• Advances in nano research
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• 제4권4호
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• pp.295-307
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• 2016

The present research work reports a low temperature ($40^{\circ}C$) chemical precipitation technique for synthesizing hydroxyapatite (HAp) nanoparticles of spherical morphology through a simple reaction of calcium nitrate tetrahydrate and di-ammonium hydrogen phosphate at pH 11. The crystallinity of the single-phase nanoparticles could be improved by calcinating at $600^{\circ}C$ in air. Thermogravimetric and differential thermal analysis (TG-DTA) revealed the synthesized HAp is stable up to $1200^{\circ}C$. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) studies confirmed the formation of spherical nanoparticles with average size of $23.15{\pm}2.56nm$ and Ca/P ratio of 1.70. Brunauer-Emmett-Teller (BET) isotherm of the nanoparticles revealed their porous structure with average pore size of about 24.47 nm and average surface area of $78.4m2g^{-1}$. Fourier transform infrared spectroscopy (FTIR) was used to confirm the formation of P-O, OH, C-O chemical bonds. Cytotoxicity and MTT assay on MG63 osteogenic cell lines revealed nontoxic bioactive nature of the synthesized HAp nanoparticles.

• 한국결정성장학회지
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• 제5권1호
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• pp.44-49
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• 1995

6H - SiC를 승화법(Sublimation Process)으로 성장하였으며, 성장 결정의 표면에서 나타난 양상에 대하여 광학 현미경을 이용하여 관찰하였다. 6H-SiC는 측면방향(Hexagonal system에서 a축 방향)으로 성장하는 속도가 seed 방향인 c축 방향보다 빠르고, 따라서 많은 성장 step을 관찰할 수 있었다. 또한, SiC 결정의 주된 결함인 micropipe는 성장 후 결정의 표면까지도 형성되고 있어, 거대한 void로 관찰되어졌다. 이것은 pore와는 다르게 구별되며, 완전한 구형의 단면을 가진다. 본 연구에서는 micropipe 및 면결함, 그리고 결정성장시의 step 형성등의 현상에 대하여 광학 현미경으로 조사형 그 결과를 보고하기로 한다.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.143-148
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• 2013

Novel titanium containing solid core mesoporous shell silica has been synthesized by using octadecyltrichloro silane and triethylamine. The synthesized material was characterized by various physicochemical techniques. The mesoporous character of the material has been revealed from PXRD studies. The presence of octadecyltrichloro silane and triethylamine in the sample has been confirmed from EDAX studies. TG/DTA analysis reveals the thermal characteristics of the synthesized material. The presence of titanium in the frame work and its coordination state has been studies by UV-vis DR studies and XPS analysis. Chemical environment of Si in the framework of the material has been studied by $^{29}SiMASNMR$ studies. The surface area of the material is found to be around $550\;m^2g^{-1}$ and pore radius is of nano range from BET analysis. The spherical morphology and particle size of the core as well as shell has been found to be 300 nm and 50 nm respectively from TEM analysis. The catalytic application of this material towards the synthesis of caprolactam from cyclohexanone in presence of hydrogen peroxide through ammoxidation reaction has been investigated. The optimum conditions for the reaction have been established. The plausible mechanism for the formation of core silica and conversion of cyclohexanone has been proposed.

• 한국재료학회지
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• 제18권3호
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• pp.163-168
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• 2008

The morphology of three-dimensional (3D) cross-linked electrodeposits of copper and tin was investigated as a function of the content of metal sulfate and acetic acid in a deposition bath. The composition of copper sulfate had little effect on the overall copper network structure, whereas that of tin sulfate produced significant differences in the tin network structure. The effect of the metal sulfate content on the copper and tin network is discussed in terms of whether or not hydrogen evolution occurs on electrodeposits. In addition, the hydrophobic additive, i.e., acetic acid, which suppresses the coalescence of evolved hydrogen bubbles and thereby makes the pore size controllable, proved to be detrimental to the formation of a well-defined network structure. This led to a non-uniform or discontinuous copper network. This implies that acetic acid critically retards the electrodeposition of copper.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.354-355
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• 2006

We manufactured photoelectrode of dye-sensitized solar cells (DSC) by using three methods such as squeeze method, spray method, and combination method (squeeze method first, spray method second). We examined how the morphology of an electrode's surface, the pore between particles, and condensation have an effect on an open-circuit voltage, photocurrent, fill factor, and energy conversion efficiency. Open-circuit voltage of dye-sensitized solar cells manufactured by using three methods is about 0.66V when the photoelectrode of the three DSCs is about $5{\mu}m$ thick. Photocurrent and fill factor and conversion efficiency of DSC manufactured by using squeeze method is 18.5 and 34 and 7.8, respectively. Photocurrent and fill factor and conversion efficiency of DSC manufactured by using spray method is 3.62 and 62 and 2.8, respectively. Photocurrent and fill factor and conversion efficiency of DSC manufactured by using combination method is 10.7 and 46 and 5.9, respectively. In conclusion, we find that the combination method is better than the other two methods in such respects as energy conversion efficiency and fill factor.

