• Title/Summary/Keyword: porous metal

Search Result 463, Processing Time 0.027 seconds

Role of Electron Acceptor-donor on Elemental Mercury Removal Using Nano-silver-plated Activated Carbons Complexes

  • Lee, Hyo In;Yim, Yoon-Ji;Bae, Kyong-Min;Park, Soo-Jin
    • Composites Research
    • /
    • v.31 no.2
    • /
    • pp.76-81
    • /
    • 2018
  • In this study, the elemental mercury removal behaviors of silver-plated porous carbons materials were investigated. The pore structures and total pore volumes of the hybrid materials were analyzed by $N_2$ adsorption/desorption analysis at 77 K. The pore structures and surface morphologies of the hybrid materials were characterized by XRD and SEM, respectively. The elemental mercury adsorption capacities of all silver-plated porous carbons hybrid materials were higher than those of the as-received samples, despite the fact that the specific surface areas and total pore volumes decreased with increasing metal loading time. It was found that silver nanoparticles showed excellent elemental mercury removal behaviors in carbonaceous hybrid materials.

A Study on the Microstructure of Sputtered Copper Thin Films Deposited by using Shadow Effect (그림자효과를 이용하여 증착한 구리박막의 구조에 관한 연구)

  • Bae, Chang-Hwan;Lee, Ju-Hee;Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.22 no.5
    • /
    • pp.275-281
    • /
    • 2009
  • The microstructure of copper films prepared by a sputtering apparatus, which was fabricated to enhance the shadowing effect, was investigated by scanning electron microscopy. Black copper films were deposited on copper wires at an Ar pressure of 10 Pa. The black films had an extremely porous structure composed of separated columns. This structure is quite similar to that of black titanium films prepared by cylindrical magnetron sputtering. These results suggest that the porous structure composed of separated columns is easily formed for metal films by enhancing the shadowing effect.

Three Dimensional Profile Measurement System for Flexible and Porous Sculptured Surfaces by Using Optical Microscope (광학현미경을 이용한 유연다공표면의 3차원 자유곡면 형상 측정시스템)

  • Park, H.G.;Kim, S.W.
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.14 no.9
    • /
    • pp.22-29
    • /
    • 1997
  • This paper describes a three dimensional profile measurement method for sheet metal products which have flexible and porous sculptured surfaces. Shadow masks are used as measuring objects for practical implementation or this study. The shadow masks are located inside the fluorescent glasses of monitors for televisions or computers and used to prevent electron guns from interfering between pixels. Three dimen- sional surface profiles are measured by adopting a software autofocusing technique to capture focused images. The experimental results show that the method is very effecive and suitable for sheet meal prod- ucts with flexible and porous surfaces.

  • PDF

Electrohydrodynamic Characteristics of AC Corona Discharge for the Frequency (교류 코로나 방전시 주파수 변화에 따른 전기유체역학적 특성)

  • Jung, Jae-Seung;Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.26 no.12
    • /
    • pp.87-92
    • /
    • 2012
  • In this paper, EHD(electrohydrodynamics) characteristics of AC corona discharge for the various frequency was investigated. Ionic wind velocity is controlled by the frequency of applied ac high voltage, and maximum velocity of the ionic wind is obtained at 1.2kHz. Maximum velocity are 1.90 m/s by metal corona electrode and 2.72m/s by wet porous corona electrode, These attain 91~99% of the maximum velocity in the DC corona discharge by adjusting the frequency through the experiments. In this paper, wet porous corona electrode has high possibility of cooling methode because a AC corona discharge using wet porous corona electrode is able to eject more water droplets than DC corona discharge.

Effective mechanical properties of micro/nano-scale porous materials considering surface effects

  • Jeong, Joonho;Cho, Maenghyo;Choi, Jinbok
    • Interaction and multiscale mechanics
    • /
    • v.4 no.2
    • /
    • pp.107-122
    • /
    • 2011
  • Mechanical behavior in nano-sized structures differs from those in macro sized structures due to surface effect. As the ratio of surface to volume increases, surface effect is not negligible and causes size-dependent mechanical behavior. In order to identify this size effect, atomistic simulations are required; however, it has many limitations because too much computational resource and time are needed. To overcome the restrictions of the atomistic simulations and graft the well-established continuum theories, the continuum model considering surface effect, which is based on the bridging technique between atomistic and continuum simulations, is introduced. Because it reflects the size effect, it is possible to carry out a variety of analysis which is intractable in the atomistic simulations. As a part of the application examples, the homogenization method is applied to micro/nano thin films with porosity and the homogenized elastic coefficients of the nano scale thickness porous films are computed in this paper.

