• Title/Summary/Keyword: pore formation

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Effect of Ca Implantation on the Sintering and Crack Healing Behavior of High Purity Al2O3 Using Micro-lithographic Technique - I. Formation of Crack-like Pore and Its Morphological Evolution (Ion Implantation으로 Ca를 첨가한 단결정 Al2O3의 Crack-like Pore의 Healing 거동 - I. Crack-like Pore의 형성과 Morphological Evolution)

  • 김배연
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.834-842
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    • 1997
  • Controlled Ca impurity implanted inner crack-like pore in the high purity alumina single crystal, sapphire, had been created by micro-fabrication technique, which includes ion implantation, photo-lithography, Ar ion milling, and hot press technique. The morphological change and the healing of cracklike pore in Ca doped high purity single crystal alumina, sapphire, during high temperature heat treatment in vacuum were observed using optical microscopy. The dot-like surface roughening was developed and hexagon like crystal appeared on inner surface of crack-like pore after heat treatment. Bar type crystals, probably CaO.6Al2O3, were observed on the inner surface after 1 hour heat treatment at 1, 50$0^{\circ}C$, but this bar type crystal disappeared after 1 hour heat treatment at 1, $600^{\circ}C$. This disappearance means that there should be a little increase of Ca solubility limit to alumina at this temperatures.

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Fabrication of Metal Nanohoneycomb Structures and Their Tribological Behavior

  • Kim, Sung-Han;Lee, Sang-Min;Choi, Duk-Hyun;Lee, Kun-Hong;Park, Hyun-Chul;Hwang, Woon-Bong
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.101-110
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    • 2008
  • Metal nanohoneycomb structures were fabricated by E-beam evaporation and a two-step anodization process in phosphoric acid. Their tribological properties of adhesion and friction were investigated by AFM in relation to the pore size of the nanohoneycomb structures. Variations of the adhesive force are not found with pore size, but formation of the pore greatly reduces the adhesive force compared to the absence of pore structure. The coefficient of friction increased nonlinearly with pore size, due to surface undulation around the pore. Tribological properties do not differ greatly between the original nanohoneycomb structure and the metal nanohoneycomb structure.

Effect of Mg content on the density and critical properties of in-situ reacted MgB2 bulk superconductor

  • Jun, Byung-Hyuk;Kim, Dan-Bi;Park, Soon-Dong;Kim, Chan-Joong
    • Progress in Superconductivity and Cryogenics
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    • v.16 no.1
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    • pp.19-22
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    • 2014
  • The effects of Mg content on the pore formation, density and critical properties were investigated in in-situ reacted $MgB_2$ superconductors. The $Mg_{1+x}B_2$, (x=-0.2, 0.0, 0.05, 0.3, 1.0) bulk samples with different Mg contents were heat-treated at $900^{\circ}C$ for 1 h in an Ar atmosphere. The dimensional changes of a pellet's mass and volume after heat-treatment were measured. After heat-treatment process, the sample mass was decreased by Mg evaporation, but the sample volume was expanded by pore formation at the Mg site; therefore, the apparent density was decreased. Spherical pores the same as Mg particles were developed after heat-treatment in all samples, and the pore density was increased with increasing Mg content. As the x of Mg content was increased to 1.0, the apparent density of $Mg_{1+x}B_2$ samples was decreased due to a relatively larger reduction in a mass change. The critical current density of Mg excessive sample of x=0.05 showed the highest values over the applied magnetic fields because the excessive Mg may compensate Mg loss and enhance grain connectivity.