• 한국산업융합학회 논문집
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• 제23권4_2호
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• pp.669-674
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• 2020

Liquid-phase-sintered (LPS) SiC materials were briefly examined with their microstructure and mechanical property. Especially, effect of high-temperature exposure on the tendency of fracture toughness of LPS-SiC were introduced. The LPS-SiC was fabricated in hot-press by sintering powder mixture of sub-micron SiC and sintering additives of Al₂O₃-Y₂O₃. LPS-SiC represented dense morphology and SiC grain-growth with some amount of micro-pores and clustered additives as pore-filling. The strength of LPS-SiC might affected by distribution of micro-pores. LPS-SiC tended to decrease fracture toughness depending on increasing exposure temperature and time.

• 대한금속재료학회지
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• 제46권6호
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• pp.370-376
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• 2008

The formation of anodic oxide film of titanium (Ti) was studied at a variety of electrolyte concentrations and current density to clarify their effects on morphology, microstructure and composition of Ti oxide layer. For the analysis of the Ti oxide films, a scanning electron microscopy (SEM), X-ray diffractometer (XRD), and X-ray photoelectron spectroscopy (XPS) were used. The results showed that the concentration of phosphoric acid played a crucial role in the crystalline structure of the Ti oxide layer while the current density gave a critical effect on the thickness and diameter of its pore. In particular, the crystalline anatase phase with a thickness larger than $2{\mu}m$, which is quite desirable for a dental implant application, could be readily prepared at the phosphoric acid concentration of 0.5 M and current density higher than $2.0A/dm^2$.

• Advances in concrete construction
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• 제5권5호
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• pp.423-436
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• 2017

Today, pozzolans are widely used in construction for various reasons such as technical and economic efficiency. In this research, in order to evaluate some of important properties of concrete, silica fume and fly ash have been used as a replacement for cement in different mass percentages. Concrete mixtures were made from a water-cement ratio of (0.45) and cured under similar conditions. The main focus of this study was to evaluate the permeability and mechanical properties of concrete made from binary and ternary cementitious mixtures of fly ash and silica fume. In this study permeability of concrete was studied by evaluating the sorptivity, water absorption, water penetration depth, electrical resistivity and rapid chloride permeability (RCP) tests. Mechanical properties of concrete were evaluated with compressive strength, splitting tensile strength and modulus of elasticity. Scanning electronic microscopy (SEM) was used to characterize the effects of silica fume and fly ash on the pore structure and morphology of concrete with cement based matrix. The results indicated that the incorporation of silica fume and fly ash increased the mechanical strength and improved the permeability of concrete.

• 한국표면공학회지
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• 제54권4호
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• pp.209-214
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• 2021

As coffee consumption per person increases annually to 323 cups in 2018, treating the spent coffee ground has arisen because spent coffee ground results in soil and air pollution. The demands of air purification filters are increasing more and more because the air pollution due to the fine dust has become worse. The spent coffee grounds had a porous structure, however, the pore was blocked by organic oil compounds. Electrocoagulation, which is one of the electrochemical methods, has the potential to remove the organic compounds. The surface area of spent coffee grounds increased effectively after the electrocoagulation treatment, and surface morphology and surface area were confirmed using SEM and BET, respectively. Using the FT-IR, both the spent coffee grounds and the electrocoagulated spent coffee grounds were characterized. The filter characteristics were examined by the adsorption test using formaldehyde, one of the air pollutants.

• 한국초전도ㆍ저온공학회논문지
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• 제8권1호
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• pp.5-8
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• 2006

The growth properties of MOD-YBCO films were investigated. To enhance the growth rate of YBCO layer and inhibit the build-up of HF gas during the annealing process in TFA-MOD for YBCO coated conductors the method of low pressure annealing was employed. Total pressure was changed from 700Torr to 1Torr and its effect on growth of YBCO films was compared with atmospheric one. The lower Pressure was effective to control of the pore size in MOD method . Surface morphology of YBCO films processed at low total pres sure was rough and composed of random YBCO (103) grains. But large pores, usually observed at atmospheric process in MOD disappeared and also the number of pores was reduced at low pressure annealing. Also discussed ate the effects of Fluorine-free Y and Cu precursor solution on the development of microstructure. Dense surface me phology and with less and small pores can be provided through controlling Fluorine content.