• 제목/요약/키워드: porous block

검색결과 71건 처리시간 0.027초

Fabrication of Colloidal Clusters of Polymer Microspheres and Nonspherical Hollow Micro-particles from Pickering Emulsions

  • Cho, Young-Sang;Kim, Tae-Yeol;Yi, Gi-Ra;Kim, Young-Kuk;Choi, Chul-Jin
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.159-166
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    • 2012
  • We have introduced the Pickering emulsion systems to generate novel confining geometries for the selforganization of monodisperse polymer microspheres using nanoparticle-stabilized emulsion droplets encapsulating the building block particles. Then, through the slow evaporation of emulsion phases by heating, these microspheres were packed into regular polyhedral colloidal clusters covered with nanoparticle-stabilizers made of silica. Furthermore, polymer composite colloidal clusters were burnt out leaving nonspherical hollow micro-particles, in which the configurations of the cluster structure were preserved during calcination. The selfassembled porous architectures in this study will be potentially useful in various applications such as novel building block particles or supporting materials for catalysis or gas adsorption.

도시철도 터널내 콘크리트 도상용 흡음블럭의 최적 배합설계 (An optimal mix design of sound absorbing block on concrete ballast in urban train tunnel)

  • 이홍주;오순택;이동준
    • 한국터널지하공간학회 논문집
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    • 제18권1호
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    • pp.75-82
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    • 2016
  • 최근 도시철도 터널내부에서 콘크리트 도상의 확대로 유발된 반사마찰소음에 대한 저감대책으로 다공성 흡음블럭이 적용되고 있다. 운영 중인 도시철도용 품질시험기준과 제정 중인 철도표준규격을 만족하는 흡음블럭의 개발을 위하여 3 단계의 최적 배합설계를 위한 주요 변수시험을 수행하였다. 순환 골재인 플라이애쉬를 혼합하여 건비빔 발포 시료를 개발하여 요구되는 구조성능을 시험하고 혼화재의 영향성을 평가하였다. 또한 도시철도 터널 내부에 시공할 경우 열악한 작업환경과 원활한 유지관리에 대한 대책으로 대표적인 경량골재들을 혼합하여 경량화와 구조성능을 평가하였다.

고분자전해질 연료전지의 환원극 블록과 공기 유량 영향에 대한 전산 해석 연구 (A Numerical Study of Cathode Block and Air Flow Rate Effect on PEMFC Performance)

  • 조성훈;김준범
    • 공업화학
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    • 제33권1호
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    • pp.96-102
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    • 2022
  • 고분자전해질막 연료전지의 반응물인 수소와 산소는 기체 상태이므로, 반응물이 원활히 전달될수록 작동 전압의 손실을 줄일 수 있다. 높은 전류밀도 영역에서 산소 물질 전달이 전압 손실을 좌우하므로, 환원극 유로의 형상 변경에 대한 연구들이 진행되어 왔다. 환원극 유로 형상 중에서 유로를 막는 블록은 반응물을 다공성 매질인 기체확산층으로 강제 대류 하도록 사용되었다. 본 연구에서는 간단한 단 채널의 연료전지 모델에 블록을 배치하였다. 전산 유체역학을 사용하였고, 공기 공급 유량을 달리하였을 때 블록으로 인한 강제 대류 효과가 전압-전류 곡선과 국부 전류 밀도에 대한 영향을 연구하였다. 기체확산층으로의 강제 대류 현상을 통하여 적은 공기 공급 유량으로도 높은 전류 밀도를 얻을 수 있었다. 다수의 블록을 직렬로 배치한 경우에 1개의 블록만 배치한 것보다 강제 대류 효과를 증가시켜 높은 전류밀도를 얻을 수 있었다.

