• 제목/요약/키워드: porous matrix

검색결과 263건 처리시간 0.029초

Fabrication of Porous Structure of BCP Sintered Bodies Using Microwave Assisted Synthesized HAp Nano Powder

  • Youn, Min-Ho;Paul, Rajat Kanti;Song, Ho-Yeon;Lee, Byong-Taek
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.475-476
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    • 2006
  • Using microwave synthesized HAp nano powder and polymethyl methacrylate (PMMA) as a pore-forming agent, the porous biphasic calcium phosphate (BCP) ceramics were fabricated depending on the sintering temperature. The synthesized HAp powders was about 70-90 nm in diameter. In the porous sintered bodies, the pores having $150-180\;{\mu}m$ were homogeneously dispersed in the BCP matrix. Some amounts of pores interconnected due the necking of PMMA powders which will increase the osteoconductivity and ingrowth of bone-tissues while using as a bone substrate. As the sintering temperature increased, the relative density increased and showed the maximum value of 79.6%. From the SBF experiment, the maximum resorption of $Ca^{2+}$ ion was observed in the sample sintered at $1000^{\circ}C$.

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The bounds for fully saturated porous material

  • Yoon, Young-June;Jung, Jae-Yong;Chung, Jae-Pil
    • 한국정보전자통신기술학회논문지
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    • 제13권5호
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    • pp.432-435
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    • 2020
  • The elasticity tensor for water may be employed to model the fully saturated porous material. Mostly water is assumed to be incompressible with a bulk modulus, however, the upper and lower bounds of off-diagonal components of the elasticity tensor of porous materials filled with water are violated when the bulk modulus is relatively high. In many cases, the generalized Hill inequality describes the general bounds of Voigt and Reuss for eigenvalues, but the bounds for the component of elasticity tensor are more realistic because the principal axis of eigenvalues of two phases, matrix and water, are not coincident. Thus in this paper, for anisotropic material containing pores filled with water, the bounds for the component of elasticity tensor are expressed by the rule of mixture and the upper and lower bounds of fully saturated porous materials are violated for low porosity and high bulk modulus of water.

고에너지 밀도 바나듐 레독스 흐름 전지를 위한 망간산화물 촉매와 다공성 탄소 기재의 시너지 효과 (Synergistic Effect of the MnO Catalyst and Porous Carbon Matrix for High Energy Density Vanadium Redox Flow Battery)

  • 김민성;고민성
    • 한국표면공학회지
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    • 제52권3호
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    • pp.150-155
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    • 2019
  • The carbon electrode was modified through manganese-catalyzed hydrogenation method for high energy density vanadium redox flow battery (VRFB). During the catalytic hydrogenation, the manganese oxide deposited at the surface of the carbon electrode stimulated the conversion reaction from carbon to methane gas. This reaction causes the penetration of the manganese and excavates a number of cavities at electrode surface, which increases the electrochemical activity by inducing additional electrochemically active site. The formation of the porous surface was confirmed by the scanning electron microscopy (SEM) images. Finally, the electrochemical performance test of the electrode with the porous surface showed lower polarization and high reversibility in the cathodic reaction compared to the conventional electrode.

Preparation of a Porous Chitosan/Fibroin-Hydroxyapatite Composite Matrix for Tissue Engineering

  • Kim, Hong-Sung;Kim, Jong-Tae;Jung, Young-Jin;Ryu, Su-Chak;Son, Hong-Joo;Kim, Yong-Gyun
    • Macromolecular Research
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    • 제15권1호
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    • pp.65-73
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    • 2007
  • Chitosan, fibroin, and hydroxyapatite are natural biopolymers and bioceramics that are biocompatible, biodegradable, and resorb able for biomedical applications. The highly porous, chitosan-based, bioceramic hybrid composite, chitosanlfibroin-hydroxyapatite composite, was prepared by a novel method using thermally induced phase separation. The composite had a porosity of more than 94% and exhibited two continuous and different morphologies: an irregularly isotropic pore structure on the surface and a regularly anisotropic multilayered structure in the interior. In addition, the composite was composed of an interconnected open pore structure with a pore size below a few hundred microns. The chemical composition, pore morphology, microstructure, fluid absorptivity, protein permeability, and mechanical strength were investigated according to the composition rate of bioceramics to biopolymers for use in tissue engineering. The incorporation of hydroxyapatite improved the fluid absorptivity, protein permeability, and tenacity of the composite while maintaining high porosity and a suitable microstructure.

