of corrosive media to porous structure as well as metal substrate, thus the surface improves the corrosion resistance. The water on the surface freeze without any contact to solid porous structure, showing a low ice adhesion for de-icing an anti-icing. The extremely high mobility of water droplets on lubricant-impregnated porous surfaces also contributes the enhancement of condensation heat transfer as well as water harvesting from fog and moisture. Moreover, the bacteria adhesion on metal surface forming biofilms causing serious hygiene issues can be inhibited on the lubricantimpregnated surfaces. Despite of such superior functionalities, the lubricant-impregnated porous surface has a limitation of lubricant depletion by external flow of fluids. Therefore, extensive efforts to improve the durability of lubricant-impregnated surface are required for practical applications.

Fabrication of Metal-Semiconductor Interface in Porous Silicon and Its Photoelectrochemical Hydrogen Production

  • Oh, Il-Whan;Kye, Joo-Hong;Hwang, Seong-Pil
    • Bulletin of the Korean Chemical Society
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    • 제32권12호
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    • pp.4392-4396
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    • 2011
  • Porous silicon with a complex network of nanopores is utilized for photoelectrochemical energy conversion. A novel electroless Pt deposition onto porous silicon is investigated in the context of photoelectrochemical hydrogen generation. The electroless Pt deposition is shown to improve the characteristics of the PS photoelectrode toward photoelectrochemical $H^+$ reduction, though excessive Pt deposition leads to decrease of photocurrent. Furthermore, it is found that a thin layer (< 10 ${\mu}m$) of porous silicon can serve as anti-reflection layer for the underlying Si substrate, improving photocurrent by reducing photon reflection at the Si/liquid interface. However, as the thickness of the porous silicon increases, the surface recombination on the dramatically increased interface area of the porous silicon begins to dominate, diminishing the photocurrent.

다공성 그물구조 음극을 이용한 구리 전착에 관한 연구 (II) -유기첨가제 PEG, MPS의 영향 - (Electrodeposition of Copper on Porous Reticular Cathode (II) - Effect of PEG and MPS on throwing Power-)

  • 이관희;이화영;정원용
    • 전기화학회지
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    • 제4권2호
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    • pp.41-46
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    • 2001
  • 황산과 황산구리 수용액을 전해질로 사용하여 다공성 그물구조 금속을 전기화학적으로 제조하였으며, 이때 균질 전착에 영향을 미치는 첨가제 PEG, MPS의 영향에 대해 살펴보았다. 분극실험과 기공의 평균 직경이 $250{\mu}m$의 그물구조 전극을 여러장 적층하여 throwing power를 정량화 한 결과, PEG의 경우 분극 초기에 전극에서 탈착됨으로써 오히려 throwing power를 감소시키고 MPS는 500ppm까지 용액 중 첨가량의 증가와 함께 throwing power를 향상시키는 결과를 보였다 또한 MPS와 PEG가 동시에 혼합된 용액에서는 MPS의 효과가 우선적으로 나타나며 PEG의 효과는 무시할 정도였다 그러나 MPS의 첨가는 전착층의 균열을 유도하여 기계적 강도에 좋지 못한 영향을 미치며 균열을 피하려면 50ppm 이하가 적정함을 SEM 관찰을 통해 확인할 수 있었다.

Development of dry-origin latent footwear impression on non-porous and semi-porous surfaces using a 5-methylthioninhydrin and L-alanine complex

  • Hong, Sungwook;Kim, Yeounjeung;Park, Jihye;Lee, Hoseon
    • 분석과학
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    • 제30권2호
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    • pp.75-81
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    • 2017
  • 5-methylthioninhydrin (5-MTN) is an amino acid sensitive reagent used for the development of latent fingermarks deposited on porous surfaces such as paper and wood. The present study demonstrates that the 5-MTN can be used as a latent footwear impression enhancement reagent, by reacting with trace multivalent metal ions, which are the main components of the latent footwear impression. 5-MTN and L-alanine complex (MTN-ALA) used for the latent footwear impression development was prepared, by mixing $4.5{\times}10^{-3}M$ 5-MTN (in methanol) and $4.5{\times}10^{-3}M$ L-alanine (in methanol) in 1:1 ratio, and keeping undisturbed at room temperature for 24 h. The latent footwear impressions were deposited on white and black non-porous surfaces (glass plate, polyethylene panel, polypropylene panel, acryl panel, polyvinyl chloride (PVC) panel, poly(methyl methacrylate) (PMMA) panel, acrylonitrile-butadiene-styrene (ABS) panel, tile), and a semi-porous surfaces (painted wood). The latent footwear impressions on these surfaces were treated with MTN-ALA complex by spraying. The fluorescence of footwear impressions (occurred due to the reaction between MTN-ALA and metal complexes) was observed under a 505 nm forensic light source and an orange barrier filter. The enhancement of latent footwear impression was achieved from black surfaces without any blurring. However, the fluorescence (enhancement) of footwear impression was not observed on the white PVC, PMMA, and ABS surfaces, because the incident light interfered and reflected on the surface. The sensitivity of MTN-ALA was superior to 2,2'-dipyridil, which is a representative non-fluorescing footwear impression enhancement reagent, and similar to 8-hydroxyquinoline, which is a representative fluorescing footwear impression enhancement reagent.

