• Journal of the Korean Electrochemical Society
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• v.15 no.3
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• pp.149-153
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• 2012

The $Cu_2O/TiO_2$ inverse opal heterojunction arrays were developed by electrochemical deposition of $Cu_2O$ nanoparticles on $TiO_2$ inverse opal arrays. The $Cu_2O$ nanoparticles completely filled the inner pores of $TiO_2$ inverse opal film (prepared by liquid phase deposition with an average thickness of 400 nm) and covered the entire area; exhibiting high crystalline properties of anatase and cubic phase from $TiO_2$ and $Cu_2O$, respectively. From asymmetric current-voltage profile, it was noticeable that a heterojunction was well formed for charge transport from $Cu_2O$ to $TiO_2$ film resulting from the enhanced charge separation yield. In addition, increased photocurrent of 0.19 $mA/cm^2$ (versus 0.08 $mA/cm^2$ under dark condition) was obtained at -0.35 V from the heterojunction structure in the 0.5M $Na_2SO_4$ solution.

• Journal of the Korean Ceramic Society
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• v.47 no.1
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• pp.86-91
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• 2010

Among various fuel cells, solid oxide fuel cells (SOFCs) offer the highest energy efficiency, when taking into account the thermal recycling of waste heat at high temperature. However, the highest efficiency and lowest pollution for a SOFC can be achieved through the sophisticated control of its constituent components such as electrodes, electrolytes, interconnects and sealing materials. The electrochemical conversion efficiency of a SOFC is particularly dependent upon the performance of its electrode materials. The electrode materials should meet highly stringent requirements to optimize cell performance. In particular, both mass and charge transport should easily occur simultaneously through the electrode structure. Matter transport or charge transport is critically related to the configuration and spatial disposition of the three constituent phases of a composite electrode, which are the ionic conducting phase, electronic conducting phase, and the pores. The current work places special emphasis on the quantification of this complex microstructure of composite electrodes. Digitized images are exploited in order to obtain the quantitative microstructural information, i.e., the size distributions and interconnectivities of each constituent component. This work reports regarding zirconia-based composite electrodes.

• BMB Reports
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• v.38 no.5
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• pp.507-516
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• 2005

Antimicrobial peptides (AMPs) have been isolated and characterized from tissues and organisms representing virtually every kingdom and phylum. Their amino acid composition, amphipathicity, cationic charge, and size allow them to attach to and insert into membrane bilayers to form pores by 'barrel-stave', 'carpet' or 'toroidal-pore' mechanisms. Although these models are helpful for defining mechanisms of AMP activity, their relevance to resolving how peptides damage and kill microorganisms still needs to be clarified. Moreover, many AMPs employ sophisticated and dynamic mechanisms of action to carry out their likely roles in antimicrobial host defense. Recently, it has been speculated that transmembrane pore formation is not the only mechanism of microbial killing by AMPs. In fact, several observations suggest that translocated AMPs can alter cytoplasmic membrane septum formation, reduce cell-wall, nucleic acid, and protein synthesis, and inhibit enzymatic activity. In this review, we present the structures of several AMPs as well as models of how AMPs induce pore formation. AMPs have received special attention as a possible alternative way to combat antibiotic-resistant bacterial strains. It may be possible to design synthetic AMPs with enhanced activity for microbial cells, especially those with antibiotic resistance, as well as synergistic effects with conventional antibiotic agents that lack cytotoxic or hemolytic activity.

• 한국태양에너지학회:학술대회논문집
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• 2012.03a
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• pp.470-474
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• 2012

This paper deals with the thermal performances of PCM/diatomite composites for energy saving. The PCM/diatomite composites were prepared by incorporating PCMs in the pores of diatomite to increase form stability of PCMs. In experiment, we used the hexadecane, octadecane and paraffin as PCM and they have each 254.7 J/g, 247.6 J/g and 144.6 J/g of latent heat capacity, and those melting points are $20.84^{\circ}C$, $30.40^{\circ}C$ and $57.09^{\circ}C$, respectively. Thermal properties of PCM/diatomite composites were determined by using DSC. And PCM/diatomite composites were characterized by SEM and FTIR analysis. The results showed that the PCMs are well infiltrated into the structure of diatomite andt he latent heat capacity of PCM/diatomite composites was obtained by 40% of pure PCMs.

• Carbon letters
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• v.13 no.4
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• pp.254-259
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• 2012

Nanoporous non-woven carbon fibers for a gas sensor were prepared from a pitch/polyacrylonitrile (PAN) mixed solution through an electrospinning process and their gas-sensing properties were investigated. In order to create nanoscale pores, magnesium oxide (MgO) powders were added as a pore-forming agent during the mixing of these carbon precursors. The prepared nanoporous carbon fibers derived from the MgO pore-forming agent were characterized by scanning electron microscopy (SEM), $N_2$-adsorption isotherms, and a gas-sensing analysis. The SEM images showed that the MgO powders affected the viscosity of the pitch/PAN solution, which led to the production of beaded fibers. The specific surface area of carbon fibers increased from 2.0 to $763.2m^2/g$ when using this method. The template method therefore improved the porous structure, which allows for more efficient gas adsorption. The sensing ability and the response time for the NO gas adsorption were improved by the increased surface area and micropore fraction. In conclusion, the carbon fibers with high micropore fractions created through the use of MgO as a pore-forming agent exhibited improved NO gas sensitivity.