Fabrication and Ammonia Gas Sensing Properties of Chemiresistor Sensor Based on Porous Tungsten Oxide Wire-like Nanostructure

  • Vuong, Nguyen Minh;Kim, Do-Jin;Hieu, Hoang Nhat
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2011.05a
    • /
    • pp.25.2-25.2
    • /
    • 2011
  • The tungsten oxide wire-like nanostructure is fabricated by deposition and thermal oxidation of tungsten metal on porous single wall carbon nanotubes (SWNTs). The morphology and crystalline quality of materials are investigated by SEM, TEM, XRD and Raman analysis. The results prove that $WO_3$ wire-like nanostructure fabricated on SWNTs show highly porous structures. Exposure of the sensors to NH3 gas in the temperature range of 150~300$^{\circ}C$ resulted in the highest sensitivity at $250^{\circ}C$ with quite rapid response and recovery time. Response time as a function of test concentrations and NH3 gas sensing mechanism is reported and discussed.

  • PDF

Transport of Zinc Ion in a Contained Liquid Membrane Permeator with Two Micro-Porous Films (지지막을 이용하는 액막 추출기 내에서 아연 이온의 이동)

  • 주창식;이석희;이민규;홍성수;하홍두;정석기
    • Journal of Environmental Science International
    • /
    • v.9 no.2
    • /
    • pp.159-164
    • /
    • 2000
  • For the purpose of development of a liquid membrane permeator which separates metal ions from aqueous solutions continuously and effectively, a continuous membrane permeator with the membrane solution trapped between extraction and stripping phases by two micro-porous hydrophilic films was manufactured. Experimental researches on the separation of zinc ion from aqueous solutions were performed in the liquid membrane permeator with 30 vol % D2EHPA solution in kerosine as liquid membrane. As results, the liquid membrane permeator separates zinc ion from aqueous solutions continuously and effectively in the wide range of operating conditions. A simple mass transfer rate model using equilibrium constant of the extraction reaction for the system used were proposed, and the model was compared with experimental results of separation of zinc ion in the permeator. And the effects of operating factors, such as space time, pH of extraction solution, extraction temperature, on the separation rate of zinc ion in the permeator were experimentally examined.

  • PDF

Specific Resistance (K2´) of Dust Layer Deposited on Porous Media (다공성 필터에서의 여과 분진층 비저항 연구)

  • 이선희;이경미;조영민
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.20 no.3
    • /
    • pp.371-380
    • /
    • 2004
  • In the dust separation by using porous filter media, the structure of dust layer deposited on the filter surface of filter medium directly affects the effective filtration. The present study has investigated the specific resistance (K$_2$') of the dust layer and its porosity ($\varepsilon$$_{c}$) for three different filters; FA composite filter, metal fiber filter and stainless filter. The specific resistance (K$_2$') increased and at the same time the cake porosity ($\varepsilon$$_{c}$) decreased with the increase of filtration velocity, possibly due to the compressible effect of dust layer. However, under the low dust concentration, subsequent dust particles would block the open channels through the layer resulting in high specific resistance of the layer. The FA composite filter among three filters was shown to be the most effective filter for dust cake filtration at low filtration velocities less than 0.1 m/s for an approximate dust concentration of 5 g/㎥.

Fabrication of Nano Metal Compounds Using Porous Aluminum Oxide Films (기공성 알루미나 산화 피막을 이용한 나노 금속화합물의 제조)

  • Oh, Han-Jun;Jeong, Yong-Soo;Chi, Choong-Soo
    • Journal of the Korean institute of surface engineering
    • /
    • v.43 no.5
    • /
    • pp.248-254
    • /
    • 2010
  • Porous $Al_2O_3$ film can be utilized as template for fabrication of nano-structured materials. Porous anodic alumina layer as template was prepared by anodization of aluminum in oxalic acid, and the pore diameter and barrier-type alumina layer can be controlled for proper anodizing parameter by widening process in $H_3PO_4$ solution. The $SiO_2$ nanodot and Ni nanowire was fabricated using anodic alumina template and their characteristics were investigated using SEM and TEM with EDS. Especially the growth mechanism of $SiO_2$ nanodot in alumina membrane compared with thinning of the alumina barrier layer during anodization was also investigated.

Low Temperature Adsorption of Hydrogen on Nanoporous Materials

  • Jhung, Sung-Hwa;Yoon, Ji-Woong;Kim, Hye-Kyung;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.7
    • /
    • pp.1075-1078
    • /
    • 2005
  • Hydrogen adsorption on various porous materials have been studied with a volumetric method at low temperature in the pressure of 0-760 torr. Their hydrogen uptakes depend at least partly on microporosity rather than total porosity. However, it is also necessary to consider other parameters such as pore size and pore architecture to explain the adsorption capacity. The heat of adsorption and adsorption-desorption-readsorption experiments show that the hydrogen adsorption over the porous materials are composed of physisorption with negligible contribution of chemisorption. Among the porous materials studied in this work, SAPO-34 has the highest adsorption capacity of 160 mL/g at 77 K and 1 atm probably due to high micropore surface area, micropore volume and narrow pore diameter.