• Journal of Electrochemical Science and Technology
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• v.12 no.2
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• pp.257-265
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• 2021

In this study, we report niobium (Nb) with hierarchical porous structure produced by a one-pot, HF-free electrochemical etching process. It is proved experimentally that a well-defined hierarchical porous structure is produced from the combination of a limited repetition of pulse etching and high concentration of aggressive anion (i.e., SO₄^2-), which results in hierarchical pores with high order over 3. A formula is derived for the surface area of porous Nb as a function of the hierarchical order of pores while the experimental surface area is estimated on the basis of the electrochemical gas evolution rate on porous Nb. From the comparison of the theoretical and experimental surface areas, an in-depth understanding was gained about porous structure produced in this work in terms of the actual pore shape and hierarchical pore order.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.1
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• pp.79-89
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• 1996

It is expected that the soil hehaviours in the seahed subjected to cyclic wave loads are much different from that on the ground Cyclic shear stresses developed below the ocean bed as a result of a passing wave train may progressively build up pore pressure in certain soils. Such build-up pore pressure may be developed dynamic behaviour such as liquefaction and significant deformation of the seabed. Currently available analytical and testing methods for the seabed subjected to cyclic wave loads are not general. The purpose of the study are to provide a test method in laboratory and to analyse the mechanism of wave-induced stresses and liquefactions potentials of the unsaturated silty marine sand. It is showed that the test set-up made especially for this study delivers exactly oscillatory wave pressures of the form of sine function. Laboratory test results defining the cyclic shear strength of the unsaturated porous medium that is homogenously sedimented. It is understood that the pore water pressure due to induced-waves is not accumulated as the wave number increases but reveals periodical change on the still water surface. The magnitude of the pore water pressure tends to be attenuated radically with a certain time lag under the action of both high and low waves as depth increases.

• Journal of the Korea Concrete Institute
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• v.14 no.1
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• pp.100-109
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• 2002

Significant damage to concrete results from the intrusion of corrosive solutions, for example, dissolved chlorides corrode reinforcing steel and cause spatting. Effectively blocks the penetration of these solutions will eliminate or greatly reduce this damage and lead to increased durability. This study is to investigate the effects of pozzolanic admixtures, fly ash and silica fume, and a blast furnace slag on the chloride ion penetration of concretes. The main experimental variables wore the water-cementitious material ratios, the types and amount of admixtures, and the curing time. And it is tested for the porosity and pore size distributions of cement paste, chloride ion permeability based on electrical conductance, and 180-day ponding test for chloride intrusion. The results show that the resistance of concrete to the penetration of chloride ions increases as the w/c was decreased, and the increasing of curing time. Also, concrete with pozzolans exhibited higher resistance to chloride ion penetration than the plain concrete. The significant reduction in chloride ion permeability(charge passed) of concrete with pozzolans due to formation of a discontinuous macro-pore system which inhibits flow. It is shown that there is a relationship between chloride ion permeability and depth of chloride ion penetration of concrete, based on the pore structure (porosity and pore size distributions) of cement paste.

• Journal of The Korean Society of Agricultural Engineers
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• v.56 no.6
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• pp.63-73
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• 2014

In this study, the large scale test was performed to investigate the behavior of failure on the embankment and spillway transitional zone by overtopping. The pore water pressure, earth pressure, settlement and failure behaviors according to several reinforcing method were compared and analyzed. The pore water pressure showed a small change in the spillway transition zone and core, indicating that the riprap and geotextile efficiently reinforced the embankment, but non-reinforcement showed a largely change in pore water pressure. The earth pressure by riprap and geotextile at upstream slope and bottom core increased rapidly with the infiltration of the pore water by overtopping. And the earth pressure at crest showed a smally change due to effect of the inclined core. A settlement by riprap showed a small change and the geotextile decreased a rapidly due to failure of crest. The width of failure by riprap at intermediate stage (50 min) showed a largely due to sliding of crest. But, the width and depth of the seepage erosion after the intermediate overtopping period (100 min) were very small due to the effect of riprap than geotextile and non-reinforcement which delayed failure. It has the effect that protect reservoir embankment from erosion in the central part. The pore water pressure at the spillway transition zone due to overtopping increased a rapidly in the case of non-reinforcement, but the reinforced methods by geotextile and riprap showed a smally change. Therefore, the reinforced method by riprap and geotextile was a very effective method to protect permanently and the emergency an embankment due to overtopping, respectively.

• Proceedings of the Korean Fiber Society Conference
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• 2007.11a
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• pp.499-500
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• 2007

• Journal of the Korean Geotechnical Society
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• v.31 no.7
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• pp.13-28
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• 2015

This study extended the Lee et al.'s (2015a) solution which improved the existing analytical solution for prediction of the residual pore water pressure into progressive wave and flow coexisting field. At this time, the variation of incident wave period and wave length should be incorporated to Lee et al.'s (2015a) analytical solution, which does not consider flow. For the case of infinite thickness, the new analytical solution using Fourier series was compared to the analytical solution using Laplace transformation proposed by Jeng and Seymour (2007). It was verified that the new solution was identical to the Jeng and Seymour's solution. After verification of the new analytical solution, the residual pore water pressure head was examined closely under various given values of flow velocity's magnitude, direction, incident wave's period and seabed thickness. In each proposed analytical solution, asymptotic approach to shallow depth with the changes in the soil thickness within finite soil thickness was found possible, but not to infinite depth. It is also identified that there exists a discrepancy case between the results obtained from the finite and the infinite seabed thicknesses even on the same soil depth.