다공성 물질을 이용한 CO2 포집 및 분리: 다공성 탄소와 유연한 MOF 비교 연구 (CO2 Capture & Separation in Microporous Materials: A Comparison Between Porous Carbon and Flexible MOFs)

  • 정민지;박서하;오현철;박귀일
    • 한국재료학회지
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    • 제28권7호
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    • pp.417-422
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    • 2018
  • The stereotype of flexible MOFs(Amino-MIL-53) and carbonized porous carbon prepared from renewable resources is successfully synthesized for $CO_2$ reduction application. The textural properties of these microporous materials are investigated, and their $CO_2$ storage capacity and separation performance are evaluated. Owing to the combined effects of $CO_2-Amino$ interaction and its flexibility, a $CO_2$ uptake of $2.5mmol\;g^{-1}$ is observed in Amino-MIL-53 at 20 bar 298 K. In contrast, $CH_4$ uptake in Amino-MIL-53 is very low up to 20 bar, implying potential sorbent for $CO_2/CH_4$ separation. Carbonized samples contain a small quantity of metal residues(K, Ca, Mg, S), resulting in naturally doped porous carbon. Due to the trace metal, even higher $CO_2$ uptake of $4.7mmol\;g^{-1}$ is also observed at 20 bar 298 K. Furthermore, the $CH_4$ storage capacity is $2.9mmol\;g^{-1}$ at 298 K and 20 bar. To evaluate the $CO_2$ separation performance, the selectivity based on ideal adsorption solution theory for $CO_2/CH_4$ binary mixtures on the presented porous materials is investigated.

다공성 표면 화염의 복사열효율측정에 관한 논의 (A Discussion on the Radiation Efficiency Measurement of Porous Surface Flames)

  • 정황희;심근선;이기만
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.157-159
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    • 2014
  • This article describes an investigation of basic combustion characteristics of radiant burner with various firing rate and equivalence ratios in porous metal. As a main experimental condition, firing rates and equivalence ratios each were adjusted from 204 to $408kW/m^2$ and 0.6 to 1.3. The purpose of this study is to investigate radiation efficiency using two experiment methods. The first way is to calculate the radiation efficiency by measuring the temperature of the burner surface, and the second is to compute the radiation efficiency by measuring the radiation intensity of the burner surface with a radio meter. The value of the radiation efficiency did not exactly match in the two cases. But we figured out that in accordance with increasing heat power, radiation efficiency was decreased. And additional complementary experiment on the relationship between these values is needed.

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Adsorption mechanism of copper ions on porous chitosan membranes: Equilibrium and XPS study

  • Ghaee, Azadeh;Zerafat, Mohammad Mahdi
    • Membrane and Water Treatment
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    • 제7권6호
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    • pp.555-571
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    • 2016
  • Heavy metal contamination has attracted considerable attention during recent decades due to the potential risk brought about for human beings and the environment. Several adsorbent materials are utilized for the purification of contaminated water resources among which chitosan is considered as an appropriate alternative. Copper is a heavy metal contaminants found in several industrial wastewaters and its adsorption on porous and macroporous chitosan membranes is investigated in this study. Membranes are prepared by phase inversion and particulate leaching method and their morphology is characterized using SEM analysis. Batch adsorption experiments are performed and it is found that copper adsorption on macroporous chitosan membrane is higher than porous membrane. The iso-steric heat of adsorption was determined by analyzing the variations of temperature to investigate its effect on adsorption characteristics of macroporous chitosan membranes. Furthermore, desorption experiments were studied using NaCl and EDTA as eluants. The mechanism of copper adsorption was also investigated using XPS spectroscopy which confirms simultaneous occurrence of chelation and electrostatic adsorption mechanisms.