• Title/Summary/Keyword: pore architecture

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Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • v.10 no.3
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

Investigation on the responses of offshore monopile in marine soft clay under cyclic lateral load

  • Fen Li;Xinyue Zhu;Zhiyuan Zhu;Jichao Lei;Dan Hu
    • Geomechanics and Engineering
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    • v.37 no.4
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    • pp.383-393
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    • 2024
  • Monopile foundations of offshore wind turbines embedded in soft clay are subjected to the long-term cyclic lateral loads induced by winds, currents, and waves, the vibration of monopile leads to the accumulation of pore pressure and cyclic strains in the soil in its vicinity, which poses a threat to the safety operation of monopile. The researchers mainly focused on the hysteretic stress-strain relationship of soft clay and kinds of stiffness degradation models have been adopted, which may consume considerable computing resources and is not applicable for the long-term bearing performance analysis of monopile. In this study, a modified cyclic stiffness degradation model considering the effect of plastic strain and pore pressure change has been proposed and validated by comparing with the triaxial test results. Subsequently, the effects of cyclic load ratio, pile aspect ratio, number of load cycles, and length to embedded depth ratio on the accumulated rotation angle and pore pressure are presented. The results indicate the number of load cycles can significantly affect the accumulated rotation angle of monopile, whereas the accumulated pore pressure distribution along the pile merely changes with pile diameter, embedded length, and the number of load cycles, the stiffness of monopile can be significantly weakened by decreasing the embedded depth ratio L/H of monopile. The stiffness degradation of soil is more significant in the passive earth pressure zone, in which soil liquefaction is likely to occur. Furthermore, the suitability of the "accumulated rotation angle" and "accumulated pore pressure" design criteria for determining the required cyclic load ratio are discussed.

Design of Pore and Matter Architectures in Cobalt Oxide Electrode for Supercapacitor (수퍼커패시터용 산화코발트전극의 세공과 재료구조의 설계)

  • Kim, Han-Joo;Shin, Dal-Woo;Kim, Yong-Chul;Kim, Seong-Ho;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.425-427
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    • 2000
  • We describe the preparation of a cobalt oxide in which the solid-pore architecture of the material is controllably varied. All $CoO_2$ gels derived from $CoCl_2$-based sol-gel synthesis, but exhibit markedly different final pore structures based on how the pore fluid is removed from forces that result from extraction are either low or nonexistent. These nanoscale mesoporous materials have higher $CoO_2$ crystallites. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of new supercapacitor and charge-storage materials.

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Simulating the influence of pore shape on the Brazilian tensile strength of concrete specimens using PFC2D

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi
    • Computers and Concrete
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    • v.22 no.5
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    • pp.469-479
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    • 2018
  • The Brazilian tensile strength of concrete samples is a key parameter in fracture mechanics since it may significantly change the quality of concrete materials and their mechanical behaviors. It is well known that porosity is one of the most often used physical indices to predict concrete mechanical properties. In the present work the influence of porosity shape on concrete tensile strength characteristics is studied, using a bonded particle model. Firstly numerical model was calibrated by Brazilian experimental results and uniaxial test out puts. Secondly, Brazilian models consisting various pore shapes were simulated and numerically tested at a constant speed of 0.016 mm/s. The results show that pore shape has important effects on the failure pattern. It is shown that the pore shape may play an important role in the cracks initiation and propagation during the loading process which in turn influence on the tensile strength of the concrete samples. It has also been shown that the pore size mainly affects the ratio of uniaxial compressive strength to that of the tensile one in the simulated material samples.

Experimental and numerical studies of the pre-existing cracks and pores interaction in concrete specimens under compression

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Marji, Mohammad Fatehi
    • Smart Structures and Systems
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    • v.23 no.5
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    • pp.479-493
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    • 2019
  • In this paper, the interaction between notch and micro pore under uniaxial compression has been performed experimentally and numerically. Firstly calibration of PFC2D was performed using Brazilian tensile strength, uniaxial tensile strength and biaxial tensile strength. Secondly uniaxial compression test consisting internal notch and micro pore was performed experimentally and numerically. 9 models consisting notch and micro pore were built, experimentally and numerically. Dimension of these models are 10 cm*1 cm*5 cm. the length of joint is 2 cm. the angularities of joint are $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$. For each joint angularity, micro pore was situated 2 cm above the lower tip of the joint, 2 cm above the middle of the joint and 2 cm above the upper of the joint, separately. Dimension of numerical models are 5.4 cm*10.8 cm. The size of the cracks was 2 cm and its orientation was $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$. Diameter of pore was 1cm which situated at the upper of the notch i.e., 2 cm above the upper notch tip, 2 cm above the middle of the notch and 2 cm above the lower of the notch tip. The results show that failure pattern was affected by notch orientation and pore position while uniaxial compressive strength is affected by failure pattern.

Controlling Pore Size of Electrospun Silk Fibroin Scaffold for Tissue Engineering (전기방사를 이용한 조직공학용 실크 피브로인 나노 섬유 지지체의 기공 크기 조절)

  • Cho, Se-Youn;Park, Hyun-Ho;Jin, Hyoung-Joon
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.651-655
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    • 2012
  • Considerable effort has been directed toward the use of silk fibroin as a biotechnological material in biomedical applications on account of its excellent biodegradability, biocompatibility, and unique mechanical properties. For use in tissue engineering, it is very important to design and control the pore architecture of polymeric scaffolds, which provide the vital framework for seeded cells to organize into functioning tissue. In the present study, a silk fibroin scaffold with controlled interconnectivity and pore size was prepared using an electrospinning method with poly(ethylene oxide).

