• Title/Summary/Keyword: pore size distributions

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Numerical Simulation of Interaction between Composite Breakwater and Seabed under Regular Wave Action by olaFlow Model (olaFlow 모델에 의한 규칙파작용 하 혼성방파제-해저지반의 상호작용에 관한 수치시뮬레이션)

  • Bae, Ju-Hyun;Lee, Kwang-Ho;Jung, Uk Jin;Kim, Do-Sam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.6
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    • pp.270-285
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    • 2018
  • The behavior of wave-induced pore water pressure inside the rubble mound and seabed, and the resultant structure failure are investigated, which are used in design of the composite breakwater representing the coastal and harbor structures. Numerical simulation techniques have been widely used to assess these behaviors through linear and nonlinear methods in many researches. While the combination of strongly nonlinear analytical method and turbulence model have not been applied yet, which can simulate these characteristics more accurately. In this study, olaFlow model considering the wave-breaking and turbulent phenomena is applied through VOF and LES methods, which gives more exact solution by using the multiphase flow analytical method. The verification of olaFlow model is demonstrated by comparing the experimental and numerical results for the interactions of regular waves-seabed and regular waves-composite breakwater-seabed. The characteristics of the spatial distributions of horizontal wave pressure, excess-pore-water pressure, mean flow velocity and mean vorticity on the upright caisson, and inside the rubble mound and seabed are discussed, as well as the relation between the mean distribution of vorticity size and mean turbulent kinetic energy. And the stability of composite breakwater are also discussed.

Comparison of Correlation between Chloride Diffusion and Pores Characteristics in Concrete Cured under Extreme Condition (가혹 조건에서 양생된 콘크리트의 염화물 확산과 공극 특성의 상관관계 비교 )

  • So Yeong Choi;Seong Joon Yang;Il Sun Kim;Eun Ik Yang
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.54-61
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    • 2023
  • In this paper, the compressive strength, pore characteristics, and chloride diffusion coefficient were measured at 28 days of age in order to examine the influence of curing conditions for the chloride diffusion and pores in concrete cured under extreme condition. According to the test results, the compressive strength was improved as the relative humidity increased. Additionally, higher compressive strength was observed when the specimens were cured at 35℃. However, the compressive strength of specimens cured at 45℃ was decreased. Meanwhile, the chloride diffusion coefficient decreased with an increase in curing temperature and relative humidity, indicating a difference compared to the trend observed for compressive strength. On the other hand, the excellent correlation showed between compressive strength and chloride diffusion coefficient, porosity and chloride diffusion coefficient when the concrete cured under water. However, when the concrete cured under extreme condition, this correlation was significantly reduced compared to the water curing case. In contrast, it has been determined that there is no significant correlation between the average pore size and chloride diffusion coefficient, regardless of the curing conditions.

Effects of Pressure-shift Freezing on the Structural and Physical Properties of Gelatin Hydrogel Matrices

  • Kim, Byeongsoo;Gil, Hyung Bae;Min, Sang-Gi;Lee, Si-Kyung;Choi, Mi-Jung
    • Food Science of Animal Resources
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    • v.34 no.1
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    • pp.33-39
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    • 2014
  • This study investigates the effects of the gelatin concentration (10-40%, w/v), freezing temperatures (from $-20^{\circ}C$ to $-50^{\circ}C$) and freezing methods on the structural and physical properties of gelatin matrices. To freeze gelatin, the pressure-shift freezing (PSF) is being applied at 0.1 (under atmospheric control), 50 and 100 MPa, respectively. The freezing point of gelatin solutions decrease with increasing gelatin concentrations, from $-0.2^{\circ}C$ (10% gelatin) to $-6.7^{\circ}C$ (40% gelatin), while the extent of supercooling did not show any specific trends. The rheological properties of the gelatin indicate that both the storage (G') and loss (G") moduli were steady in the strain amplitude range of 0.1-10%. To characterize gelatin matrices formed by the various freezing methods, the ice crystal sizes which were being determined by the scanning electron microscopy (SEM) are affected by the gelatin concentrations. The ice crystal sizes are affected by gelatin concentrations and freezing temperature, while the size distributions of ice crystals depend on the freezing methods. Smaller ice crystals are being formed with PSF rather than under the atmospheric control where the freezing temperature is above $-40^{\circ}C$. Thus, the results of this study indicate that the PSF processing at a very low freezing temperature ($-50^{\circ}C$) offers a potential advantage over commercial atmospheric freezing points for the formation of small ice crystals.