Determination of the Period of the Formation and Size of Sieve Element Area and Sieve Pore (Streptanthus tortus 조직배양 세포에서 사공의 형성시기와 사공 영역과 사공의 크기 결정)

  • Cho, Bong-Heuy
    • Journal of Plant Biotechnology
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    • v.29 no.1
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    • pp.41-44
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    • 2002
  • During the phloem development from parenchyma cells in a suspension culture of Streptanthus induced sucrose carrier and glucose carrier disappeared. Sieve element area and sieve pore induced suspension culture of Streptanthus were formed almost at the last period of the synthesis of sieve endoplasmic reticulum (SER) and p-protein. The new synthesized cell wall begann to digeste only after the new cell wall was surrounded by SER. The digested region of the cell wall and the formed region of sieve pore were regular comparatively. The completed sieve pore was an oval form, and the outer portion of sieve pore varied, ca 1.2 ${\mu}{\textrm}{m}$~1.6 ${\mu}{\textrm}{m}$ in longitudinal, 0.8 ${\mu}{\textrm}{m}$~1.3 ${\mu}{\textrm}{m}$ in tangential, and the inner size of sieve pore was irregular form of a star-like shape. The number of sieve pore between sieve cells was ca 2~7 per ${\mu}{\textrm}{m}$$^2$ and the sieve pore wall with callose was 0.05 ${\mu}{\textrm}{m}$~0.07 ${\mu}{\textrm}{m}$ in thickness. The energy for the formation of sieve element area and sieve pore might be supplied by mitochondria near the new cell wall and the role of SER remains to be illucidated.

An Empirical Study on the Characteristics of Pore Water Pressure Reaction in Colluvium Model (붕적층내의 간극수압 반응에 관한 실험적 연구)

  • 정두영;최길렬
    • Geotechnical Engineering
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    • v.8 no.2
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    • pp.59-70
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    • 1992
  • This work is to study experimentally the measurment of pore air pressure according to rainfall in colluvium model and the characteristics of pore water pressure according to increasement of artesian ground water head. After modeling a geological feature of the Tertiary formation, the experiment was performed about sixty times on three kinds of soil. This experimental results showed the variation of pore water and pore air pressures with time, the change of void ratio and appling pressure head in the nonsaturated soil. It can be also expressed by the final pore water and the air reaction ratios and then formularizing the relationship between the permeability coefficient and the void ratio. In the results of this experiment, the patterns of the pore water pressure reaction are classified by the step-type and the wave-type, and the time-lag to reach final point of pore water pressure is in order sand, sandy silt and clayey sand.

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Formation and Control of Dual Porous Structures of Metal by an Electrochemical Method (전기화학적 방법을 통한 금속 이중기공구조 형성 및 제어)

  • Ha, Seong-Hyeok;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.65-72
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    • 2019
  • Dual porous structures are observed for the first time on a metallic Cu surface underneath anodic Cu oxide by the application of an anodizing voltage to Cu in oxalic acid. The as-prepared porous Cu surface contains macropores of less than $1{\mu}m$ diameter and mesopores of about tens of nanometers diameter with circular shapes. The size and density (number of pores/area) of the macropores are dependent on the applied voltage. It is likely that the localized dissolution (corrosion) of Cu in oxalic acid under the anodizing voltages is responsible for the formation of the mesopores, and the combination of a number of the mesopores might create the macropores, especially under a relatively high anodizing voltages or a prolonged anodizing time. The variations of pore structure (especailly macropores) with applied voltage and time are reasonably explained on the basis of the proposed mechanism of pore formation.

EFFECT OF TEFLON MEMBRANE AND NYLON MEMBRANE ON GUIDED BONE REGENERATON IN RABBIT TIBIA (가토 경골 골결손부에서 Nylon Membrane과 Teflon Membrane의 골유도 재생 효과)

