• 폴리머
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• 제37권4호
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• pp.478-485
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• 2013

본 연구에서는 식품첨가물로 승인되어 있는 생물고분자 물질을 이용하여 신속팽윤성과 고흡수성을 갖는 하이드로젤을 제조하고 팽윤특성을 분석하였다. 하이드로젤을 제조하는 과정에서 기포발생제를 이용하여 기공을 형성시켜 기존 하이드로젤의 팽윤성 향상을 시도하였고 각 하이드로젤의 평형 팽윤도, 팽윤속도 및 세포독성을 비교하였다. Alginate hydrogel에서는 digital microscope 관찰을 통해 수백 ${\mu}m$ 크기의 열린 채널로 다공성 구조를 관찰하였으며 제조된 모든 하이드로젤들은 poly(acrylic acid)에 비해 높은 세포생존율을 보였다.

• 멤브레인
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• 제17권4호
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• pp.329-337
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• 2007

본 연구에서는 p-toluenesulfonic acid (TSA)와 polyvinylpyrrolidone (PVP)를 함유한 polyethersulfone (PES) 고분자 용액을 이용하여 PES 멤브레인 내에 최소 공경을 갖는 내부 분리층을 만드는 방법에 관한 새로운 방법을 제시하고자 한다. 팽윤제로 사용된 PVP와 응고제로 사용된 TSA를 함유한 평막형 PES 멤브레인의 제조 및 구조적인 특성 조사가 수행되었으며, 상업용 막에 대등할 만한 투과 성능과 좁은 pore size distribution을 가지는 멤브레인을 제조할 수 있음을 확인하였다. 또한 PVP의 첨가는 멤브레인의 단면구조와 투과 성능에, TSA는 투과 성능보다는 pore size distribution에 영향을 준다는 것을 확인하였으며 이는 FE-SEM 결과와 TSA를 첨가한 멤브레인의 단면 사진에서 내부 최소 기공층의 두께가 두꺼워짐을 확인할 수 있었다.

• 센서학회지
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• 제21권4호
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• pp.256-262
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• 2012

Hyaluronic acid(HA) hydrogels were synthesized by immersing HA microbeads in phosphate buffered saline solutions having different pH levels to assess the effect of pH on the swelling ratio of HA hydrogels for smart drug delivery systems. No beads were formed when the HA solution(below pH 9) was crosslinked with divinyl sulfone(DVS) because DVS is a basic solution. The variation regarding the size of the microbead was not significant, suggesting that the bead size is not a function of pH(10 ~ 14). However, the pore size of the microbeads decreased with increasing pH from 10 to 14, leading to the surface smoothness and dense network as a result of higher crosslinking. The swelling ratio of hydrogels increased when the pH rose from 2(acidic) to 6(neutral). Afterwards, it decreased with further increasing pH(basic). The lower swelling ratio may be due to the lack of ionization of the carboxyl groups. On the other hand, a higher swelling ratio is likely due to the increased electrostatic repulsions between negatively charged carboxyl groups on different chains. Experimental results suggested that pH-responsive HA hydrogels can be applicable to the controlled drug delivery systems.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.557-558
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• 2006

In all conventional sintered PM products, the pores present are of two types, primary and secondary. Primary pores forming during compaction and latter during sintering, due to penetration of formed liquid through the matrix grain boundary. Effect of carbon addition on diffusion of Cu in SH737-2Cu system was investigated. After compaction and transient liquid phase sintering at $1120^{\circ}C$ and $1180^{\circ}C$, samples were characterized for densification, showing rise in sintering density and reduction in swelling on carbon addition. Quantitative microstructural characterization (shape factor and pore size) revealed bimodal distribution for 0% carbon, more rounded pores for 0.9% carbon and higher sintering temperature, and pore coarsening at higher sintering temperature.

• 한국지반공학회논문집
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• 제19권5호
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• pp.311-317
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• 2003

일정변형속도 압밀시험(CRS)을 이용하여 점성토의 팽창지수 산정 특성을 조사하였다. CRS압밀시험에서 재하단계의 변형률은 0.05%/min와 0.03%/min을 적용하였으며, 재하단계에서는 재하단계의 변형속도의 1/1, l/5, 1/10, 1/15에 해당하는 변형속도를 적용하였다. 표준압밀시험과 비교하여 팽창지수를 산정한 결과 1/5∼1/10정도의 변형속도를 적용했을 때 서로 유사한 팽창지수가 산정되었다. 또한, 유효응력과 과잉간극수압비의 관계에서 교차점이 존재함을 알았으며 이 교차점을 기준으로 변형속도에 의존적인 부분과 비의존적인 부분이 존재함을 알 수 있었다.

• Macromolecular Research
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• 제17권4호
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• pp.250-258
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• 2009

One-step seeded polymerization was used to prepare $7{\sim}10{\mu}m$ of crosslinked monodisperse spheres with four crosslinking agents using $4.68{\mu}m$ poly(methyl methacrylate)(PMMA) seed particles in aqueous-alcoholic media in the absence of the swelling process. The crosslinking agents used were ethylene glycol dimethacrylate(EGDMA), allyl methacrylate(AMA), 1,6-hexanediol diacrylate(HDDA) and trimethylolpropane trimethacrylate(TMPTMA). The effects of the type and concentration of the crosslinking agents on the swelling, pore size, thermal property of the networks and morphology of the particles were studied. The chemical structures and concentrations of the crosslinking agents affected both the swelling ratio and the porosity of the networks. In addition, the chemistry of the reactive vinyl group and chain length of the crosslinking agents affected the stability of the monodisperse particles of the ultimate morphology.

