• Journal of the Korea Concrete Institute
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• v.15 no.2
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• pp.345-351
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• 2003

The transport characteristics of deleterious ions such as chlorides depend on the pore structures of concrete and are the major factors in the durability of concrete structures in subjected to chloride attack such as in marine environments. In this paper, the effect of the pore structure on compressive strength and chloride diffusivity of concrete was investigated. Six types of concretes were tested. The pore volume of concrete containing mineral admixtures increased in the range of 3∼30nm due to micro filling effect of hydrates of the mineral admixtures. There was a good correlation between the median pore diameter, the pore volume above 50nm and compressive strength of concrete, but there was not a significant correlation between the total pore volume and compressive strength. The relationship between compressive strength and chloride diffusivity were not well correlated, however, pore volume above 50nm were closely related to the chloride diffusion coefficient.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.711-714
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• 2003

Factors causing deterioration of concrete structures under marine environment are various, especially penetration and diffusion of chloride ion, carbon dioxide, and water through pore effects on the durability of concrete as well as mechanical properties of concrete. Pore of porous materials like concrete can be classified as micro-, meso-, and macro-pore. And pore of cement matrix is classified as pore which occupied by water, air void, and ITZ between cement paste and aggregates. In this study, to verify the relationship between pore of cement matrix and the property of chloride ion diffusivity, the regression analysis is producted. From the result of regression analysis, the average pore diameter more than total pore volume effects on the diffusivity of chloride ion.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.87-92
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• 2002

At present, the polymer-modified mortars are used as high-performance as well as multi-functional materials in the construction industry. The purpose of this study is to synthesize polymer to modify in cement mortars and make test samples to understand pore size distribution. This paper deals with the effect of monomer ratio on the typical properties of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate(MMA/BA) latexes synthesized through emulsion polymerization. From the results, we knew that the pore volume of polymer-modified mortars using Methylmethacrylate-Butyl Acrylate latexes at bound MMA contents of 70 and 60 percent is 7.5-75cm$^3$/g and the fine pore volume is increased with an increase in the polymer-cement ratio. The total pore volume of polymer-modified mortars using MMA/BA latexes is linearly reduced with an increase in the bound MMA content and increased in the polymer-cement ratio.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.10a
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• pp.365-368
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• 2002

This paper considers transference number in calculating diffusion coefficient of chloride ions of concrete and mercury intrusion porosimetry to investigate the volume and distribution of pore size, respectively, analyzing and discussing the property of resistance to chloride ion of concrete with granulated blast furnace slag. The experimental results show that the diffusion coefficient of chloride ion decreases with the rise of quantity of granulated blast furnace slag and pore structure of concrete with granulated blast furnace slag is different from that of OPC concrete. And from the results of regression analysis, the result showed that the diffusion coefficient of chloride ions is affected by capillary pore above 50nm.

• Computers and Concrete
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• v.4 no.2
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• pp.157-166
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• 2007

The paper considers a theoretical model to study sulfate ion diffusion in saturated porous media - cement based mineral composites, accounting for simultaneous effects, such as filling micro-capillaries (pores) with ions and chemical products and liquid push out of them. Pore volume change and its effect on the distribution of ion concentration within the specimen are investigated. Relations for the distribution of the capillary relative radius and volume within the composite under consideration are found. The numerical algorithm used is further completed to consider capillary size change and the effects accompanying sulfate ion diffusion. Ion distribution within the cross section and volume of specimens fabricated from mineral composites is numerically studied, accounting for the change of material capillary size and volume. Characteristic cases of 2D and 3D diffusion are analyzed. The results found can be used to both assess the sulfate corrosion in saturated systems and predict changes occurring in the pore structure of the composite as a result of sulfate ion diffusion.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.233-238
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• 2006

