• 제목/요약/키워드: porosity control

검색결과 291건 처리시간 0.029초

Effect of Strontium Carbonate Content on Flexural Strength of Clay-Based Membrane Supports

  • Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • 한국세라믹학회지
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    • 제52권6호
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    • pp.467-472
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    • 2015
  • The effect of $SrCO_3$ content on the microstructure, porosity, flexural strength, and pore size distribution of clay-based membrane supports was investigated. Green compacts prepared from low cost materials such as kaolin, bentonite, talc, sodium borate, and strontium carbonate were sintered at $1000^{\circ}C$ for 8 h in air. It was possible to control the porosity of the clay-based membrane supports within the range of 33% to 37% by adjusting the $SrCO_3$ content. The flexural strength of the clay-based membrane supports was found to strongly depend on their porosity. In turn, the porosity was affected by the $SrCO_3$ content. The average pore size and flexural strength of the clay-based membrane supports containing 4 wt% $SrCO_3$ were $0.62{\mu}m$ and 33 MPa at 34% porosity.

적층 평판형 SOFC에서 LSM 전극의 기공 제어 (Porosity Control in LSM Electrode Formation in Layered Plannar SOFC Module)

  • 이원준;여동훈;신효순;정대용
    • 한국전기전자재료학회논문지
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    • 제27권12호
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    • pp.866-870
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    • 2014
  • In solid oxide fuel cell system, yttria-stabilized zirconia is generally adopted as the electrolyte, which has high strength and superior oxygen ion conductivity, and the air electrode and the fuel electrode are attached to this. Recently, new structure of 'layered planar SOFC module' was suggested to solve the reliability problem due to the high temperature stability of a sealing agent and a binding material. In this study to materialize the air electrode in a layered planar SOFC module, the LSM ink was coated to form homogeneous electrode in the channel after the ink preparation. As the porosity control agent, PMMA or active carbon powder was adopted with use of a commercial dispersant in ethanol. The optimal amounts of both the porosity control agents and the dispersant were determined. Four (4) vol% of the dispersant for the LSM-PMMA case and 15 vol% for LSM-carbon powder showed the lowest viscosities respectively to indicate the best dispersed states of the slurries. With PMMA and carbon powder, sintered LSM ink shows the relatively homogeneous distributions of pores and with increases of the agents, the porosities increased in both cases. From this, it can be thought that the amount of the PMMA or carbon powder could be used to control the porosity of the LSM ink.

극초단파에너지에 의해 온성된 의치상용 레진의 다공성에 관한 연구 (A STUDY ON THE POROSITY OF DENTURE BASE RESINS PROCESSED BY MICROWAVE ENERGY)

  • 정창모
    • 대한치과보철학회지
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    • 제34권4호
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    • pp.816-822
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    • 1996
  • The purpose of this study was to determine whether there was any difference in the mean porosity of denture base resin cured by microwave energy, when the liquid monomers of denture resin(K-33 : methyl methacrylate for conventional water bath curing or Acron MC : special monomer for microwave curing) and/or the thicknesses of denture base($5{\times}10{\times}60mm\;or\;10{\times}10{\times}60mm$) were varied. The mean porosities of k-33 specimens cured in water bath with two different thicknesses were used as control. The results were as follows : 1. Regardless of specimen thickness, Acron MC cured by microwave energy showed the least mean porosity, followed by K-33 cured by water bath heat, and K-33 cured by microwave energy showed the highest level of mean porosity(P<0.05). 2. In both K-33 and Acron MC cured by microwave energy the mean porosities of 5mm thickness groups were lower than those of 10mm thickness groups(P<0.05). But no significant difference was found in mean porosity between 5mm thickness and 10mm thickness of water bath heat cured groups made of K-33(P>0.05).

