• Title/Summary/Keyword: porous PTFE

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Porous Electrode manufacture by catalyst powdering method for PAFC (촉매분말법에 의한 PAFC용 다공성 전극제작)

  • 김영우;이주성
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.194-199
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    • 1993
  • Gas diffusion passes are introduced to catalyst layer so as to enlarge reaction region in cathode and anode and then improve electrode performances. The catalyst layer was manufactured with PTFE/carbon (none catalyst loaded) for gas diffusion and Pt/carbon (10 w/o Pt catalyst loaded) by varing the mixing ratio of (PTFE/carbon) to (Pt/carbon) by catalyst powdering method. The electrodes made by mixing Pt(10 w/o)/carbon powders and PTFE/carbon powders containing 60 w/o PTFE at the ratio of 7 : 3 showed the best electrode performances. It was known that by comparing the porosities to electrode performances the electrode performances were increased as both macro pore for gas diffusion and micro pore for electrolyte intrusion were formed much more. The platinum catalyst content in electrode was 0.2 mg/$\textrm{cm}^2$ and the PTFE content was 42 w/o. The electrode performance in unit cell was 220 ㎃/$\textrm{cm}^2$/0.7 V at operating temperature of 150$^{\circ}C$.

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PREVENTION OF MURAL THROMBUS IN POROUS INNER TUBE OF DOUBLE-LAYERED TUBE BY SALINE PERFUSION (생리식염수의 재료표면에의 분출에 의한 이중튜브의 응혈 방지)

  • Kim, Sung-S.;Park, Joon-B.
    • Proceedings of the KOSOMBE Conference
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    • v.1993 no.11
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    • pp.110-113
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    • 1993
  • An in vitro experiment under laminar non-pulsatile blood flow and an acute canine ex vivo femoral A-V series shunt experiment were undertaken to investigate the effectiveness of saline perfusion through pores of porous tubes to prevent formation of mural thrombus. PS/SBR porous tubes were used for the in vitro experiment. Commercially obtained ePTFE porous tubes were etched by sodium naphthalenide, and the etched tubes were used for the ex vivo experiment. According to the results of the in vitro experiment, mural thrombus on the surface of the porous tribe could be prevented by the saline perfusion. Adhered blood cells decreased semi-logarithmically with increased perfusion rate (up to $0.022\;ml/min-cm^2$) of isotonic saline solution. According to results of the ex vivo experiment, mural thrombus decreased with increased perfusion rate (upto $0.060\;ml/min-cm^2$).

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Preparation and Characterization of Partially Fluorinated Poly (arylene ether sulfone)/PTFE Composite Membranes for Fuel Cell (연료전지용 부분불소계 Poly (arylene e ther sulfone)/PTFE 복합막의 제조 및 특성 분석)

  • Kim, Eun Hee;Chang, Bong-Jun;Kim, Jeong-Hoon
    • Membrane Journal
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    • v.22 no.3
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    • pp.191-200
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    • 2012
  • New composite membranes were manufactured by impregnating post-sulfonated poly(arylene ether sulfone)s containing perfluorocyclobutane (PFCB) groups into porous polytetrafluoroethylene (PTFE) films. Two kinds of post-sulfonated poly(arylene ether sulfone)s with two different monomer ratios (sulfonable biphenylene monomer : non-sulfonable sulfonyl monomer = 6 : 4, 4 : 6) were first prepared through three synthetic steps: synthesis of trifluorovinylether-terminated monomers, thermal cycloaddition polymerization and post-sulfonation using chlorosulfonic acid (CSA). The composite membranes were then prepared by adjusting the concentrations (5~20 wt%) of the resulting copolymers impregnated in the PTFE films. The water uptake, ion exchange capacity (IEC) and ion conductivity of the composite membranes were characterized and compared with their unreinforced dense membranes and Nafion. All the synthesized compounds, monomers and polymers were characterized by $^1H$-NMR, $^{19}F$-NMR and FT-IR and the composite membranes were observed with scanning electron micrographs (SEM).

Perfluorinated Sulfonic Acid Ionomer-PTFE Pore-filling Membranes for Polymer Electrolyte Membrane Fuel Cells (고분자전해질연료전지용 과불소계 술폰화 이오노머-PTFE 강화막)

  • Kang, Seong Eun;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.2
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    • pp.171-179
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    • 2015
  • Perfluorinated sulfonic acid ionomers (PFSAs) have been widely as solid electrolyte materials for polymer electrolyte membrane fuel cells, since they exhibit excellent chemical durability under their harsh application conditions as well as good proton conductivity. Even PFSA materials, however, suffer from physical failures associated with repeated membrane swelling and deswelling, resulting in fairly reduced electrochemical lifetime. In this study, pore-filling membranes are prepared by impregnating a Nafion ionomer into the pore of a porous PTFE support film and their fundamental characteristics are evaluated. The developed pore-filling membranes exhibit extremely high proton conductivity of about $0.5S\;cm^{-1}@90^{\circ}C$ in liquid water.