Hydration and Carbonation Properties of Different Hydraulic Lime (수경성석회 종류에 따른 수황 및 탄산화 특성)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Kye-Hong;Cho, Jin-Sang;Ahn, Ji-Whan;Yeon, Kyu-Seok
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.72-81
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    • 2014
  • The main mineral phases of natural hydraulic lime (NHL) as a hydraulic lime binderare $Ca(OH)_2$, $C_2S$, $C_3S$, $C_3A$, and $SiO_2$ residues. Also, NHL has the characteristic of setting and hardening by a hydration reaction with water and by carbonation reactions with carbon dioxide from the air. In this study, in an effort to investigate changes of the mineral phases by NHL hydration and carbonation reactions, transitions of mineral phases and the microstructures of hardened pastes were analyzed by XRD, DSC, SEM, and by pore size distributions using domestic and foreign-sourced NHL pastes after curing at 1, 3, 7, and 28 days. On the basis of the analysis results, it was confirmed that domestic low-grade limestone can be used for the manufacturing of NHL. The main hydration mineral phases were $Ca(OH)_2$, $CaCO_3$, $C_2S$, and $SiO_2$ residues, while in the case of foreign-sourced NHL, a small amount of an aluminium hydration phase formed. Also, the $CaCO_3$ content after the carbonation reaction increased with an increase in the curing time. After hydration for 28 days, NHL containing considerable amounts of $C_2S$ and $C_3S$ showed higher carbonation ratios than others types.

Acoustic Abosrption Characteristic and Fabrication process of Foamed Aluminum (발포알루미늄의 제조공정 및 흡음특성)

  • Hur, Bo-Young;Ahn, Hyo-Jun;Jeon, Sung-Hwan;Choi, Dae-Choul;Kim, Sang-Youl;Hur, Yoon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.11a
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    • pp.396-402
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    • 2000
  • Porous structures of aluminum foam have been studied. The apparent foam shape, foam hight, density, pore size, shape, and their distributions in various section areas of the experimental samples have been investigated. The sample have been cast into metallic mold, using aluminum foam prepared from a precursor based on pure Al ingot mixed with various amount of 1-2wt% increasing viscosity and foam agent materials. The process provides for flexibility in design of foam structures via relatively easy control over the amount of hydrogen evolution and the drainage processes which occur during foam formation. This is facilitated by manupulating parameters such as the foaming agent, thermal histories during solidification and mix melt viscosities. The acoustical performance of the panel made with the foamed aluminum is considerably improved; its absorption coefficient shows NRC 0.6-0.8. It has been found that the Al foam is very preferable for the compactness of the thermal system.

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Analysis of Quartz Contents by XRD and FTIR in Respirable Dust from Various Manufacturing Industries Part 2 - Ceramics, Stone, Concrete, Glass and Briquets, etc. (제조업체에서 발생하는 호흡성분진중 XRD와 FTIR를 이용한 결정형유리규산 농도의 분석 제2부 : 요업, 석재, 콘크리트, 유리, 연탄 및 기타사업장)

  • Kim, Hyunwook;Phee, Young Gyu;Roh, Young Man;Won, Jeoung Il
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.9 no.1
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    • pp.99-111
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    • 1999
  • The purpose of this study was to evaluate crystalline silica contents in airborne respirable dusts from various manufacturing industries and to compare analytical ability of two different methods of quantifying crystalline silica, X-ray diffraction(XRD) and Fourie transform infrared spectroscopy(FTIR). Various manufacturing industries with a history of having pneumoconiosis cases and also known to generate dusts containing crystalline silica were investigated. These industries include: ceramics, brick, concrete, and abrasive material etc. The personal respirable dust samples were collected using l0mm, Dorr-Oliver nylon cyclone equipped with 37mm, $5{\mu}m$ pore size. polyvinylchloride (PVC) filters as collection media. All samples were weighed before and after sampling and were pretreated according to the NIOSH sampling and analytical methods 7500, and 7602 for dust collection and quartz analysis. A total of 48 samples were collected from these industries. Initial analyses of these samples showed log-normal distributions for dust and quartz concentrations. Some results from ceramics and stone exceeded current Korean Occupational Exposure Limits. The average concentrations of personal respirable dust by cyclone were 0.43, 0.24, 0.26, 0.42, 0.53 and $0.29mg/m^3$ in ceramics, stone, concrete, glass, briquets, and others, respectively. A comparison of performance of two analytical methods for quantifying crystalline silica was performed using data from ceramics. The results showed that no significant difference was found between two methods for ceramics. The mean crystalline silica contents determined by XRD were 3.41 % of samples from briquets and 7.18 % from ceramics and were 2.58 % from concrete and 10.33 % from ceramics by FTIR. For crystalline silica analysis, two analytical techniques were highly correlated with $r^2=0.81$ from ceramics. Both cristobalite and tridymite were not detected by XRD and FTIR.