• The Journal of Engineering Geology
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• v.34 no.2
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• pp.217-228
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• 2024

During deep drilling, confined aquifers can present various challenges such as the inability to remove cuttings, rapid groundwater influx, and mud loss. Particularly in flowing well conditions, it is essential to apply the suitable mud density since the aquifer can generates an overpressurized condition. This paper proposes a method for determining the suitable mud density while drilling (SMD) through confined aquifers using mud window analysis and applies it to a case study. The minimum mud density at each depth, which represents the lower limit of the mud window, is determined by the equivalent mud density pore pressure gradient (or by adding a trip margin) at that depth. The pore pressure gradient of a confined aquifer can be calculated using the piezometric level or well head pressure of the aquifer. As the borehole reaches the confined aquifer, there is a significant increase in pore pressure gradient, which gradually decreases with increasing depth. The SMD to prevent a kick can be determined as the maximum value among the minimum mud densities in the open hole section. After entering the confined aquifer, SMD is maintained as the minimum mud density at the top of the aquifer during the drilling of the open hole section. Additionally, appropriate casing installation can reduce the SMD, minimizing the risk of mud loss or invasion into the highly permeable aquifer.

• Journal of the Korean GEO-environmental Society
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• v.6 no.2
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• pp.15-20
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• 2005

Moutain side ditch is constructed at the top of cutting slopes around road and it drains the surface water that flowed from upper part. About 70% of a country is composed of mountains so occurrence of cutting face by road general observation is necessary. Instability of cutting face is increased by permeation of underground water by rainfall the summer, pore water pressure increases. However, moutain side ditch is constructed on the top of cutting slopes has some troubles. For example, difficulty of qualify control and lack of drainage faculty. Therefore, stability variation of cutting slope is analyzed by hydraulic conductivity and construction depth of mountain side ditch and effective depth of mountain side ditch is decided in this paper.

• Journal of Korean Society on Water Environment
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• v.34 no.1
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• pp.84-95
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• 2018

The community structure of benthic macroinvertebrates in the fine sediments of freshwater was analyzed according to various sampling tools and methods. The sediment core with the inner diameter of 7.5 cm was more effective in cost and labor in comparison to that of ${\Phi}5cm$ or ${\Phi}10cm$. The number of species increased with the increase in sample size (replicates). When it was collected five times with the ${\Phi}7.5cm$ sediment core, Shannon-Weaver's diversity and McNaughton's dominance of the sample reached about the 80 % level of the community estimates. Most species appeared in the sediment layer of 0-4 cm, and there were no newly recruited species below the depth of 4 cm. Individual abundance of benthic macroinvertebrates decreased exponentially along with the increase in sediment depth. Compared with the individual abundance of the 0-15 cm sediment layer, the abundance was 60 % in the 0-2 cm layer, 25 % in the 2-4 cm layer, 10 % in the 4-6 cm layer and 95 % in the 0-6 cm layer. Compared with organisms collected with the sieve of 0.2 mm pore, the number of species and the individual abundance sifted through the sieve with pore of 1 mm were 36 % and 88 %, and those with pore of 0.5 mm were 5 % and 55 %, respectively.

• Journal of Industrial Technology
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• v.28 no.B
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• pp.71-79
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• 2008

Reports about coefficients of consolidation in horizontal direction of marine clays located at seven different sites on western and southern coast area in Korea were reviewed and characteristics of them were investigated. As results of analyses, for relation between the depth of ground and coefficients, any trend and correlation between them can not be found since they are more influenced by the nature of geological formation rather than the depth of ground. Dissipation time t50, one of important factors in estimating value of coefficient of consolidation in horizontal direction, was found to be quite related to them. For the correlation between the maximum pore pressure developed and coefficients, coefficient of consolidation in the horizontal direction tend to decrease with increase of the maximum pore pressure whereas the ground water level or static pore pressure do not have any specific correlation with those coefficients. Values of coefficient tends to increase with values of liquid limit, plastic limit and plastic index and thus they are found to be directly influenced by the contents of fines. Values of coefficient of consolidation in horizontal direction are also increased with increases of permeability in horizontal direction and coefficient of consolidation in vertical direction. They were highly correlated between coefficient of consolidation and permeability in horizontal direction while values of coefficient of consolidation in horizontal direction have a relatively low correlation with values of coefficient of consolidation in horizontal direction. Sometimes, coefficient of consolidation in horizontal direction obtained from field tests were estimated 2-3 times greater than those from laboratory tests.