Enhancing Adhesion between Polyphenylene Sulfide Fabric and Polytetrafluoroethylene Film for Thermally Stable Air Filtration Membrane (열안정 공기 여과막용 폴리페닐렌 설파이드 원단과 폴리테트라플루오로에틸렌 필름 사이의 접착력 향상)

  • Jin Uk Kim;Hye Jeong Son;Sang Hoon Kang;Chang Soo Lee
    • Membrane Journal
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    • v.33 no.4
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    • pp.201-210
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    • 2023
  • Dust filter membranes play a crucial role in human life and various industries, as they contribute to several important aspects of human health, safety, and environmental protection. This study presents the development of a polysulfone@polyphenylene sulfide/polytetrafluoroethylene (PSf@PPS/ePTFE) composite dust filter membrane with excellent thermal stability and adhesion properties for high-temperature conditions. FT-IR analysis confirms successful impregnation of PSf adhesive onto PPS fabric and interaction with ePTFE support. FE-SEM images reveal improved fiber interconnection and adhesion with increased PSf concentration. PSf@PPS/ePTFE-5 exhibits the most suitable porous structure. The composite membrane demonstrates exceptional thermal stability up to 400℃. Peel resistance tests show sufficient adhesion for dust filtration, ensuring reliable performance under tough, high-temperature conditions without compromising air permeability. This membrane offers promising potential for industrial applications. Further optimizations and applications can be explored.

Hydrodynamic Characteristics of Self-expandable Graft Stents in Steady Flow (정상유동에서 자가팽창성 그래프트 스텐트의 수력학적 특성)

  • 이홍철;김철생;박복춘;박복춘
    • Journal of Biomedical Engineering Research
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    • v.24 no.1
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    • pp.37-44
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    • 2003
  • This experimental study is aimed at evaluating the hydrodynamic performance of newly designed self-expandable graft stents under steady flow condition. Two graft stents with different coating materials and a bare TiNi metallic stent for comparison test were used in the experiment. Pressure variation and velocity distribution at the upstream and downstream of the stents were measured at flow rates of 5, 10, and 15 l/min, respectively. Pressure loss due to insertion of the stent increased with increasing flow rate exponentially as expected. At a flow rate of 15 l/min, pressure loss of Polyure-thane(PU)-coated graft stent was 6 times higher than that of TiNi metallic stent, while the pressure loss of a porous Polytetrafluoroethylene(PTFE)-coated graft stent was comparable to a bare TiNi metallic stent. Velocity profiles of the porous PTFE-coated graft stent were similar to those of a bare TiNi metallic stent regardless of flow rate. Furthermore, the velocity profile of PU-coated graft stent revealed an asymmetrical and relatively low central velocity at a higher flow rate than 10 1/min, expecially, where the effects resulted in increases of wall shear stress and normal stress. The worse hydrodynamic behavior of PU-coated graft stent than the other two stents might be attributed to formation of folds due to poor flexibility of coated material when inserting the graft stent into the pipe with a more smaller size, which later gave rise non-symmetry of flow area, increase of surface roughness and jet flow via the crevice between the stent and cylinder wall.

Removal of Volatile Organic Compounds from Water Using PU/PDMS-PTFE Composite Membranes by Vapor Permeation Separation Process (PU/PDMS-PTFE 복합막을 이용한 증기투과공정에 의한 물로부터 휘발성 유기화합물 제거)

  • Rhim Ji Won;Cheon Se Won;Yun Tae Ihl;Shin Hyun Su;Kim Baek Ahm;Chung Rae Ick
    • Membrane Journal
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    • v.15 no.1
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    • pp.44-51
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    • 2005
  • Polyurethane-polysiloxanes (PU/PDMS) was synthesized using 4,4'-diphenylmethane diisocyanate (MDI) and 1,4-butanediol (BD) to overcome the weakness to the organic chemicals. The composite membranes were prepared onto porous poly(tetrafluoroethylene) (PTFE) supports. In vapor permeation experiments, the flux increased with increasing operating temperatures and feed concentrations while the separation factors showed the opposite trend, so-called 'trade-off'. In this study, the effect of the flux on the operating temperatures was not severe since the content of the soft segments is fairly higher than that of the hard segments. The composite membrane type of PU/PDMS maintained high flux and separation factor as well when comparing with the dense type membranes.