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이축연신 PTFE 막 제조 공정에 관한 연구(I) (A Study of Bi-Axial Stretching Process for the PTFE Membrane(I))

  • 신홍철;김성철;조을룡
    • Elastomers and Composites
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    • 제42권2호
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    • pp.86-92
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    • 2007
  • 이축 연신에 의한 폴리테트라플루오르에틸렌(PTFE) 막을 제조하기 위한 공정 조건을 확립하기 위하여 상용화되는 PTFE 막 및 PTFE 미세 분말을 선택하였다. 막 제조공정에 사용 되기 위해 PTFE 미세 분말은 전처리 되었고, 첨가제와 혼합되었으며, 혼합물의 숙성, 페이스트 압출 공정, 칼렌더 가공 공정 등이 수행되었고 막의 두께 및 기공크기와 다공성을 측정하였다. 기계적 물성을 강화하기 위하여 시료의 후처리가 실시되었고, PTFE 막 제조공정을 위한 페이스트 압출 공정에서의 PTFE 분말과 첨가제의 혼합비, 숙성 시간, 숙성 온도, 압력 등에 관한 공정 조건이 확립되었고, 기공크기(pore size)와 다공성(porosity)을 조절할 수 있는 이축연신 공정에 대한 최적공정 조건도 확립하였다.

Pharmaceutical Potential of Gelatin as a pH-responsive Porogen for Manufacturing Porous Poly(d,l-lactic-co-glycolic acid) Microspheres

  • Kim, Hyun-Uk;Park, Hong-Il;Lee, Ju-Ho;Lee, Eun-Seong;Oh, Kyung-Taek;Yoon, Jeong-Hyun;Park, Eun-Seok;Lee, Kang-Choon;Youn, Yu-Seok
    • Journal of Pharmaceutical Investigation
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    • 제40권4호
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    • pp.245-250
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    • 2010
  • Porous poly(lactic-co-glycolic acid) microspheres (PLGA MS) have been utilized as an inhalation delivery system and a matrix scaffold system for tissue engineering. Here, gelatin (type A) is introduced as an extractable pH-responsive porogen, which is capable of controlling the porosity and pore size of PLGA microspheres. Porous PLGA microspheres were prepared by a water-in-oil-in-water ($w_1/o/w_2$) double emulsification/solvent evaporation method. The surface morphology of these microspheres was examined by varying pH (2.0~11.0) of water phases, using scanning electron microscopy (SEM). Also, their porosity and pore size were monitored by altering acidification time (1~5 h) using a phosphoric acid solution. Results showed that the pore-forming capability of gelatin was optimized at pH 5.0, and that the surface pore-formation was not significantly observed at pHs of < 4.0 or > 8.0. This was attributable to the balance between gel-formation by electrostatic repulsion and dissolution of gelatin. The appropriate time-selection between PLGA hardening and gelatin-washing out was considered as a second significant factor to control the porosity. Delaying the acidification time to ~5 h after emulsification was clearly effective to make pores in the microspheres. This finding suggests that the porosity and pore size of porous microspheres using gelatin can be significantly controlled depending on water phase pH and gelatin-removal time. The results obtained in this study would provide valuable pharmaceutical information to prepare porous PLGA MS, which is required to control the porosity.

Effect of Spraying Distance on Properties of $B_4C$ Coating

  • Zeng-Y;Zhang-Y.F;Huang-J.Q
    • 한국진공학회지
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    • 제7권s1호
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    • pp.179-182
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    • 1998
  • Boron carbide coating has some very attractive properties for nuclear and semiconductor industry. The potential of atmosheric plasma spray as manufacturing methods for $B_4C$ coating was discussed. In this work, the boron carbide coating with low porosity, high microhardness and good life of thermal shock resistance was deposited by the control of spraying distance. The relationship between the properties of $B_4C$ coatings and their spraying distance was studied.

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방풍벽에 의한 비산 먼지 저감 효과 (The Effects of Windbreaks on Reduction of Suspended Particles)

  • 송창근;김재진;송동웅
    • 대기
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    • 제17권4호
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    • pp.315-326
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    • 2007
  • The effects of windbreaks on the reduction of suspended particles are investigated using a computational fluid dynamics (CFD) model with the ${\kappa}-{\varepsilon}$ turbulence closure scheme based on the renormalization group (RNG) theory. In the control experiment, the recirculation zones behind the storage piles are generated and, as a whole, relatively monotonous flow patterns appear. When the windbreaks with the 0% porosity are constructed, the recirculation zones are generated by the windbreaks and very complicated flow patterns appear due to the interference between the windbreaks and storage piles. The porosity of the windbreaks suppresses the generation of the recirculation zone and decreases the wind velocity in the windbreaks as well as that outside the windbreaks. As the emission of suspended particles from the storage piles are closely related with the friction velocity at the surfaces of the storage piles, variation of the friction velocity and total amount of the emission of the suspended particles with the height and porosity of the windbreaks are investigated. The results show that higher and more porous windbreaks emit less suspended particles and that the reduction effect of the porosity is still more effective than that of the height. In the case of the windbreak with 30 m height and 50% porosity, friction velocities above the storage piles are smaller than the critical friction velocity above which particles would be suspended. As a result, total amount of suspended particles are much fewer than those in other cases.