Application on Supercapacitor of Manangese Oxide Electrodes Prepared by Various Synthesis Methods (다양한 합성방법으로 제조된 망간옥사이드 전극들의 수퍼커패시터에 대한 응용)

  • 김한주;신달우;김용철;김성호;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.606-609
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    • 2000
  • We describe the preparation of a manganese oxide polymorph in which the solid-pore architecture of the material is controllably varied. All MnO$_2$ gels derived from a KMnO$\_$4/-based sol-gel synthesis. The mesoporous structure of the initial gel is maintained by removingore fluid under conditions where the capillary forces that result fro extraction are either low or no existent. are either low or noexistent. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of supercapacitor.

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Development and Validation of a Perfect KASP Marker for Fusarium Head Blight Resistance Gene Fhb1 in Wheat

  • Singh, Lovepreet;Anderson, James A;Chen, Jianli;Gill, Bikram S;Tiwari, Vijay K;Rawat, Nidhi
    • The Plant Pathology Journal
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    • v.35 no.3
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    • pp.200-207
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    • 2019
  • Fusarium head blight (FHB) is a devastating wheat disease with a significant economic impact. Fhb1 is the most important large effect and stable QTL for FHB resistance. A pore-forming toxin-like (PFT) gene was recently identified as an underlying gene for Fhb1 resistance. In this study, we developed and validated a PFT-based Kompetitive allele specific PCR (KASP) marker for Fhb1. The KASP marker, PFT_KASP, was used to screen 298 diverse wheat breeding lines and cultivars. The KASP clustering results were compared with gelbased gene specific markers and the widely used linked STS marker, UMN10. Eight disagreements were found between PFT_KASP and UMN10 assays among the tested lines. Based on the genotyping and sequencing of genes in the Fhb1 region, these genotypes were found to be common with a previously characterized susceptible haplotype. Therefore, our results indicate that PFT_KASP is a perfect diagnostic marker for Fhb1 and would be a valuable tool for introgression and pyramiding of FHB resistance in wheat cultivars.

Experimental study on damage and debonding of the frozen soil-concrete interface under freeze-thaw cycles

  • Liyun Tang;Yang Du;Liujun Yang;Xin Wang;Long Jin;Miaomiao Bai
    • Structural Engineering and Mechanics
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    • v.86 no.5
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    • pp.663-671
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    • 2023
  • Freeze-thaw cycles induce strength loss at the frozen soil-concrete interface and deterioration of bonding, which causes construction engineering problems. To clarify the deterioration characteristics of the interface under the freeze-thaw cycle, a frozen soil-concrete sample was used as the research object, an interface scanning electron microscope test under the freeze-thaw cycle was carried out to identify the micro index information, and an interface shear test was carried out to explore the loss law of interface shear strength under the freeze-thaw cycle. The results showed that the integrity of the interface was destroyed, and the pore number and pore size of the interface increased significantly with the number of freeze-thaw cycles. The connection form gradually deteriorates from surface-to-surface contact to point-to-surface contact and point-to-point contact, and the interfacial shear strength decreases the most at 0-3 freeze-thaw cycles, with small decreases from to 3-8 cycles. After 12 freeze-thaw cycles, the interfacial shear strength tends to be stable, and shear the failure occurs internally in the soil.

Thaw consolidation behavior of frozen soft clay with calcium chloride

  • Wang, Songhe;Wang, Qinze;Xu, Jian;Ding, Jiulong;Qi, Jilin;Yang, Yugui;Liu, Fengyin
    • Geomechanics and Engineering
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    • v.18 no.2
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    • pp.189-203
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    • 2019
  • Brine leakage is a common phenomenon during construction facilitated by artificial freezing technique, threatening the stability of frozen wall due to the continual thawing of already frozen domain. This paper takes the frequently encountered soft clay in Wujiang District as the study object, and remolded specimens were prepared by mixing calcium chloride solutions at five levels of concentration. Both the deformation and pore water pressure of frozen specimens during thawing were investigated by two-stage loading tests. Three sections were noted from the changes in the strain rate of specimens during thawing at the first-stage load, i.e., instantaneous, attenuated, and quasi-stable sections. During the second-stage loading, the deformation of post-thawed soils is closely correlated with the dissipation of pore water pressure. Two characteristic indexes were obtained including thaw-settlement coefficient and critical water content. The critical water content increases positively with salt content. The higher water content of soil leads to a larger thaw-settlement coefficient, especially at higher salt contents, based on which an empirical equation was proposed and verified. The normalized pore water pressure during thawing was found to dissipate slower at higher salt contents, with a longer duration to stabilize. Three physical indexes were experimentally determined such as freezing point, heat conductivity and water permeability. The freezing point decreases at higher salt contents, especially as more water is involved, like the changes in heat conductivity. The water permeability maintains within the same order at the considered range of salt contents, like the development of the coefficient of consolidation. The variation of the pore volume distribution also accounts for this.