In lifetime estimation, the FEM analysis method is proposed for predicting corrosion failure time of concrete structures exposed to sea-water. This study shows that the corrosion rate of rebar in artificial pore solution can be transferred to the corrosion rate of rebar in concrete using the relationship between pore volume and concrete volume by Jennings' model. And this study considered the pitting corrosion effects of reinforcement bar on corrosion failure analysis, rebar size to cover depth and nonlinear crack analysis. These analysis results have good accordance with the experimental results of Williamson's work. This methodology can be applied to lifetime prediction procedure of reinforced concrete structures and also gives more reasonable results of concrete cover failure time estimation of reinforced concrete structures exposed to sea-water.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.4
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• pp.67-74
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• 2015

In this study, effects of micropores on the freezing-thawing resistance of high volume slag concrete are reviewed. Concrete was made with slag which contains the ground granulated blast furnace slag(GGBS) and the pig iron preliminary treatment slag(PS) by replacing 0, 40, 70 %, then compressive strength, freezing-thawing resistance, micropores were reviewed. Also, specified design strength, target air contents were set. Deterioration was induced by using 14-day-age specimen which has low compressive strength for evaluating deterioration by freeze-thawing action. As results of the experiment, despite of specified design strength which has been set similarly and ensured target air contents, the pore size distribution of the concrete showed different results. Micropores in GGBS70 specimen have small amount of water which is likely to freeze because there is small amount of pore volume of 10~100 nm size at 0 cycle which has not been influenced by freezing-thawing. For these reasons, it was confirmed that the freezing-thawing resistance performance of GGBS70 is significantly superior than other specimens because relatively small expansion pressure is generated compared to the other specimens.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.979-984
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• 1997

Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.1066-1072
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• 1999

The physical properties of polymer concrete were investigated for development of high-performance construction materials. Various specimens of polymer concrete were prepared using unsaturated polyester resin as the polymer-binder with the various dosage of calcium carbonate as microfiller (5~20 wt %) and fine aggregate(10~50 wt %). For the evaluation of the physical properties of polymer concretes, tests such as compressive strength, flexural strength, water absorption test, hot water immersion test, acid resistance test and pore size distribution analysis were conducted. As a result, it is concluded that compressive and flexural strengths of polymer concretes increased up to 4 times than those of conventional cement concrete. Whereas the compressive and flexural strengths of polymer concretes tested after hot water immersion, compared with those of polymer concretes tested before hot water immersion, decreased about 67%, 47%, respectively. By hot water immersion, total pore volume and porosity(%) of polymer concretes were remarkable increased due to decomposition of polymer binder. And also, it is showed that water absorption(%) and weight loss(%) of polymer concrete specimens by acid immersion, compared with those of ordinary portland cement concrete, decreased about 1/100, 1/27, respectively.

• Advances in concrete construction
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• v.4 no.2
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• pp.71-88
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• 2016

Metakaolin, a dehydroxylated product of the mineral kaolinite, is one of the most valuable admixtures for high-performance concrete applications, including constructing reinforced concrete bridges and impact- and fire-resistant structures. Concretes produced using metakaolin become more homogeneous and denser compared to normal-strength concrete. Yet, these changes cause a change of volume throughout hardening, and increase the brittleness of hardened concrete significantly. In order to examine how the use of metakaolin affects the fracture and mechanical behavior of high-performance concrete we produced concretes using a range of water to binder ratio (0.42, 0.35 and 0.28) at three different weight fractions of metakaolin replacement (8%, 16% and 24%). The results showed that the rigidity of concretes increased with using 8% and 16% metakaolin, while it decreased in all series with 24% of metakaolin replacement. Similar effect has also been observed for other mechanical properties. While the peak loads in load-displacement curves of concretes decreased significantly with increasing water to binder ratio, this effect have been found to be diminished by using metakaolin. Pore structure analysis through mercury intrusion porosimetry test showed that the addition of metakaolin decreased the critical pore size of paste phases of concrete, and increasing the amount of metakaolin reduced the total porosity for the specimens with low water to binder ratios in particular. To determine the optimal values of water to binder ratio and metakaolin content in producing high-strength and high-performance concrete we applied a multi-objective optimization, where several responses were simultaneously assessed to find the best solution for each parameter.