Evaluation of tissue ingrowth and reaction of a porous polyethylene block as an onlay bone graft in rabbit posterior mandible

  • Sosakul, Teerapan;Tuchpramuk, Pongsatorn;Suvannapruk, Waraporn;Srion, Autcharaporn;Rungroungdouyboon, Bunyong;Suwanprateeb, Jintamai
    • Journal of Periodontal and Implant Science
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    • 제50권2호
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    • pp.106-120
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    • 2020
  • Purpose: A new form of porous polyethylene, characterized by higher porosity and pore interconnectivity, was developed for use as a tissue-integrated implant. This study evaluated the effectiveness of porous polyethylene blocks used as an onlay bone graft in rabbit mandible in terms of tissue reaction, bone ingrowth, fibrovascularization, and graft-bone interfacial integrity. Methods: Twelve New Zealand white rabbits were randomized into 3 treatment groups according to the study period (4, 12, or 24 weeks). Cylindrical specimens measuring 5 mm in diameter and 4.5 mm in thickness were placed directly on the body of the mandible without bone bed decortication, fixed in place with a titanium screw, and covered with a collagen membrane. Histologic and histomorphometric analyses were done using hematoxylin and eosin-stained bone slices. Interfacial shear strength was tested to quantify graft-bone interfacial integrity. Results: The porous polyethylene graft was observed to integrate with the mandibular bone and exhibited tissue-bridge connections. At all postoperative time points, it was noted that the host tissues had grown deep into the pores of the porous polyethylene in the direction from the interface to the center of the graft. Both fibrovascular tissue and bone were found within the pores, but most bone ingrowth was observed at the graft-mandibular bone interface. Bone ingrowth depth and interfacial shear strength were in the range of 2.76-3.89 mm and 1.11-1.43 MPa, respectively. No significant differences among post-implantation time points were found for tissue ingrowth percentage and interfacial shear strength (P>0.05). Conclusions: Within the limits of the study, the present study revealed that the new porous polyethylene did not provoke any adverse systemic reactions. The material promoted fibrovascularization and displayed osteoconductive and osteogenic properties within and outside the contact interface. Stable interfacial integration between the graft and bone also took place.

Blocking layer 제작에 따른 염료감응형 태양전지 출력특성 및 내부 임피던스 분석 (Analyses of the Output Characteristics and the Internal Impedance of Dye-sensitized Solar Cell According to the Fabrication of the Blocking Layer)

  • 김진경;손민규;김수경;홍나영;김병만;프라바카르;김희제
    • 전기학회논문지
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    • 제61권1호
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    • pp.85-88
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    • 2012
  • DSCs are based on a dye-adsorbed porous $TiO_2$ layer as a photo electrode [1]. Under the illumination, dye molecules are excited and electrons are produced. The injected electrons in the conduction band of $TiO_2$ may recombine with the electrolyte. To obtain high performance DSCs, it is essential to retard the recombination. The charge recombination can be reduced by forming core-shell structure. In this work, we investigated the core-shell structure with $Al_2O_3$ and MgO coating layer on the porous $TiO_2$ layer. We confirmed the photovoltaic properties by I-V characteristics. The current and the efficiency was improved. In addition to, Through decrease in the width of EIS arc, which is the sum of the interfacial charge transfer resistances of both electrodes, we can be indicated that the block effect.

An Experimental Study on Wafer Demounting by Water Jet in a Waxless Silicon Wafer Mounting System

  • Kim, Kyoung-Jin;Kwak, Ho-Sang;Park, Kyoung-Seok
    • 반도체디스플레이기술학회지
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    • 제8권2호
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    • pp.31-35
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    • 2009
  • In the silicon wafer polishing process, the mounting stage of silicon wafer on the ceramic carrier block has been using the polishing template which utilizes the porous surface instead of traditional wax mounting method. Here in this article, the experimental study is carried out in order to study the wafer demounting by water jet and the effects of operating conditions such as the water jet flowrate and the number of water jet nozzles on the wafer demounting time. It is found that the measured wafer demounting time is inversely proportional to the water flowrate per nozzle, regardless of number of nozzles used; implying that the stagnation pressure by the water jet impingement is the dominant key factor. Additionally, by using the transparent disk instead of wafer, the air bubble formation and growth is observed under the disk, making the passage of water flow, and subsequently demounting the wafer from the porous pad.