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Synthesis of Chromium Nitride and Evaluation of its Catalytic Property (크롬 질화물(CrN)의 합성 및 촉매특성에 관한 연구)

  • Lee, Yong-Jin;Kwon, Heock-Hoi
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.451-457
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    • 2006
  • We synthesized phase pure CrN having surface areas up to $47m^2/g$ starting from $CrCl_{3}$ with $NH_{3}$. Thermal Gravimetric Analysis coupled with X-ray diffraction was carried out to identify solid state transition temperatures and the phase after each transition. In addition, the BET surface areas, pore size distributions, and crystalline diameters for the synthesized materials were analyzed. Space velocity influenced a little to the surface areas of the prepared materials, while heating rate did not. We believe it is due to the fast removal of reaction by-products from the system. Temperature programmed reduction results revealed that the CrN was hardly passivated by 1% $O_{2}$. Molecular nitrogen was detected from CrN at 700 and $950^{\circ}C$, which may be from lattice nitrogen. In temperature programmed oxidation with heating rate of 10 K/min in flowing air, oxidation started at or higher than $300^{\circ}C$ and resulting $Cr_{2}O_{3}$ phase was observed with XRD at around $800^{\circ}C$. However the oxidation was not completed even at $900^{\circ}C$. CrN catalysts were highly active for n-butane dehydrogenation reaction. Their activity is even higher than that of a commercial $Pt-Sn/Al_{2}O_{3}$ dehydrogenation catalyst in terms of volumetric reaction rate. However, CrN was not active in pyridine hydrodenitrogenation.

Isolation of Marine Bacteria Killing Red Tide Microalgae I. Isolation and Algicidal Properties of Micrococcus sp. LG-1 Possessing Killing Activity for Harmful Dinoflagellate, Cochlodinium polykrikoides (적조생물 살조세균 탐색 I. 유해 적조생물 Cochlodinium Polykrikoides 살조세균 Micrococcus sp. LG-1의 분리와 살조특성)

  • PARK Young-Tae;PARK Ji-Bin;CHUNG Seong-Youn;Song Byung-Chul;LIM Wol-Ae;KIM Chang-Hoon;LEE Won-Jae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.767-773
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    • 1998
  • In this study, we have investigated the distributions and killing effects of marine bacteria that tend to kill the red tide microalgae, C. polykikoides in the area of Masan bay from June to October, 1996. To summarize, C. polykikoides killing bacteria were detected at $10^2$ to $10^3$ cells/ml of seawater samples during the survey period, and the bloom was observed in September by containing $4.8\times10^3$cells/ml. It appears however that the number of these bacteria is decreased ($2.0\times10^2$cells/ml) in October, A total of 110 strains were isolated from seawater samples and seawater filtrate (pore size, 0.8 $\mu$m)-containing mixed culture of C. polykikoides in which the mixed culture was grown in f/2 medium. As results we have successfully isolated Micrococcus sp. LG-1 which decreased to less than 10cells/ml within 6days and 5days sfter inoculation of Micrococcus sp. LG-1 into the la9 and logarithmic growth phases of C. polykrikoides respectively. Therefore, it appears that inoculation of Micrococcus sp. LG-1 against the logarithmic C. polykrikoides is more effective than the lag growth phase, (n addition, the killing effects were increased in accordance with bacterial cell densities inoculated in a dose dependent manner. Especially, the filtrate of kitling bacterium culture (nore size, 0.2 $\mu$m) revealed a dramatic effect in which C. polykrikoides were decreased to less than 10 cells/mf of culture within 1 hr, 1,5 hrs, 1,5 hrs, 3.5 hrs. and 5,5 hrs after inoculations of the culture filtrate with concentration of $30\%,\;20\%,\;10\%,\;5\%$ and $2.5\%$, respectively. Moreover Micrococcus sp. LG-1 showed a selective specificity against C. polykrikoides and any other killing effects of Micrococcus sp. LG-1 were not observed against Alexandrium tamarense, Prorocentrum micans, Scrippsiella trochoidea. ana Gymnodinium sanguineum.

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