Effects of macroporosity and double porosity on noise control of acoustic cavity

  • Sujatha, C.;Kore, Shantanu S.
    • Advances in aircraft and spacecraft science
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    • 제3권3호
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    • pp.351-366
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    • 2016
  • Macroperforations improve the sound absorption performance of porous materials in acoustic cavities and in waveguides. In an acoustic cavity, enhanced noise reduction is achieved using porous materials having macroperforations. Double porosity materials are obtained by filling these macroperforations with different poroelastic materials having distinct physical properties. The locations of macroperforations in porous layers can be chosen based on cavity mode shapes. In this paper, the effect of variation of macroporosity and double porosity in porous materials on noise reduction in an acoustic cavity is presented. This analysis is done keeping each perforation size constant. Macroporosity of a porous material is the fraction of area covered by macro holes over the entire porous layer. The number of macroperforations decides macroporosity value. The system under investigation is an acoustic cavity having a layer of poroelastic material rigidly attached on one side and excited by an internal point source. The overall sound pressure level (SPL) inside the cavity coupled with porous layer is calculated using mixed displacement-pressure finite element formulation based on Biot-Allard theory. A 32 node, cubic polynomial brick element is used for discretization of both the cavity and the porous layer. The overall SPL in the cavity lined with porous layer is calculated for various macroporosities ranging from 0.05 to 0.4. The results show that variation in macroporosity of the porous layer affects the overall SPL inside the cavity. This variation in macroporosity is based on the cavity mode shapes. The optimum range of macroporosities in poroelastic layer is determined from this analysis. Next, SPL is calculated considering periodic and nodal line based optimum macroporosity. The corresponding results show that locations of macroperforations based on mode shapes of the acoustic cavity yield better noise reduction compared to those based on nodal lines or periodic macroperforations in poroelastic material layer. Finally, the effectiveness of double porosity materials in terms of overall sound pressure level, compared to equivolume double layer poroelastic materials is investigated; for this the double porosity material is obtained by filling the macroperforations based on mode shapes of the acoustic cavity.

팽윤 능력이 다른 고흡수성수지(Super Absorbent Polymers)의 혼합 비율별 모래 토양의 물리화학성 변화 (Enhancement of Soil Physicochemical Properties by Blending Sand with Super Absorbent Polymers of Different Swelling Capacities)

  • 김영선;김태웅;김윤섭;나양호;이긍주
    • 한국환경농학회지
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    • 제42권1호
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    • pp.1-7
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    • 2023
  • Super absorbent polymers (SAPs) are hydrophilic molecules that can absorb large amounts of water. This study was conducted to investigate the enhancement of the physicochemical properties of sand soil blended with three SAPs imbibed with 100, 150, and 200-fold water. Three treatments were applied, namely, 100SAP, 150SAP, and 200SAP. The three SAPs were blended at concentrations of 0% (control), 3%, 5%, 7%, and 10% with sand. The pH, electrical conductivity, and cation exchangeable capacity (CEC) of soil blended with the three SAPs were pH 6.35-6.46, 0.09-0.65 dS/m, and 1.42-1.92 cmolc/kg, respectively, and their capillary porosity, total porosity, and saturated hydraulic conductivity were 21.0-29.3%, 39.2-48.7%, and 272-470 mm/hr. CEC, capillary porosity, total porosity, and saturated hydraulic conductivity of soil were positively correlated with the ratio of the SAPs (p<0.01). These results indicate that blending sand soil with SAPs increased CEC, capillary porosity, and saturated hydraulic conductivity, thus improving the nutrient-retention capacity, water-retention capacity, and permeability of the soil.