세라믹 매트릭스 버너에 형성된 예혼합 화염의 NOx 및 CO 배출특성 (Nitric Oxide and Carbon Monoxide Emission from a Premixed Flame Stabilized in a Porous Ceramic Matrix Burner)

  • 정종수;이교우
    • 대한기계학회논문집B
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    • 제20권10호
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    • pp.3243-3250
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    • 1996
  • Emission characteristics of nitric oxides and carbon monoxide from a porous media combustor has been experiment studied. The relationship between the change of flame shape and emission has also been examined. As the equivalence ratio decreases, the flame shape on the ceramic matrix plate changes from a diffusion flame, R(radiant)-type flame, to B(Blue)-type flame. With large fuel flow rate, R-type flame turns to be two dimensional R-II type flame around the equivalence of 0.7. Carbon monoxide emission increases very rapid with decreasing equivalence ratio. It changes a lot from some 10 ppm to 100-10,000 ppm with the change of flame type from R-I to R-II type. Nitric oxide emission from the premixed burner is less than 25 ppm over all range of fuel flow rate, which is less than 20% of NOx emission from conventional gas burners.

용탕 침투법을 이용한 복합 삽입 금속의 제조 (Fabrication of Composite Filler Metal by Melt Infiltration)

  • 박흥일;김지태;김우열
    • 한국주조공학회지
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    • 제23권5호
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    • pp.244-250
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    • 2003
  • The aim of this study is fabricating of composite filler metal (CFM) by a combination of selective laser sintering (SLS) of stainless steel powders (RapidSteel $2.0^{TM}$ and liquid phase infiltration of Ag-28 wt.%Cu alloy. Porous stainless steel body with inter-connected pore channels was fabricated by SLS, binder decomposing and densification processes. By the direct contact infiltration, the narrow inter-particle channels of the porous body were completely filled with the Ag-28 wt.%Cu alloy infiltrant. During infiltration, the dissolved elements of Fe, Ni and Cr from the porous body were solved into copper solid solution phases, which consist of eutectic structure of composite metal matrix. The S10C/CFM/S10C joints, which have narrow clearance gaps between them up to 10 micrometers, were joined successfully by self-feeding of filler metal from the matrix of CFM. The CFM kept its original thickness and microstructure after brazing. The tensile strength of brazed specimen was higher than 30 kgf/$mm^2$ and showed a typical ductile fracture mode in the CFM.

굵은골재 최대치수 40 mm 투수 콘크리트의 물리적 특성과 질소산화물 제거에 관한 연구 (An Experimental Study on NOx Degradation Efficiency and Physical Characteristics of Maximum Size 40 mm Porous Concrete)

  • 홍종현;김문훈;류성필;정광옥
    • 한국환경과학회지
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    • 제15권5호
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    • pp.431-438
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    • 2006
  • The strength, water permeability, and photo-degradation efficiency of NOx of porous concrete with a new concept were studied in this paper. The porous concrete was comprised of coarse aggregate of maximum size 40 mm, cement, silica fume, water and air-entraining(AE) water reducing agent. The strength of porous concrete was strongly related to its matrix proportion and compaction energy. An experimental test was carried out to study the parameters of cement proportions and silica fume content for pavement applications of porous concrete which were paving a footpath, a bikeway, a parking lot, and a driveway. The regressed equations of relation-ships between compressive strength and flexural strength, and coefficient permeability and void ratios were indicated as y=7.69x+71.74 and $y=0.42e^{0.28x}$. A method of making an air purification-functioning road, which was spraying a mixture of a photocatalyst, cement, and water onto the surface of the road, was suggested.

팽창흑연을 혼입한 시멘트 경화체의 흡착 특성 (Fine Dust Adsorption Properties of Cement Matrix Mixed with Expanded Graphite)

  • 이진원;이창우;황우준;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2022년도 가을 학술논문 발표대회
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    • pp.105-106
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    • 2022
  • Now, the world is increasingly anxious about fine dust due to abnormal temperatures caused by global warming and increased yellow dust caused by desertification, and the World Health Organization (WHO) pointed out that more than 99% of the world's population is exposed to fine dust. In this situation, the reduction rate of fine dust and carbon dioxide of the matrix was tested by using expanded graphite, an eco-friendly and porous material, to improve air quality. As a result of the test, since expanded graphite is a material that expands between layers compared to conventional graphite, the reduction rate of fine dust and carbon dioxide decreases as the replacement rate of expanded graphite increases.

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