• Journal of the Korean Ceramic Society
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• v.48 no.6
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• pp.595-599
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• 2011

ALC(Autoclaved Lightweight Concrete) is produced using quartz sand, lime and cement and water. And aluminum powder is used for blowing agent. ALC is manufactured by autoclave chamber under high-temperature and high-pressure. Generally, ALC is 1/4 levels lighter than concrete and mortar, because it has a lot of pores. So density of ALC is about 0.45~0.65 g/$cm^3$. But, ALC has a weakness, typically low strength, with its porous structure. So, it is necessary to excellent strength properties for extensive apply of ALC materials in high porosity. In this study, melamine resin was used to improve the strength characteristics of ALC materials. We performed compressive and bending strength measurements. Compressive strength of ALC with 2% melamine resin increased 26.88% than 'melamine-free' ALC. Also we performed functionality evaluation such as thermal conductivity, sound absorption, and flame-resistance.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.5
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• pp.420-425
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• 2008

PMMA light guiding plate with nano-sized pattern was fabricated using anodized aluminum oxide membrane as a template for nano imprint lithography. Nano-sized pore arrays were prepared by the self-organization processes of the anodic oxidation using the aluminum plate with 99.999% purity. Since the aluminum plate has a rough surface, the aluminum plate with thickness of 1mm was anodized after the pre-treatments of chemical polishing, and electrochemical polishing. The surface morphology of the alumina obtained by the first anodization process was controlled by the concentration of electrochemical solution during the first anodization. The surface morphology of the alumina was also changed according to temperature of the solution during chemical polishing performed after first anodization. The pore widening process was employed for obtaining the one-channel with flat surface and height of the channel because the pores of the alumina membrane prepared by the fixed voltage method shows the structure of two-channel with rough surface. It is shown from SPM results that the nano-sized pattern on PMMA light guiding plate fabricated by nano imprint lithography method was well transferred from that of anodized aluminum oxide template.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.4
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• pp.218-224
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• 2016

The surface of Mg alloy, AZ31 and AZ91, were treated by PEO (plasma electrolytic oxidation) in Na-P system electrolyte, with different applied voltage and time. Thickness, roughness and X-ray crystallographic analysis revealed several results. The more applied time and voltage of PEO treated, the thicker oxidized surface coating layer were covered. And surface roughness increased with the thickness of oxidized layer. It was thought that when oxide layer grew, resistivity and breakdown voltage increased with the thickness of layer, and then, the energy of micro plasma need to be higher then before. So, it made craters and pores of surface become greater, which were responsible for the coarse surface.

• Advances in concrete construction
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• v.1 no.4
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• pp.341-358
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• 2013

Due to fast growth in urbanisation, a highly developed infrastructure is essential for economic growth and prosperity. One of the major problems is to preserve, maintain, and retrofit these structures. To meet the requirements of construction industry, the basic information on all the mechanical properties of various concretes is essential. This paper presents the details of development of various concretes, namely, normal strength concrete (around 50 MPa), high strength concrete (around 85 MPa) and ultra high strength concrete (UHSC) (around 120 MPa) including their mechanical properties. The various mechanical properties such as compressive strength, split tensile strength, modulus of elasticity, fracture energy and tensile stress vs crack width have been obtained from the respective test results. It is observed from the studies that a higher value of compressive strength, split tensile strength and fracture energy is achieved in the case of UHSC, which can be attributed to the contribution at different scales viz., at the meso scale due to the fibers and at the micro scale due to the close packing of grains which is on account of good grading of the particles. Micro structure of UHSC mix has been examined for various magnifications to identify the pores if any present in the mix. Brief note on characteristic length and brittleness number has been given.

• Journal of Korean Society for Atmospheric Environment
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• v.31 no.6
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• pp.538-547
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• 2015

Test activated carbon fiber (ACF) was prepared from Polyacrylonirile (PAN) through oxidation and chemical activation. Immersion of ACF precursors in the aqueous KOH solution enhanced the surface structure, as examined by BET pore analysis. Specific surface area increased greatly from less than $70m^2/g$ to $1226m^2/g$ with 4 M KOH, and total pore volume also rose up to $0.483cm^3/g$. In particular, it was found that micropores favorable for $CO_2$ molecule capture occupied more than 95%. Maximum $CO_2$ adsorption capacity was 3.59 mmol/g at 298 K. Low depth of pores in the present ACF may facilitate the molecules' desorption for its regeneration.