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바이오 복합 식생블록의 수질정화 특성 연구 (A Study on the Water-Purification Characteristics of Bio-Composite Planting Blocks)

  • 김영익;연규석;최중대;김기성;서지연;김용성
    • 한국농공학회논문집
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    • 제53권2호
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    • pp.75-82
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    • 2011
  • This study was performed to evaluate the water purification properties of bio-composites planting blocks using oyster shell and effective microorganism that have high absorption ability of heavy metals and organics to develop environmentally friendly river embankment technique contained various factors such as oyster shells, effective microorganism, porous concrete and planting embankment block. To maximize greening effect, the seeds were arbitrarily sown. In addition, in order to analyze the effect of water quality purification after the planting, the samples were collected from each designated zone 1, 7 and 30 days after steeping in water. Then, the samples were analyzed in terms of seven test items such as SS, BOD, COD, T-N, T-P, pH, etc. on the basis of the test method for water pollution. The following conclusions were reached from the test result. As a result of analysis for water quality purification for the concrete block containing the effective microorganism, it was found that the values for SS, BOD, T-N and T-P for the sample taken after 30 days were lower than the initial values, which indicated that the water purification effect had been created. The result of the water quality purification analysis for the concrete block containing oyster shell showed that the values for SS, BOD, COD and T-P for the sample taken after 30 days were lower than the initial values which also indicated that it had been effective in water quality purification.

환경친화 옹벽용 포러스콘크리트의 현장적용성에 관한 연구Ⅱ (A Study on the Filed application of Environmental Friendly Porous Concrete For Retaining Wall)

  • 김정환;이남익;이준;박승범;장영일;서대석
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 춘계 학술발표회 제20권1호
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    • pp.817-820
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    • 2008
  • 본 연구는 투수, 다기능, 수질정화, 흡음성을 가진 포러스 콘크리트를 하천의 제방공사, 농업수로의 제방공사, 도로 법면의 사방공사, 철도의 측방사면공사, 조경담장, 도로 방호벽, 어소블록 등을 구축하도록 하는 옹벽블록을 장투리천에 적용시켰으며 그 결과는 다음과 같다. 포러스 콘크리트 옹벽블록의 시공은 기초터파기, 잡석부설 및 다짐, 기초콘크리트, 부착모르타르 부설, 블록쌓기, 뒷채움 잡석 부설 및 다짐, 블록연결핀으로 연결 등의 순서로 진행되었으며 공종별로 그 특성에 맞는 재료를 선정하여 시공하였다.현장에 적용된 포러스콘크리트 옹벽블록의 품질 특성 평가 결과, 압축강도는 $20.1{\sim}22.5MPa$, 공극률은 $10.0{\sim}10.4$%로 측정되어 시방서에 명기되어 있는 압축강도 18MPa이상, 공극률 10%이상을 모두 만족시키는 것으로 나타났다. Slope/w를 이용하여 포러스콘크리트 옹벽블록의 사면 안정성 검토결과 안전율이 1.739으로 해석되어 설계 기준 안전률인 1.3을 초과하여 안전한 것으로 나타났다. 시공 6개월 후 식생 모니터링 결과, 갯버들이 식재된 식재공에서 양호하게 성장하여 포러콘크리트옹벽블록은 이 치수위주의 하천정비나 불량한 유역관리에 의해 훼손된 하천의 생태서식처를 되살리고 하도와 하천변을 원래의 자연하천에 가깝게 되돌리는 데 유효한 공법으로 판단된다.