• 멤브레인
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• 제25권2호
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• pp.171-179
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• 2015

과불소계 술폰화 이오노머(perfluorinated sulfonic acid ionomers; PFSAs)는 뛰어난 수소이온전도성과 높은 내화학성으로 인해 고분자 전해질 연료전지(polymer electrolyte fuel cells)용 고체전해질로 널리 사용되고 있다. 그러나 PFSA 전해질은 가습-건조조건에서 연료전지가 구동에 따라 반복적인 팽윤-수축으로 인해 전극층이 전해질로부터 탈리되어 전기화학적 수명특성이 감소되는 문제점을 가지고 있다. 본 연구에서는 다공성 PTFE support film의 기공특성에 대한 이해를 바탕으로 기공구조 내 나피온 이오노머를 함침시키는 강화막을 제조하였고, 기본특성을 평가하였다. 제조된 강화막은 매우 높은 수소이온전도도(${\sim}~0.5S\;cm^{-1}@90^{\circ}C$ in liquid water)를 나타내었다.

• 한국세라믹학회지
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• 제30권11호
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• pp.881-890
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• 1993

MAS system has narrow sintering temp. range due to the liquid phae sintering and thereby densify rapidly. And especially, its poor mechanical properties limitedthe industrial application. In this study, the improvement of mechanical properties and densification is suggested by the consideration of the toughening mechanisms and isolated pore generation mechanism which is derived by the liquid phase sintering theory in 3Y-TZP added composites. After Pressureless sintering up to 140$0^{\circ}C$ for 5hr, the dihedral angle and contact angle are analyzed by the observation of microstructure. As a result of microstructure analysis, the sintering stage of the specimen sintered for 5hr is analyzed as solid-skeleton stage. And the isolated pore generation mechanisms are considered as (1) The swelling of the liquid phase is predominent due to the facts that dihedral angle is larger than 60$^{\circ}$, contact angle is large and that liquid volume fraction is smaller than 10%. (2) The porous characteristics of the MAS system is also suggested as: the SiO2-rich liquid film is firstly formed at the srface and therefore this reduces the contiguity of the pore, which induces the isolated pore. The strength and fracture toughness increased with the addition of 3Y-TZP and the main fracture toughness improvement mechanisms are analyzed as the crack deflection.

• 한국환경복원기술학회지
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• 제3권1호
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• pp.52-61
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• 2000

Permeability is important factor in the geotechnical problems, such as seepage discharge and dissipation of excess pore water pressure. The Kozeny-Carman equation works well for graded soils but serious discrepancies are found in clays. Major factor for these discrepancies is the tortuous flow path and unequal pore size. To estimate the permeability of fine grained soils, a permeability equation in which swelling potential is coupled with Kozeny-Carman equation is proposed in this study. To verify proposed equation, a series of variable head permeability test was carried out for steel making slag and sludge mixed with bentonite. The coefficients of permeability which is measured in the laboratory is compared with the values by the proposed equation. From the comparison, it is shown that the proposed equation can predict the coefficient of permeability of clays with satisfaction. As steel making slag and sludge is industry waste, it is reused as material of road foundation and cement but the rate of use is low. It mixed sodium-bentonite with high swelling property and permeability decrease effect. Then, Admixture investigates reuse possibility as liner of waste fill.

• 한국식품조리과학회지
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• 제18권4호
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• pp.381-389
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• 2002

The purpose of this study was to select an ingredient acting as a natural emulsifier to retard the retrogradation of rice cake by the measurement of mechanical characteristics of the cakes. For the purpose, Backsulgi, the most basic type of rice cake, was prepared by adding various ingredients having high contents of lecithin such as raw soybean powder, parched soybean powder, soybean oil, egg yolk powder, and the measurements and observations on the chromaticity, swelling power, pore ratio and cross-section were made. In addition, changes in the textural characteristics of Backsulgi samples were determined while storing them at the temperatures of 4$^{\circ}C$ and 20$^{\circ}C$ for 0, 1, 2 and 3 days. The results of the study were as follows: 1. In terms of chromaticity, the Backsulgi samples added with egg yolk powder, raw soybean flour and parched soybean flour were higher in yellowness(b) than the controls. 2. Both swelling power and pore ratio of Backsulgies added with raw soybean flour were higher than those of controls. 3. A cross-sectional observation using an electron microscope indicated that rice flour particles of controls had uneven pores and were conglomerated in a large lump while Backsulgi samples of raw soybean flour or roasted soybean flour had large and even pores and showed loosened bonding to be transformed into a sponge shape. 4. In hardness, Backsulgi samples added with raw soybean flour had less changes in hardness than that of controls, indicating that the effect of retarding retrogradation was higher when the storage time got longer.