  • Kim, Kwan-Shik;Cho, Byoung-Ouck;Lee, Young-Chan
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.2
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    • pp.146-153
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    • 2000
  • The purpose of present study is comparing the effect of Teflon Membrane and Nylon Membrane on bone regeneration in rabbit tibia. The 6 defects of $8{\times}8{\times}5mm$ size were drilled with dental handpiece in rabbit tibia, which on left side as an order of Control group(no coverage), Group 1(Nylon $5{\mu}m$ size), Group 3(Nylon $10{\mu}m$ size), and on right side Control group, Group 2($5{\mu}m$ Teflon), Group 4($10{\mu}m$ Teflon). Animals were killed at 7, 10, 14, 42 days to make specimens and observed the difference of healing potentials with light microscopy. The results were as follows ; 1. New bone formation has taken place at 14 days in Guided Bone Regeneration (GBR) group comparing to the Control group of massive inflammatory status. 2. Larger pore membrane allows more favorable healing potentials. Bone formation started earlier in larger membrane pore groups than smaller groups, until 14 days. 3. Bone forming potentials of Teflon membrane group was higher than Nylon membrane groups, Control group has the lowest bone forming potentials. 4. New bone formation was almost ended in 42 days, and there was no difference of bone formation between Nylon and Teflon membrane group of different size. There was no difference of bone formation at final stage(42 days) between Nylon membrane and Teflon membrane of same pore size. So nylon membrane may be clinically usable in guided bone regeneration case with further studies.

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Pore Structure and Permeability of Concrete Containing Pozzolanic Materials (포졸란 함유 콘크리트의 공극구조와 투과특성)

  • 김재신;소형석;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.159-162
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    • 1999
  • The paper presents results of an investigation on the permeability characteristics and pore structure of concrete containing different levels of fly ash, silica fume, or blast furnace slag. The total cementitious content was 351kg/㎥, and the water/cementitious materials ratio was 0.55. The porosity and pore structure of representative pastes of the matrix were measured using mercury intrusion porosimetry, and the permeability characteristics of concrete were also determined by water and oxygen permeability, chloride ion penetration. The results show that significant reduction in permeability of concrete containing pozzolanic materials due to formation of a discontinuous macro-pore system which inhibits flow. And, the permeability of concrete and pore structure(capillary porosity or total porosity) shows linear relationship.

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The formation of highly ordered nano pores in Anodic Aluminum Oxide

  • Im, Wan-soon;Cho, Kyung-Chul;Cho, You-suk;Park, Gyu-Seok;Kim, Dojin
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.53-53
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    • 2003
  • There has been increasing interest in the fabrication of nano-sized structures because of their various advantages and applications. Anodic Aluminum Oxide (AAO) is one of the most successful methods to obtain highly ordered nano pores and channels. Also It can be obtained diverse pore diameter, density and depth through the control of anodization condition. The three types of substrates were used for anodization; sheets of Aluminum on Si wafer and Aluminum on Mo-coated Si wafer. In Aluminum sheet, a highly ordered array of nanoholes was formed by the two step anodization in 0.3M oxalic acid solutions at 10$^{\circ}C$ After the anodization, the remained aluminum was removed in a saturated HgCl$_2$ solution. Subsequently, the barrier layer at the pore bottom was opened by chemical etching in phosphoric acid. Finally, we can obtain the through-channel membrane. In these processes, the effect of various parameters such as anodizing voltage, anodizing time, pore widening time and pre-heat treatment are characterized by FE-SEM (HITACH-4700). The pore size. density and growth rate of membrane are depended on the anodizing voltage and temperature respectively. The pore size is proportional to applied voltage and pore widening time The pore density can be controlled by anodizing temperature and voltage.

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Formation of Sieve Element Area and Sieve Pore in Suspension Cultures of Streptanthus tortus (Streptanthus tortus 조직배양 세포에서 사부 영역과 사공의 형성)

  • 조봉희
    • Korean Journal of Plant Tissue Culture
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    • v.28 no.2
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    • pp.109-112
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    • 2001
  • Sieve element area and sieve pore formed generally from plasmodesmata. Sieve pore formed by the fusion of several tiny vesicles with plasmodesmata, or those with cell wall after the destruction of special region of newly formed cell wall or those finally with circular arranged form from tissure culture of Streptanthus. The tiny vesicles were produced from dispersed nucleolus or heterochromatin. The sieve area and sieve pore formed from tissue cultured cells were shown round tube form similar to those of natural plants. Sieve area and sieve pore were produced by various methods, and it suggested that the basic materials of the construction of sieve pore originated from the vesicles.

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