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투수성 포장재의 우수 표면유출 저감 효과 (The Effect of Pervious Pavement on Reducing the Surface Runoff)

  • 이춘석;류남형;한승호
    • 한국환경복원기술학회지
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    • 제11권6호
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    • pp.26-37
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    • 2008
  • The purpose of the study was to evaluate the effect of pervious pavements on reducing the surface runoff caused by rainfall. The surface runoff from twelve steel experimental beds with different pavement had been recorded every minute from May to September 2008, by the measuring system of tipping buckets(0.1mm/count) and data aquisition systems(National Instrument's Labview and DAQ boards & Autonics PR12-4). The dimension of the experimental bed was $1.5m(W){\times}2.0m(L){\times}0.6m(D)$ and eleven different kinds of vegetational(grass, grass+cubic stone, grass+hole brick), modular(brick, cubic stone, small cubic stone, wood block, interlocking block, clay brick, granular clay brick) and granular(naked soil, gravel) paving materials and concrete were applied for the comparison. Six rain events with depth over 30mm were selected and compared. The maximum depth of the rainfall selected was 137.5mm for 28 hours, and the minimum 30mm for 5 hours. The maximum rainfall per hour was 23mm/hr and the minimum 11.4mm/hr. The major findings were as follows; 1. All pervious pavement applied reduced over 75% of the surface runoff compared with concrete pavement. The grassy and porous pavements were relatively efficient in reducing surface runoff. 2. The grass was the more efficient as intercepting average 69.5mm of initial surface runoff, and maximum 77.8mm at the condition of 13.5mm/hr rainfall. The next was gravel intercepting maximum 65.5mm at the condition of 13.5mm/hr and the 40.9mm at 19.1mm/hr, average 55.7mm. 3. The modular pavements common in urban area were not good in intercepting the runoff except the 'clay granular brick' compared with others. The 'clay granular brick' showed relatively efficient intercepting average 14.1mm, which was the bigger amount than the 'grass+hole brick'. 4. The 'naked soil' were more effective than the 'concrete', 'brick', and 'interlocking block' in reducing the surface runoff, but less efficient than other materials. The capacity of the 'naked soil' to intercept the initial rainfall was similar to the 'brick'. As summary, the more grassy and porous pavement shows more effective in reducing surface runoffs.

빗물저장 및 활용을 위한 보도블럭구조의 최적화 (An Optimization of a Walkway Block Structure for Rainwater Harvesting)

  • 조태준;손병직
    • 한국구조물진단유지관리공학회 논문집
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    • 제22권1호
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    • pp.40-47
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    • 2018
  • 다공성 보도 블록은 이미 많이 사용되지만, 큰 침투성으로 인해 블록의 강도를 감소시키고, 균열 및 침전의 문제를 만든다. 본 연구에서는 최소 주응력의 결정된 위치를 설계하고 검증하기 위하여, 이동하는 체중하중에 대한 보행로 블록에서의 최소 주응력의 위치를 결정함으로써, 주어진 문제에 대한 최적해를 제시하였다. 최소 주응력의 결정된 위치에 대한 검증 예를, 내부에 빗물을 저장하기위한 통행보도의 탄성 기초상의 2 차원 블록 부재에 대하여 제시하였다. 전단력의 합력에 대한 최소값은 ${\times}1$이 58.58 mm(전체 스팬의 30%, 200 mm)일 때, 최소 변형은 ${\times}2=80mm$(전체 스팬의 70%, 200 mm)에 있다. 수정 된 모델에서, 이동하는 경계 조건(보도 보행 하중)이 ${\times}1$(= 0 mm)에 있을 때, 168 mm (스팬의 84%, 200 mm)에서 최소 주응력의 위치가 발견되었으며, 스프링으로 모델링 된 기초의 응답에 대하여 모델링하였다. 결과적으로, 중립 축(${\times}2=167mm$)에서의 빗물저장을 위한 보도블럭의 "0"변형 위치가 3 차원 FEM 분석 검증을 통하여 결정되었다.